Detection and analysis of xenon isotopes for the comprehensive nuclear-test-ban treaty international monitoring system

The use of the xenon isotopes for detection of nuclear explosions is of great interest for monitoring compliance with the comprehensive nuclear-test-ban treaty (CTBT). Recently, the automated radioxenon sampler-analyzer (ARSA) was tested at the Institute for Atmospheric Radioactivity (IAR) in Freiburg, Germany to ascertain its use for the CTBT by comparing its results to laboratory-based analyses, determining its detection sensitivity and analyzing its results in light of historical xenon isotope levels and known reactor operations in the area. Xe-133 was detected nearly every day throughout the test at activity concentrations ranging between approximately 0.1 mBq/m3 to as high as 120 mBq/m3. Xe-133m and 135Xe were also detected occasionally during the test at concentrations of less than 1 to a few mBq/m3.     

WATER RESOURCES MANAGEMENT: INTERNATIONAL CHALLENGE AND OPPORTUNITIES1

The entire water resources field is not contemplated, although reference thereto will be registered. Water supply for potable and hygienic purposes will be presented as symbolic of the global issues confronting 4.8 billion people. Some two billion of these live in the so-called developing or less favored countries. They are either underserved or not served at all by utility systems of whatever grade. Targets for meeting their needs were exemplified by the international agencies in the International Water and Sanitation Decade of 1980-1990. Some successes are apparent, but, in general, hopes are not fulfilled. The pace of accomplishment is very slow. Constraints will be reviewed in some detail. Challenges for reducing these and increasing pace of installations are presented. The potential for a global public works program unprecedented in history is reviewed. Several issues will not be discussed in this paper. Their omission rests primarily upon the fact that their resolution is improbable for decades ahead, if ever. Economists have categorized water as any other economic commodity - and should always be subject to benefit-cost scrutiny. I do not share that view. People could well live without the telephone or the automobile, a destroyer. Without water, their survival is a matter of days. Cost-benefit seems unreal and singularly inappropriate under such circumstances. Secondly, the search for quantifying the health impact of safe water goes on forever. My view is that the results speak for themselves - while sturdy souls continue to seek out the exact correlation figure. Thirdly, the population explosion, although softened a bit, proceeds apace while I write. Lastly, the exposition herein is restricted to potable water and its associated sanitation aspects. Other major uses of water, obviously highly important, are not addressed.     

Elephants,people, parks and development: the case of the Luangwa Valley,Zambia

New ideas about conserving wildlife are emerging to compete with conventional national park policies. But methods of analyzing wildlife conservation problems in Africa are inadequate for the analysis of complex issues of policy. Much of the analysis of conservation policy attempts to be apolitical on issues charged with social conflict. Analyses are too often ahistorical when history can say a great deal about the origins of present-day ecological problems. Further-more, problems are commonly analyzed within narrow discilinary frameworks which predetermine the nature of conclusions and lead to professionally biased proposals. This case study of the Luangwa Valley, Zambia, is used to demonstrate a method which attempts to remedy these weaknesses,In the first part of the article we examine the role of the Luangwa National Parks in the context of the Zambian political economy, and identify social groups which compete for the resources of the national parks. Next we trace the historical origins of present-day ecological changes. These analyses lead toward a model of the Parks and some of their relationships with the national economy. We end with a proposal for communal use of wildlife which attempts to resolve some of the contradictions inherent in current policy.     

Spatial distribution of lead concentrations in urban surface soils of New Orleans, Louisiana USA

Immediately following hurricane Katrina concern was raised over the environmental impact of floodwaters on the city of New Orleans, especially in regard to human health. Several studies were conducted to determine the actual contaminant distribution throughout the city and surrounding wetlands by analyzing soil, sediment, and water for a variety of contaminants including organics, inorganics, and biologics. Preliminary investigations by The Institute of Environmental and Human Health at Texas Tech University concluded that soils and sediments contained pesticides, semi-volatiles, and metals, specifically arsenic, iron, and lead, at concentrations that could pose a significant risk to human health. Additional studies on New Orleans floodwaters revealed similar constituents as well as compounds commonly found in gasoline. More recently, it has been revealed that lead (Pb), arsenic, and vanadium are found intermittently throughout the city at concentrations greater than the human health soil screening levels (HHSSLs) of 400, 22 (non-cancer endpoint) and 390 μg/g, respectively. Of these, Pb appears to present the greatest exposure hazard to humans as a result of its extensive distribution in city soils. In this study, we spatially evaluated Pb concentrations across greater New Orleans surface soils. We established 128 sampling sites throughout New Orleans at approximately half-mile intervals. A soil sample was collected at each site and analyzed for Pb by ICP-AES. Soils from 19 (15%) of the sites had Pb concentrations exceeding the HHSSL threshold of 400 μg/g. It was determined that the highest concentrations of Pb were found in the south and west portions of the city. Pb concentrations found throughout New Orleans in this study were then incorporated into a geographic information system to create a spatial distribution model that can be further used to predict Pb exposure to humans in the city.     

Florida seagrass habitat evaluation: a comparative survey for chemical quality

Contaminant concentrations were determined for media associated with 13 Florida seagrass beds. Concentrations of 10 trace metals were more commonly detected in surface water, sediment and two seagrass species than PAHs, pesticides and PCBs. Concentrations of copper and arsenic in surface water exceeded Florida aquatic life criteria more frequently than other trace elements. Total organic carbon, mercury, chromium, zinc, total chlordane, total PAHs, total PCBs, DDD and DDE were significantly greater in seagrass-rooted sediments than adjacent non-vegetated sediments. Total DDT, DDD, DDE, total chlordane, arsenic, copper and nickel exceeded proposed sediment quality guidelines at six of 13 grass beds. Pesticides, PAHs, and PCBs were below detection in seagrass tissues. Mercury, cadmium, nickel, lead and silver were detected in 50% or more of the tissues for Thalassia testudinum (turtle grass) and Halodule wrightii (shoal grass). Spatial, interspecific and tissue differences were usually an order of magnitude or less.     

Microplastics in aquatic environment: characterization,ecotoxicological effect,implications for ecosystems and developments in South Africa

Microplastics are small-size plastic piece scales (particles <?5 mm) in sediments and waters which interact with environment and organisms by various means. Microplastics are becoming a universal ecological concern since they may be a source of hazardous chemicals to marine organisms and environments. Recent research suggests microplastics could enable the transfer of hydrophobic aquatic pollutants or chemical additives to biota. Even though microplastic presence and interactions are recently being detected in marine and freshwater systems, the fate of microplastics is still very poorly understood. This literature review is a summary of the sources and transport of microplastics, their interactions with toxic chemicals and the methodologies for chemical quantification and characterization of microplastics. The environmental outcome and impact of microplastics in wastewater treatment plants were assessed as well as the trends and update on microplastic research in the South African aquatic ecosystem.