Determination of antimony in human blood with inductively coupled plasma-mass spectrometry

A method is presented for the determination of antimony in whole human blood samples with an ICP-MS instrument using a quadrupole mass analyzer. A nitric acid/hydrogen peroxide open digestion procedure was employed for the blood sample treatment and preparation for analysis. The precision and accuracy of the method were evaluated by analyzing several Seronorm trace elements whole blood reference materials. The precision of the method at various antimony levels was better than 4% RSD and the recovery was greater than 92% at all levels. The detection limit, calculated as three times the standard deviation of the blank (3sigma, n= 12), was 0.03 microg L(-1). The method was successfully applied for the determination of antimony in blood samples from school children in rural areas of Kwazulu/Natal, South Africa and adults from Dearborn, Michigan. Blood antimony levels ranged from <0.03 to 3.82 microg L(-1) in children and 1.40 to 4.35 microg L(-1) for adults.     

Physiopathology and effectiveness of therapeutic vaccines against human papillomavirus

Environmental Science and Pollution Research - Human papillomavirus (HPV) is a well-known sexually transmitted disorder globally. Human papillomavirus (HPV) is the 3rd most common cancer that...     

REAL-TIME SOIL WATER MONITORING FOR OPTIMUM WATER MANAGEMENT1

Abstract: Efficient water resource management is one of the most important policy issues facing agriculture in Hawaii in the years ahead. Soil water sensors, multisensor capacitance probes (MCP), have been successfully used for different water management projects. These MCPs monitor water content at multiple depths and at various locations in real-time. The objectives of this study were to determine the effect of water content on field soil bulk density of Wahiawa silty clay tropical soil; measure field saturated hydraulic conductivity of this tropical soil: calibrate MCP system for this soil: and monitor and evaluate real-time soil water content variations under a tomato crop using the calibrated MCP system. Sensor calibration was conducted under laboratory conditions. Soil bulk density at different water contents and saturated hydraulic conductivity were measured on the field. Bulk density increased with increasing water content: there was a 30 percent bulk density increase as a result of 0.25 cm³ cm^-3 water content variation. Compared with the manufacturer's calibration, site specific laboratory calibration of MCP gave a more accurate determination of soil water. Field determined saturated hydraulic conductivity was higher than laboratory determined values reported in the literature for the same soil type. Real-time soil water content monitoring within the root zone showed substantial variations due to water input (irrigation and rainfall) and water output (evapotranspiration and deep percolations). However, water content variations were much further reduced in the soil layer below the root zone.     

Chemical aspects of mass spawning in corals. I. Sperm-attractant molecules in the eggs of the scleractinian coral Montipora digitata

This paper provides the first evidence for sperm chemotaxis in the Scleractinia. Montipora digitata Dana, 1845 (Scleractinia: Coelenterata) is a hermaphroditic coral which reproduces bi-annually, releasing egg-sperm bundles during the mass spawning at Magnetic Island (19°10S; 146°52E) in late spring-early summer, and autumn each year. The buoyant egg-sperm bundles float to the surface where they break apart, releasing eggs and sperm into the ocean. Fertilisation occurs after 30 min. Unfertilized eggs were collected, washed free of sperm, and freeze-dried. The eggs were extracted with dichloromethane, fractionated by chromatography on silica gel, and the fractions assayed for their ability to attract M. digitata sperm. The active fraction was further fractionated by high-performance liquid chromatography, resulting in the isolation of three highly unsaturated fatty alcohols: (1) dodeca-2,4-diynol; (2) tetradec-13-ene-2,4-diynol; (3) (14Z)-heptadeca-14,16-diene-2,4-diynol. Of these three compounds, only Compound 1 attracted sperm of M. digitata. Synthetic Compound 1, produced from simple precursors by known reactions, possessed sperm-attracting activity comparable to the naturally derived attractant. Preliminary experiments suggest that the natural mixture of Compounds 1, 2 and 3 in the ratio 1:4:9 is more effective in attracting sperm from M. digitata than sperm from other Montipora species. Sperm attractants may act to reduce the incidence of hybridisation between different species of Montipora.     

Evaluation of poly-aromatic hydrocarbons (PAHs) in the aquatic species of Suez Gulf water along El-Sokhna area to the Suez refineries

The Egyptian Red Sea environment especially along El-Sokhna area to the Suez refineries (Suez) is severely contaminated with organic compounds, as well as overfishing. This may be well contributory to recent serious declines in fish stocks. Fish embryos are also particularly vulnerable to oil exposure, even at extremely low concentrations of less than one part per billion. Consequently, even traces of oil pollution at levels often considered safe for wildlife can cause severe damage to fish. Sixteen polycyclic aromatic hydrocarbons (PAHs) were investigated in ten fish species of aquatic species by high performance liquid chromatography (HPLC). The compositions of PAHs determined in all samples were measured in order to use them as chemical markers for identifying different sources of PAH pollutants in the studied region. The total content of these16 PAHs ranged from 399.616 up to 67,631.779 ng/g wet weight. The data show that these values are considered to be alarmingly high enough to cause lethal toxicity effect by accumulation. All studied aquatic species samples are characterized by relatively high concentrations of the six-membered ring PAHs. The origin of PAHs in the collected samples is either petrogenic, biogenic, or mixed petrogenic and biogenic.     

Study of non-revenue water status and enforcement measures to reduce water loss: case study in villages of Kermanshah Province of Iran

In this study, the volume and the cash value of water loss, and reduction of water loss as a result of enforcement action during 2011–2013 in the drinking water network of villages in Kermanshah Province, Iran, have been investigated. Date collected by referring to the different parts of rural water and waste water company of Kermanshah Province and checklist were completed. The study showed the volume of produced water and sold water has increased and the water loss percentage has decreased. High cost of water production compared to revenue of sold water and water loss resulted in significant detriments in terms of the water production costs. Water loss level decreased from 33% to 30% as result of measures taken to reduce water loss but, it is still 15% higher than the world average level. Also the reduction in number of water resources and increase in the number and volume of reservoirs indicates a lack of water and a growing need. As result of high water loss, waste of costs in the contrast of water production cost and also because physical water loss accounts for most of the water loss of villages, necessary measures can be effective in reducing loss and have economic justification.     

Petroleum residues in the waters of the Shatt al-Arab River and the northwest region of the Arabian Gulf

During April 1980, water samples were collected from 12 sites in the Shatt al-Arab River and its estuary in the northwest region of the Arabian Gulf. The samples were extracted and the concentration of petroleum hydrocarbons were determined spectrofluorometrically, in order to provide information on the background values of oil generally present in these waters. Total hydrocarbon concentrations of these samples ranged from 2.7 to 86.7 μgL^?1 expressed in terms of Kuwait crude oil equivalents. The highest concentrations were found at sites in the Shatt al-Arab River that are near port areas.     

Size fraction of hazardous particulate matter governing the respiratory deposition and inhalation risk in the highly polluted city Delhi

Environmental Science and Pollution Research - Delhi has been identified as one of the highly polluted cities in the world and recently associated with the highest population weighted PM2.5...     

Satellite-based monitoring of meteorological drought over different regions of Iran: application of the CHIRPS precipitation product

Environmental Science and Pollution Research - In the present study, the spatiotemporal evaluation of the Climate Hazards Group InfraRed Precipitation with Station (CHIRPS) satellite precipitation...