Room temperature aqueous Paal–Knorr pyrrole synthesis catalyzed by aluminum tris(dodecyl sulfate)trihydrate

This article reports a novel procedure to prepare pyrroles using a modification of the Paal–Knorr reaction. Water is a safe solvent meeting environmental considerations, but most organic substrates are not soluble in water. A possible solution to improve the solubility of substrates is the use of surface-active reagents that can form micelles. For instance, combined Lewis acid–surfactant catalyst acts both as a Lewis acid to activate the substrate molecules and as a surfactant to form emulsions in water. Here, we prepared and used aluminum tris(dodecyl sulfate)trihydrate to condense various amines to 2,5-hexadione at room temperature. The sole solid pyrrole was separated by a simple filtration. Our findings thus show a novel and improved modification of the Paal–Knorr reaction in terms of mild reaction conditions and clean reaction profiles, using a simple workup procedure and improved yields with excellent chemo-selectivity.     

Thermal and Environmentally Induced Degradation Behaviors of Amorphous and Semicrystalline PLAs Through Rheological Analysis

Journal of Polymers and the Environment - The degradation behaviors of an amorphous and a semicrystalline PLA (i.e., aPLA and cPLA) with similar molecular weights are compared at elevated...     

SWOT analysis for socio-ecological landscape variation as a precursor to the management of the mountainous Kanshi watershed,Salt Range of Pakistan

Variations in geo-environmental attributes differ strongly from those of urban anthropogenic structures. Similarly, these types of structures are self-directed and arranged and prone to abrupt process-related changes and modifications. Thus, there are many reasons why planned urbanization forms in association with disturbances in ecosystem mobility. The current research highlights these variations in the context of social–cultural assessments within the Jhelum River watershed, which strongly expresses urbanization structure development mechanisms. The climate ranges from semi-arid to subhumid subtropical and sub-mountainous climate, though the extreme temperatures may rise as high as 49.4°C in June and may drop as low as ?1.6°C in January. The rainfall is low in the southwest and gradually increases towards the northeast, whereas the Salt Range is the major topographic feature that controls climatic impacts and promotes sustainable development. Cross-disciplinary methods are adopted in this investigation to assess the social–ecological landscape system (SELS) in terms of its mobility and degree of urbanization. The Sustainable Development Goals of the 2030 Agenda recognize that human livelihoods and the management of natural resources cannot be addressed separately. Investing in the sustainability of mountain communities and ecosystem conservation and protection will provide benefits for humanity as a whole. It pertains to the commensurate development of the SELS and its response to interruptions. Thus, a reliable SWOT analysis for management approaches is introduced that may enable the development of competencies that promote and lead towards rapid improvements in the sustainability of retrograde urban infrastructure, including watersheds.     

Optimization of biodiesel production from waste cooking oil using ion-exchange resins

Waste cooking oil is a potential substitution of refined vegetable oil for the production of biodiesel due to the low cost of raw material and for solving their disposal problem. In this study, optimization of esterification process of free fatty acids in artificially acidified soybean oil with oleic acid has been carried out using methanol as an agent and ion exchange resin as a heterogeneous catalyst. The esterification reaction has been investigated based on the mass balance of the developed model. The model has been validated against experimental data and effects of temperature and catalyst weight have been analyzed. Thereafter, optimization process has been fulfilled for two different objective functions as conversion of acid oil and benefit. Optimization results indicated that the maximum conversion of acid is 95.95%, which is achievable at 4.48-g catalyst loading and reaction temperature of 120°C. Maximum benefit was obtained as US$0.057 per batch of reaction at a catalyst amount of 1 g and temperature of 120°C.     

