Superior incident photon-to-current conversion efficiency of Mo-doped activated carbon supported CdS-sensitized solar cells

Environmental Science and Pollution Research - In this study, the performance of activated carbon (AC) produced from defatted black cumin (Nigella sativa L.) by chemical activation with zinc...     

Classification of residential areas according to physical vulnerability to natural hazards: a case study of Çanakkale,Turkey

The selection of new settlement areas and the construction of safe buildings, as well as rendering built‐up areas safe, are of great importance in mitigating the damage caused by natural disasters. Most cities in Turkey are unprepared for natural hazards. In this paper, Çanakkale, located in a first‐degree seismic zone and sprawled around the Sartçay Delta, is examined in terms of its physical vulnerability to natural hazards. Residential areas are analysed using GIS (geographic information system) and remote‐sensing technologies in relation to selected indicators. Residential areas of the city are divided into zones according to an evaluation of geological characteristics, the built‐up area's features, and urban infrastructure, and four risk zones are determined. The results of the analysis show that the areas of the city suitable for housing are very limited. In addition, the historical centre and the housing areas near Sartçay stream are shown to be most problematic in terms of natural disasters and sustainability.     

Fatty acid composition of marine macroalgae from the Black Sea and Dardanelles

The fatty acid (FA) composition was determined in 14 species of marine macroalgae belonging to the Chlorophyta, Phaeophyta and Rhodophyta, which were collected from ?ile in the Black Sea and Kepez in the Dardanelles. Generally, polyunsaturated FAs and monounsaturated FAs were major components (50–77%). Total saturated FAs ranged from 22% to 50%, with 16?:?0 as the most abundant saturate (32–38%). Two samples of Cystoseira barbata collected from a different station had some differences from each other in their contents of 18?:?2n-6 and 18?:?3n-3 and in the 18?:?2n-6/20?:?4n-6 ratios. Green algal species had a significantly higher proportion of unsaturated FAs and a significantly lower proportion of saturated FAs than the red and brown algae. The amount of n-3 FAs was significantly higher in Ulva rigita, Chaetomorpha linum, Enteromorpha linza and Gracilaria verrucosa (8.88, 6.44, 5.31 and 5.24, respectively).     

Cadmium accumulation by green algae Cladophora glomerata (L.) Kutz. (Chlorophyta) in presence of Nile tilapia Oreochromis niloticus (L.)

Accumulation of metals by aquatic organisms is mostly affected by other biological components in environments. In this study, cadmium (Cd) accumulation in green algae, Cladophora glomerata (L.) Kutz., exposed to 0.1 and 1.0 mg L^?1 of Cd for 15 and 30 days was examined in laboratory conditions in the presence of Nile tilapia Oreochromis niloticus (L.). The green algae C. glomerata accumulated Cd concentrations as 690 ± 70 and 3430 ± 470 mg kg^?1 on day 15, and 1130 ± 180 and 6830 ± 1540 mg kg^?1 on day 30. There were significant increases (p < 0.05) in metal accumulation by green algae as the exposure time and metal concentration increased. The results also indicated that the presence of Nile tilapia in the medium led to a significant Cd accumulation in the green algae compared to control (p < 0.05).     

Particulate and semivolatile associated aliphatic hydrocarbon exhaust emission from heavy duty diesel vehicles

The exhaust emissions from two heavy duty diesel vehicles running on eight different fuel compositions were investigated regarding their content of high molecular weight (≥ C₁₂) aliphatic/ olefinic hydrocarbons. It was concluded that the emitted amount of semi‐volatile associated aliphatic hydrocarbons (range C₁₂‐C₂₂) depend on the fuel used in the engines and that these emissions mainly consisted of uncombusted fuel components. It was also found that uncombusted engine lubrication oil was the main constituent of the emitted particulate associated aliphatic hydrocarbons (C₁₇‐C₄₀). These constituted between 58% and 95% of the total emissions of the high molecular weight aliphatic compounds. Emission factors for the total of high molecular aliphatic hydrocarbons (C₁₂‐C₄₀) were demonstrated to be in the range of 15–100 mg/km. Some individual aliphatic hydrocarbons with cocarcinogenic effects were identified and quantified in both particulate and semi‐volatile phases of the exhaust. Multivariate data analysis was used to investigate the relationship between fuel parameters and emission of semi‐volatile aliphatic emission.     

Public space networks as a guide to sustainable urban development and social life: A case study of Muğla,Turkey

This study examines the possibility of designating and implementing a citywide public space network, constituted of randomly dispersed and not interrelated public spaces and greenways across the city of Mu?la. Although Mu?la is a major coastal province, with worldwide tourism districts, the city centre falls behind other settlements in terms of quality of social life, physical layout, economic investment and tourism revenue. In 2001, the local government commissioned the Department of Landscape Architecture of Ege University to prepare a comprehensive master plan towards achieving a corporate public space network, as well as development strategies to ameliorate the previous failures. The master plan developed a blueprint for the citywide network and addressed each existing or potential public space and greenway as integrated components of the network. The process involved short-, medium- and long-term action from the local government to achieve the physical layout and efficiently implement phases of the network. As a guide for other small or medium urban settlements in Turkey, a model proposal was derived from the study to address formulation, implementation, and management of the network in order to create a sustainable urban development.     

