Review on industrial wastewater energy sources and carbon emission reduction: towards a clean production

This review provides an innovative approach of treating palm oil mill effluent (POME) from open pond and closed anaerobic sludge reactor for generation of green energy in the form of biogas containing methane. Improper techniques for the treatment and management of POME produce hazards to people and contribute to global warming. In all over the world, the total crude oil palm production in the countries like Malaysia, Indonesia, Africa, Latin America, Asian countries, Solomons and other were around 51, 31, 7, 6, 3, 2 and 1% compared with soya 41.8% and coconut 3.48%, respectively. In the year 2014–15, Malaysia generated at least 87.8 million tonnes of palm effluent per year. Various studies reveal that about 80% of palm effluent is disposed off partially treated in open dumps. The generated certified emission reductions (CERs) estimated and favoured the treatment of POME in anaerobic reactor by replacing open lagoon of aerobic system for cleaner production. The clean development mechanism (CDM) encourages the utilisation of upflow anaerobic sludge blanket reactors for POME treatment and methane capture to earn CER credits as a source of revenue.     

Residues of endosulfan in cotton growing area of Vehari,Pakistan: an assessment of knowledge and awareness of pesticide use and health risks

This study is based on self-reported information collected from selected farmers of Vehari District, Punjab, Pakistan, to determine their technical knowledge and awareness about pesticide use and associated environmental and health risks. Moreover, soil contamination by routinely used persistent organochlorine pesticide, endosulfan, was also evaluated. Survey data revealed very low literacy rate (on an average 9th grade education) and technical knowledge (almost missing) of the farmers in Vehari District. The farmers are unable to fully read and understand the instructions about the use of pesticide marked on the containers. They are not fully aware of pesticide persistence and toxicity (73%), unable to identify cotton pests and diseases (86%), and do not know which crop to grow in cotton adjacent fields (100%). Data also revealed that the farmers (100%) do not follow safety measure during pesticide application and are unaware of pesticide toxicity symptoms in human as well as the basic first-aid practices (89%).

Poor literacy rate and lack of technical knowledge of farmers in Vehari regarding pesticide use and handling are posing serious environmental and health risks among the local inhabitants, particularly among farmers. Soil analysis results showed that concentration of α- and β-endosulfan ranged from 0–14 to 0–14.64 μg/mg, respectively. Principal component analysis showed that soil organic matter is the key soil parameter controlling the occurrence and fate of endosulfan under sandy loam soil conditions of Vehari District. There is a serious need of improving technical and environmental knowledge of farmer about pesticide risks on human health in the studied area, in particular, and the entire country in general. Findings are of great use for policymaking in Pakistan to minimize pesticide risks in Pakistan.

     

Ameliorative effect of zinc oxide nanoparticles against potassium bromate-mediated toxicity in Swiss albino rats

Environmental Science and Pollution Research - Potassium bromate (PB) is a commonly used food additive, a prominent water disinfection by-product, and a class IIB carcinogen. It exerts a various...     

Transformation of sulfaquinoxaline by chlorine and UV light in water: kinetics and by-product identification

Sulfaquinoxaline (SQX) is an antimicrobial of the sulfonamide class, frequently detected at low levels in drinking and surface water as organic micropollutant. The main goal of the present study is the evaluation of SQX reactivity during chlorination and UV irradiations which are two processes mainly used in water treatment plants. The SQX transformation by chlorination and UV lights (254 nm) was investigated in purified water at common conditions used for water disinfection (pH =?7.2, temperature =?25 °C, [chlorine] =?3 mg L^?1). The result shows a slow degradation of SQX during photolysis compared with chlorination process. Kinetic studies that fitted a fluence-based first-order kinetic model were used to determine the kinetic constants of SQX degradation; they were equal to 0.7?×?10^?4 and 0.7?×?10^?2 s^?1corresponding to the half time lives of 162 and 1.64 min during photolysis and chlorination, respectively. In the second step, seven by-products were generated during a chlorination and photo-transformation of SQX and identified using liquid chromatography with electrospray ionization and tandem mass spectrometry (MS-MS). SO₂ extrusion and direct decomposition were the common degradation pathway during photolysis and chlorination. Hydroxylation and isomerization were observed during photodegradation only while electrophilic substitution was observed during chlorination process.     