Monitoring of organic pollutants in marine environment by semipermeable membrane devices and mussels: accumulation and biochemical responses

This study involves the monitoring of organic pollutants using transplanted mussels (Mytilus galloprovincialis) as bioindicator organisms and semipermeable membrane devices (SPMDs) as passive samplers. Mussels and SPMDs were deployed to marinas, shipyards and shipbreaking yards on the coastal area of Turkey and retrieved after 60 days. Polycyclic aromatic hydrocarbons (PAH), polychlorinated biphenyls (PCB) and organochlorine pesticide (OCP) compounds were analysed with high-resolution GC-MS. Total PAH concentrations in SPMDs and mussels ranged from 200 to 4740 ng g sampler^?1 and from 7.0 to 1130 ng g^?1 in wet weight (ww). PCB and OCP concentrations in SPMDs changed between 0.04–200 and 4.0–26 ng g sampler^?1, respectively. The highest PCB (190 ng g^?1 ww) and OCP (200 ng g^?1 ww) concentrations in mussels were measured at shipyard stations. A strong correlation was observed between the PAH and PCB concentrations in SPMDs and mussels. Enzyme assays (acetylcholinesterase, ethoxyresorufin-O-deethylase, glutathione S-transferase, glutathion reductase and carboxylesterase activities) were performed as biomarkers to reveal the effects of pollution on the mussels. There was no clear relationship found between the enzyme levels and the pollutant concentrations in mussels. Integrated biomarker responses were calculated to interpret the overall effect of pollutants.

     

Supporting the risk management process with land information: a case study of Australia

It is frequently argued that, at the parcel level, 1 stakeholders are capable of and well supported in managing their land‐related risks. Yet, evidence from the contemporary Australian context suggests otherwise: numerous large‐scale disaster events have revealed that citizens are ill‐prepared to respond and recover adequately. This paper begins with the premise that information, specifically land information, could better support parcel‐level risk preparation, mitigation, response, and recovery. State land administration organisations in Australia primarily maintain this information and make it accessible. Land information is used regularly across all levels of government to support risk management activities; however, such application has not always occurred at the parcel and citizen level. Via a case study approach, this paper initially explores the land information available in Australia to stakeholders interested in parcel‐level detail, and then goes on to propose how the utilisation of parcel‐level land information could serve to enhance risk management practices.     

Factors affecting incentive dependency of residents to participate in e-waste recycling: a case study on adoption of e-waste reverse supply chain in Iran

Modern societies face a dilemma called electronic waste (e-waste). This waste, which may contaminate the soil or cause unwanted impacts on human health when treated improperly, is one of the fastest growing waste streams in developed as well as developing countries and has brought great environmental impacts. Developing countries like Iran also face this modern waste management challenge. In order for more appropriate disposal or, if possible, recycling of this waste, more attention has been paid to reverse logistics as the most appropriate way to manage them. The first and most important action to address e-waste and implementation of reverse logistics is to persuade residents to bring back their obsolete electronic products. This paper attempts to understand significant factors affecting residents’ incentive dependency to participate in e-waste recycling program. Socioeconomic and demographic information of different residents is discussed by means of logistic regression for the first time in Iran. The results show that about 58.7 % of residents will participate even if no incentive is given. Household income, household size, education, e-waste concern level, and marital status are the significant factors affecting the incentive dependency of respondents.     

A multivariate statistical analysis of the composition of rainwater near Cubatão, SP, Brazil

With the aim of estimating the chemical composition of bulk precipitation (wet + dry) in Cubat?o, rainwater samples were collected at several localities in the Cubat?o region from May 1984 to October 1985. The levels of some inorganic ions (Na+, Ca2+, K+, Mg2+, Cl-, SO4(2-), NH4+, PO4(3-)) were measured by atomic absorption spectrophotometry, turbidimetry and titration analysis. Correlation and Fisher discrimination indices, principal component and varimax loading and scores were determined in the multivariate statistical data treatment. The results showed that ionic concentrations in rainwater from Vila Parisi are significantly higher than those of Cubat?o Centro, Santos and Serra do Mar. The ionic compositions of the Vila Parisi rainwater seem to be mainly determined by local anthropogenic activities (industrial pollution). Besides the influence of this factor on water quality, there is also a natural oceanic contribution involving Cl- and Na+ at the other locations.     

Spatial analysis of drought severity and magnitude using the standardized precipitation index and streamflow drought index over the Upper Indus Basin,Pakistan

Environment, Development and Sustainability - Droughts are one of the multidimensional extreme events that negatively influence agriculture, water availability and food security in the World. The...