Effects of sewage sludge amendments on pesticide sorption and leaching through undisturbed Mediterranean soils

The Gharb region in Morocco is an important agricultural zone where soils receive pesticide treatments and organic amendments to increase yields. The groundwater aquifer in the Gharb region is relatively shallow and thus vulnerable. The objective of this work was to study the influence of organic amendments on diuron, cyhalofop-butyl and procymidone leaching through undisturbed soil columns. Two soils were sampled from the Gharb region, a Dehs (sandy soil) and a R’mel (loamy clay soil). Following elution (124.5 mm), the amount of pesticide residues in the leachates of the sandy soil (0.06–0.21 %) was lower than in those of the loamy clay soil (0.20–0.36 %), which was probably due to preferential flow through the loamy clay soil. The amount of procymidone leached through the amended soil columns was greater than the control for the sandy soil only. The organic amendments did not significantly influence diuron and cyhalofop-butyl leaching in either of the soils. The application of organic amendments affected the amounts of dissolved organic matter (DOM) eluted and thus pesticide leaching as a function of soil-type. Nevertheless, in some case, the formation of pesticide-DOM complexes appeared to promote pesticide leaching, thus increasing groundwater contamination risks.     

Cluster analysis and quality assessment of logged water at an irrigation project, eastern Saudi Arabia

A multivariate statistical technique, cluster analysis, was used to assess the logged surface water quality at an irrigation project at Al-Fadhley, Eastern Province, Saudi Arabia. The principal idea behind using the technique was to utilize all available hydrochemical variables in the quality assessment including trace elements and other ions which are not considered in conventional techniques for water quality assessments like Stiff and Piper diagrams. Furthermore, the area belongs to an irrigation project where water contamination associated with the use of fertilizers, insecticides and pesticides is expected. This quality assessment study was carried out on a total of 34 surface/logged water samples. To gain a greater insight in terms of the seasonal variation of water quality, 17 samples were collected from both summer and winter seasons. The collected samples were analyzed for a total of 23 water quality parameters including pH, TDS, conductivity, alkalinity, sulfate, chloride, bicarbonate, nitrate, phosphate, bromide, fluoride, calcium, magnesium, sodium, potassium, arsenic, boron, copper, cobalt, iron, lithium, manganese, molybdenum, nickel, selenium, mercury and zinc. Cluster analysis in both Q and R modes was used. Q-mode analysis resulted in three distinct water types for both the summer and winter seasons. Q-mode analysis also showed the spatial as well as temporal variation in water quality. R-mode cluster analysis led to the conclusion that there are two major sources of contamination for the surface/shallow groundwater in the area: fertilizers, micronutrients, pesticides, and insecticides used in agricultural activities, and non-point natural sources.     

Nutrient-impregnated charcoal: an environmentally friendly slow-release fertilizer

The widespread contamination of surface and ground water quality from the heavy use of fertilizer in modern agriculture is the current concern. Therefore, this study was carried out to develop a slow-release fertilizer using charcoal. The morphology of the charcoal impregnated fertilizer was investigated by scanning electron microscopy (SEM). This study also evaluated the release patterns of N, P, and K from impregnated charcoal using a simulated soil solution and distilled water as leaching solutions. The patterns of N, P, and K releases were examined in both static and continuous-flow conditions for 360 h. Releases of N, P, and K from impregnated charcoal were found to be slow and steady. However, the release trends of N, P, and K were higher in soil solution than distilled water under both the above conditions. Dissolution occurred when N, P, and K were released in the above leached solutions. As a result, the fertilizer impregnated charcoal could be developed as slow-release type fertilizer to minimize the contamination.     

Correction to: Ecotoxicological assessment of oil-based paint using three-dimensional multi-species bio-testing model: pre- and post-bioremediation analysis

Environmental Science and Pollution Research - The original publication of this paper contains a mistake.     