Crosslinked Polyacrylamide Composite Hydrogels Impregnated with Fly Ash: Synthesis,Characterization and Their Application as Fractures Sealant for High Water Producing Zones in Oil and Gas Wells

Polymeric hydrogels are designed to serve many purposes in various fields of human endeavor. Herein, crosslinked polyacrylamide (PAM) composite hydrogels impregnated with coal fly ash (CFA) were synthesized, characterized and tested as fracture sealing agents in high water producing permeable zones in petroleum industry. The concept of utilizing CFA as an inorganic additive in the matrix of hydrogel emanates from the fact that CFA constitutes majorly alumina and silica. Both chemical oxides can induce the CFA to promote the inherent properties of hydrogel. Polyethyleneimine (PEI) was chosen as the crosslinking agent. Neat PAM/PEI hydrogel and PAM/PEI–CFA hydrogels at various CFA loadings (0.5, 1 and 2 wt%) were synthesized via a transamidation reaction pathway. The developed hydrogels were characterized by hybrid rheometer, FTIR, SEM and XRD instruments. Rheological results reveal that the PAM/PEI–CFA composite hydrogels embedded with various CFA quantities were more elastic than the neat PAM/PEI hydrogel, indicating the dispersion and reinforcing effect of CFA. The functional groups of these hydrogels were confirmed by the FTIR while SEM analysis show that the surface micrographs of neat PAM/PEI hydrogel and PAM/PEI–CFA1 hydrogel were porous in several regions. In contrast, the micrographs of PAM/PEI–CFA2 and PAM/PEI–CFA3 hydrogels demonstrated dense and “net-like” structural patterns. Further, XRD analysis revealed that CFA impregnation has a significant effect on the bulk structural properties of the fabricated hydrogels. The swelling rates of these hydrogels were determined by the gravimetric method and their diffusion parameters evaluated using Fickian diffusion and Schott-order kinetic models. Efficacy of the PAM/PEI–CFA composite hydrogel as fractures sealant in oil and gas wells was conducted at a typical reservoir temperature, 90 °C, and the outcome demonstrated considerable sealing potency.     

Multivariate analysis and geochemical approach for assessment of metal pollution state in sediment cores

Environmental Science and Pollution Research - Vertical distribution of metals (Cu, Zn, Cr, Fe, Mn, Pb, Ni, Cd, and Li) in four sediment core samples (C1, C2, C3, and C4) from Anzali international...     

AutoRAPID: A Model for Prompt Streamflow Estimation and Flood Inundation Mapping over Regional to Continental Extents

This article couples two existing models to quickly generate flow and flood‐inundation estimates at high resolutions over large spatial extents for use in emergency response situations. Input data are gridded runoff values from a climate model, which are used by the Routing Application for Parallel computatIon of Discharge (RAPID) model to simulate flow rates within a vector river network. Peak flows in each river reach are then supplied to the AutoRoute model, which produces raster flood inundation maps. The coupled tool (AutoRAPID) is tested for the June 2008 floods in the Midwest and the April‐June 2011 floods in the Mississippi Delta. RAPID was implemented from 2005 to 2014 for the entire Mississippi River Basin (1.2 million river reaches) in approximately 45 min. Discretizing a 230,000‐km² area in the Midwest and a 109,500‐km² area in the Mississippi Delta into thirty‐nine 1° by 1° tiles, AutoRoute simulated a high‐resolution (~10 m) flood inundation map in 20 min for each tile. The hydrographs simulated by RAPID are found to perform better in reaches without influences from unrepresented dams and without backwater effects. Flood inundation maps using the RAPID peak flows vary in accuracy with F‐statistic values between 38.1 and 90.9%. Better performance is observed in regions with more accurate peak flows from RAPID and moderate to high topographic relief.     

Occurrence of phthalates in aquatic environment and their removal during wastewater treatment processes: a review

Phthalates are plasticizers and are concerned environmental endocrine-disrupting compounds. Due to their extensive usage in plastic manufacturing and personal care products as well as the potential to leach out from these products, phthalates have been detected in various aquatic environments including drinking water, groundwater, surface water, and wastewater. The primary source of their environmental occurrence is the discharge of phthalate-laden wastewater and sludge. This review focuses on recent knowledge on the occurrence of phthalate in different aquatic environments and their fate in conventional and advanced wastewater treatment processes. This review also summarizes recent advances in biological removal and degradation mechanisms of phthalates, identifies knowledge gaps, and suggests future research directions.