Indoor and outdoor radon measurements at lung cancer patients’ homes in the dwellings of Rize Province in Turkey

In this study, indoor and outdoor radon (²²²Rn) surveys were carried out in the summer and winter seasons in homes of one hundred lung cancer patients in the year 2013–2014. The aim was to investigate the relationship between radon and cancer patients. Lung cancer patients completed a questionnaire concerning their living environment, various physical parameters and living habits. Pearson correlation and t tests revealed no meaningful results between radon concentrations, on one hand, and environmental and personal living habits, on the other hand. Consequently, the BEIR VI model was adapted and ²²²Rn exposure was estimated to be responsible for about 12% of the lung cancer incidences in the winter season and around 5% in the summer season in the Rize Province. However, due to the limited number of data and numerous parameters that could lead to lung cancer, the estimations done with the model should be taken very lightly. The annual effective doses due to inhalation of indoor and outdoor ²²²Rn were estimated to be, respectively, 1.43 and 0.94 mSv y^?1. The indoor and outdoor annual effective doses were, respectively, close and below the world annual effective dose (1.3 mSv y^?1). At the district level, the indoor annual effective dose equivalent in the ?yidere district was 4.52 mSv y^?1, which was 3.5 times greater than the world average. The number of patients in the majority of the houses in this district was more than one.     

Evaluation of the relationship of picoplankton and viruses to environmental variables in a lagoon system (Çakalburnu Lagoon,Turkey)

Lagoons are defined as wetlands separated from the sea coasts on which they are located and sit between continental and marine aquatic ecosystems. Çakalburnu Lagoon is a coastal wetland on the southern side of the Bay of ?zmir. Microorganisms, which are quite sensitive to changes occurring in environmental factors, are commonly used to determine the impact of environmental effects on the functioning of the ecosystem. In this study, variations in the abundance and biomass of picoplankton (Synechococcus spp. and bacteria) and the abundance of viruses, which identify the ecological productivity of the food chain, were seasonally examined by epifluorescence microscopy. Moreover, the microbial abundance and biomass relation over time between the physical and chemical parameters was evaluated. According to our results, the maximum abundance of Synechococcus spp. and viruses was 6.7?×?10⁴ cell/ml and 9.9?×?10⁸?cell/ml in the summer, respectively. Otherwise, the highest level of bacteria was measured at 3.6?×?10⁷ cell/ml in the spring. Based on the principal component analysis and Pearson correlation analysis results, we concluded that total suspended solids, Chl-a, particulate organic carbon and particulate organic nitrogen were the major parameters influencing the observed variability of the lagoon system. Overall, to protect and improve the ecological and microbiological quality of aquatic systems such as lagoons, the necessary monitoring and measurement studies should be conducted in these sensitive areas.     

Effects of nanoparticles on Daphnia magna population dynamics

Spherical TiO₂ nanoparticles (npTiO₂) were prepared by controlled hydrolysis of tetraethoxy orthotitanate under a nitrogen atmosphere. ZnO nanoparticles (npZnO) were prepared using hydrothermal methods. The crystal structure, chemical, thermal and morphological properties of npZnO and npTiO₂ were characterised using Fourier Transform Infrared Spectrometer, enery-dispersive X-ray spectroscopy, X-ray diffraction, and scanning electron microscope techniques. The short- and long-term experiments were started with neonates taken from the same culture and laboratory condition. In the acute experiments, npTiO₂, npZnO, and cocktail concentrations were applied. 96h-LC₅₀ values were 1.8, 0.7, and 0.1?mg?L^?1, respectively (p?<?.05). For the chronic experiments, different npTiO₂ concentrations were performed. 21d-LC₅₀ value was 1.0?mgL^?1 (p?<?.05). Morphometry became progressively worse in concentrations of more than 1?mgL^?1 npTiO₂. Neonate and young individuals were more sensitive to death because of their low tolerance. This result was affected by population progeny and growth rates (p?<?.05). While control and 0.5?mgL^?1 npTiO₂ groups were determined as growing population, 1.5 and 2?mgL^?1 npTiO₂ groups had decreased population size as R₀ values. Consequently, the relationships between nanoparticle accumulation within Daphnia magna and its population structure and body morphometry for each concentration were important indicators. Its tolerance level to nanoparticles under laboratory conditions reflected its replacement and behaviour in the ecosystem.     

Health importance of arsenic in drinking water and food

Arsenic is a toxic metalloid of global concern. It usually originates geogenically but can be intensified by human activities such as applications of pesticides and wood preservatives, mining and smelting operations, and coal combustion. Arsenic-contaminated food is a widespread problem worldwide. Data derived from population-based studies, clinical case series, and case reports relating to ingestion of inorganic arsenic in drinking water, medications, or contaminated food or beverages show the capacity of arsenate and arsenite to adversely affect multiple organ systems. Chronic arsenic poisoning can cause serious health effects including cancers, melanosis (hyperpigmentation or dark spots, and hypopigmentation or white spots), hyperkeratosis (hardened skin), restrictive lung disease, peripheral vascular disease (blackfoot disease), gangrene, diabetes mellitus, hypertension, and ischemic heart disease.