Laboratory and field evaluation of real-time and near real-time PM2.5 smoke monitors

ABSTRACT

Increases in large wildfire frequency and intensity and a longer fire season in the western United States are resulting in a significant increase in air pollution, including concentrations of PM_2.5 (particulate matter <2.5 µm in aerodynamic diameter) that pose significant health risks to nearby communities. During wildfires, government agencies monitor PM_2.5 mass concentrations providing information and actions needed to protect affected communities; this requires continuously measuring instruments. This study assessed the performance of seven candidate instruments: (1) Met One Environmental beta attenuation monitor (EBAM), (2) Met One ES model 642 (ES642), (3) Grimm Environmental Dust Monitor 164 (EDM), (4) Thermo ADR 1500 (ADR), (5) TSI DRX model 8543 (DRX), (6) Dylos 1700 (Dylos), and (7) Purple Air II (PA-II) in comparison with a BAM 1020 (BAM) reference instrument. With the exception of the EBAM, all candidates use light scattering to determine PM_2.5 mass concentrations. Our comparison study included environmental chamber and field components, with two of each candidate instrument operating next to the reference instrument. The chamber component involved 6 days of comparisons for biomass combustion emissions. The field component involved operating all instruments in an air monitoring station for 39.5 days with hourly average relative humidity (RH) ranging from 19% to 98%. Goals were to assess instrument precision and accuracy and effects of RH, elemental carbon (EC), and organic carbon (OC) concentrations. All replicate candidate instruments showed high hourly correlations (R² ≥ 0.80) and higher daily average correlations (R² ≥ 0.90), where all instruments correlated well (R² ≥ 0.80) with the reference. The DRX and Purple Air overestimated PM_2.5 mass concentrations by a factor of ~two. Differences between candidates and reference were more pronounced at higher PM_2.5 concentrations. All optical instruments were affected by high RH and by the EC/OC ratio. Equations to convert candidate instruments data to FEM BAM type data are provided to enhance the usability of data from candidate instruments.

Implications: This study tested the performance of seven candidate PM_2.5 mass concentration measuring instruments in two settings - environmental chamber and field. The instruments were tested to determine their suitability for use during biomass combustion events and the effects of RH, PM mass concentrations, and concentrations of EC and OC on their performance. The accuracy and precision of each monitor and effect of RH, PM concentration, EC and OC concentrations are varied. The data show that most of these candidate instruments are suitable for measuring PM_2.5 concentration during biomass combustions with a proper correction factor for each instrument type.     

Determination of hierarchical relationships among sustainable development goals using interpretive structural modeling

This paper analyses the complex interactions among the seventeen sustainable development goals (SDGs) and presents them in a hierarchical framework using interpretive structural modeling technique. The driving and dependence powers of each of these goals have been ascertained to help the developing and least developed countries improve their strategic orientation for a particular goal within a given time frame. This would also help them in prioritizing their resource allocations on a specific SDG by focusing on its hierarchical ranking on one hand and driving and dependence powers on the other.     

Advanced microbial fuel cell for waste water treatment—a review

Environmental Science and Pollution Research - Petroleum, coal, and natural gas reservoir were depleting continuously due to an increase in industrialization, which enforced study to identify...     

Green synthesis,characterization, application and functionality of nitrogen-doped MgO/graphene nanocomposite

Environmental Science and Pollution Research - A facile, feasible, and green synthesis via an electrochemical exfoliation process was applied to synthesize nitrogen-doped MgO/graphene nanocomposite...     

Trace element contamination in the mine-affected stream sediments of Oued Rarai in north-western Tunisia: a river basin scale assessment

Environmental Geochemistry and Health - High-quality and accurate environmental investigations are essential for the evaluation of contamination and subsequent decision-making processes. A...     

Sustainable technologies for on-site domestic wastewater treatment: a review with technical approach

Environment, Development and Sustainability - The rapid population growth has rendered the centralized sewerage systems a non-realistic option in sparsely populated areas, particularly in...