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广东韶钢集团公司拥有原料加工、烧结、焦化、炼钢炼铁、轧钢及辅助厂和矿山等22个生产单位,是一个联合性的钢铁企业。也是全国3000家污染大户之一,并被广东省政府列人限期治理的“黑名单”。在这样污染严重的企业,怎样控制污染、实行清洁生产呢?多年来,我们认真贯彻执行《环保法}),以“三杯”竞赛为主线,厂容建设等为辅助,全方位开展综合治理活动,减少钢铁企业生产污染。“三杯”竞赛的内容为:蓝天杯,它是以控制大气污染为主要内容的劳动竞赛活动:包括生产过程、燃料燃烧过程及粉尘治理、废气中烟尘(粉尘)排放浓度、燃料消… 相似文献
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Xiangjuan Yuan Xuan Yan Haiming Xu Dongya Li Lei Sun Gang Cao Dongsheng Xia 《环境科学学报(英文版)》2017,29(11):3-13
Enhanced ozonation degradation of atrazine (ATZ) with nano-ZnO (nZnO) as catalyst and the influences of the operational parameters have been investigated through semi-continuous experiments in this study. The results demonstrated that the combination of ozone (O3) and nZnO showed an obvious synergetic effect and the ATZ degradation conformed to pseudo-first-order kinetics. An improvement of ATZ degradation efficiency by 41.8% and pseudo-first-order rate constant by more than a factor of four was obtained in the O3/nZnO process after 5 min of reaction compared to O3 alone. Meanwhile, the degradation efficiency of ATZ was gradually enhanced with increasing nZnO dosage and initial pH in the range from 3.0 to 8.0, and a higher amount of ATZ was degraded when the initial concentration of ATZ rose from 0.5 to 5 mg/L. Additionally, sulfate ion, chloride ion, nitrate ion and low concentrations of humic acid substances led to enhancement of the ATZ degradation. The notable decrease of ATZ removal efficiency observed in the presence of radical scavengers and the results of free radical tests indicated that OH is the dominant active radical species. The mechanism investigation demonstrated that the enhancement effect could be attributed to the introduction of nZnO, which could promote the utilization of O3, enhance the formation of superoxide radical, and further accelerate the production of hydrogen peroxide and the generation of OH/O2-. 相似文献
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Qingyu Zhang Jiaoyu Liu Youjiang He Jiaying Yang Jian Gao Houfeng Liu Wei Tang Yizhen Chen Wenhao Fan Xuan Chen Fahe Chai Shiro Hatakeyama 《环境科学学报(英文版)》2018,30(2):72-81
Gaseous peroxides play important roles in atmospheric chemistry. To understand the pathways of the formation and removal of peroxides, atmospheric peroxide concentrations and their controlling factors were measured from 7:00 to 20:00 in September, October, and November 2013 at a heavily trafficked residential site in Beijing, China, with average concentrations of hydrogen peroxide (H2O2) and methyl hydroperoxide (MHP) at 0.55 ppb and 0.063 ppb, respectively. H2O2 concentrations were higher in the afternoon and lower in the morning and evening, while MHP concentrations did not exhibit a regular diurnal pattern. Both H2O2 and MHP concentrations increased at dusk in most cases. Both peroxides displayed monthly variations with higher concentrations in September. These results suggested that photochemical activity was the main controlling factor on variations of H2O2 concentrations during the measurement period. Increasing concentrations of volatile organic compounds emitted by motor vehicles were important contributors to H2O2 and MHP enrichment. High levels of H2O2 and MHP concentrations which occurred during the measurement period probably resulted from the transport of a polluted air mass with high water vapor content passing over the Bohai Bay, China. 相似文献
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In this paper, marine brown algae Laminaria japonica was chemically-modified by crosslinking with epichlorohydrin (EC(1), EC(2)), or oxidizing by potassium permanganate (PC), or only washed by distilled water (DW). They were used for equilibrium sorption uptake studies with lead. As can be seen from the experimental results that biosorption equilibriums were rapidly established in about 2h. The lead adsorption was strictly pH dependent, and maximum removal of lead on biosorbents were observed at pH 5.3. The effects solid/liquid ratio on lead biosorption was also investigated. The maximum lead uptakes were 1.67 mmol g(-1), 1.62 mmol g(-1), 1.54 mmol g(-1) and 1.21 mmol g(-1), respectively for EC(1), EC(2), PC and DW. The order of maximum lead uptakes for different pretreated and raw alga was EC(1)>EC(2)>PC>DW. A comparison of different isotherm models revealed that the combination of Langmuir and Freundlich (L-F) isotherm model fitted the experimental data best. 相似文献
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Xiangke Wang Zhongshan Chen Xuan He Qian Li Hui Yang Yang Liu Lining Wu Zhixin Liu Baowei Hu 《环境科学学报(英文版)》2022,34(12):1-13
For the continuous utilization of nuclear energy and efficient control of radioactive pollution, low-cost materials with high efficient U(VI) removal are of great importance. In this study, low temperature plasma method was applied for the successful modification of O-phosphorylethanolamine (O-PEA) on the porous carbon materials. The produced materials (Cafe/O-PEA) could adsorb U(VI) efficiently with the maximum sorption capacity of 648.54 mg/g at 1 hr, T=298 K, and pH=6.0, much higher than those of most carbon-based composites. U(VI) sorption was mainly controlled by strong surface complexation. From FTIR, SEM-EDS and XPS analyses, the sorption of U(VI) was related to the complexation with -NH2, phosphate and -OH groups on Cafe/O-PEA. The low temperature plasma method was an efficient, environmentally friendly and low-cost method for surface modification of materials for the effective enrichment of U(VI) from aqueous solutions. 相似文献
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Feng Wang Weiying Li Yue Li Junpeng Zhang Jiping Chen Wei Zhang Xuan Wu 《Frontiers of Environmental Science & Engineering》2018,12(3):6
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Wanqi Qi Weiying Li Junpeng Zhang Xuan Wu Jie Zhang Wei Zhang 《Frontiers of Environmental Science & Engineering》2019,13(1):15
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The influence of the Haizhou Open Pit Mine on the atmospheric flow in nearby Fuxin City in China was analyzed with the aid of the steady-state Navier-Stokes equations. The finite element method was used to obtain numerical solutions to these equations. The results showed that the Haizhou Open Pit Coal Mine contributes to the turbulent flow in the Fuxin City and its surroundings. However,when compared with the climatic effects, the open pit mine has a relatively small impact on the atmospheric flow over Fuxin. 相似文献