纳滤膜在洁霉素废水浓缩分离中的应用

考察了DLNF₂-30(0.24m²)、MPS-44(1.4m²) 2种卷式纳滤膜串联运行时对洁霉素废水中残余洁霉素的浓缩性能.实验结果表明,当进水中洁霉素浓度为200mg/L 时,对废水浓缩10～20倍后洁霉素浓度可浓缩至2000mg/L 以上,满足回用要求,浓缩时间为60～70h.在浓缩过程中,COD_Cr的截留率始终高于80%,洁霉素截留率始终高于90%,且洁霉素的回收率高于90%.     

Kinetic effect of humic acid on alachlor degradation by anodic Fenton treatment

Contamination of water often results from the heavy use of agricultural chemicals, and the disposal of aqueous pesticide waste is a concern. Anodic Fenton treatment (AFT) has been shown to be a successful remediation method for pesticides in solution, but the effect of soil on the degradation kinetics of pesticides using this method has not been determined. The purpose of this study was to study the effect of humic acid, as a soil surrogate, on the degradation kinetics of alachlor [2-chloro-N-(2,6-diethylphenyl-N-(methoxymethyl) acetamide], a heavily used herbicide that has been studied in pure aqueous solution by AFT. The AFT consists of a controlled constant delivery of Fenton reagents, using an electrochemical half-cell to deliver ferrous iron. Alachlor was quickly degraded by AFT, and the kinetics were found to obey the previously developed AFT model well. Degradation of alachlor by AFT in humic acid slurry showed that when the amount of humic acid was increased, alachlor degradation was significantly slowed down and the degradation kinetics were shifted from the AFT model to a first-order model. Further experimentation indicated that humic acid not only competes with alachlor for hydroxyl radicals, reducing the degradation rate of the target compound, but also buffers the slurry at near neutral pH, blocking regeneration of ferrous ion from ferric ion and subsequently shifting the kinetics to first order. Degradation of several other pesticides in humic acid slurry also followed first-order kinetics. These results imply that higher concentrations of Fenton reagents will be required for soil remediation.     

Do the designated drivers of college students stay sober?

PROBLEM: By numerous accounts, alcohol abuse is considered the number one drug problem facing young people today. Alcohol consumption and its negative consequences, especially those due to drinking and driving, continue to have devastating effects on the college student population. METHOD: This field study examined the blood alcohol concentration (BAC) levels of male and female designated drivers (DD), non-DD, and their respective passengers as they were leaving drinking establishments in a university town. Also investigated were the effects of group size and gender on DD use. RESULTS: A 2 Gender x 2 Driver type (DD vs. non-DD) analysis of variance (ANOVA) for BAC indicated significant main effects for Gender and Driver type, with higher BAC for men and non-DD (p's<.001). A significant Gender x Driver type interaction (p<.05) was primarily due to female DD having lower BAC than male DD. In addition, larger groups were more likely to have a DD. IMPACT ON INDUSTRY: Results indicate that the success of DD programs may be influenced by group size and a DD's gender. While larger groups are more likely to have a DD, students riding home with a male DD may still be at risk for the negative consequences of drunk driving.     

Environmental impact assessment in flanders,belgium: An evaluation of the administrative procedure

Two years of experience with EIA in Flanders (northern Belgium) was evaluated in order to gain perspective on the effectiveness of the administrative procedure. The four essential characteristics of the EIA procedure that were evaluated are: completeness, open and public character, objectivity, and verifiability. Representatives of all parties involved in the EIA procedure were interviewed. The result of the evaluation is a list of major problems with EIA. Recommendations for a more efficient procedure are suggested at a time when a proposal for a new, comprehensive, and permanent EIA decree is being discussed. The evaluation of the administrative procedure for EIA in Flanders shows that several vital characteristics of the EIA procedure are lacking. This reduces the obligatory and open nature of the process, resulting in insufficient guarantees that the environment receives the altention it deserves during the decision-making process.     

Landscapes for tomorrow

Seven different landscapes that might realistically represent the Yorkshire Dales National Park in the lifetime of the present generation were created out of detailed interviews with policy managers, landowners and farmers. These landscapes were imaged in the form of water colour paintings, then incorporated with appropriate explanatory commentary into a large graphic display, a video sequence, a floor game and a leaflet. The interpretive material was taken to the public as a touring exhibition, travelling around the National Park over two consecutive summers. The exhibition was designed to be participatory: its purpose to discover how far people could grasp the processes leading to landscape change, become aware of why these forces were happening and become sufficiently concerned for the future to participate in the creation of landscape design of their choice. The results revealed that the approach experimented with was successful in meeting its aims, that those less conversant with the issues were more influenced than those already familiar with some of the causes of change and that participatory interpretation can be a highly educative and enjoyable experience.     

LIMITATIONS OF CONCEPTS USED TO DETERMINE INSTREAM FLOW REQUIREMENTS FOR HABITAT MAINTENANCE1

ABSTRACT: Today most rivers are not freely flowing but are highly regulated to meet both human and wildlife needs. Several models allow the determination of instream flows that are needed to meet wildlife demands. However, these models are based on assumptions that limit their applicability to certain types of rivers. While these limitations do not preclude the use of the models on other types of rivers, like the Platte River in Nebraska, their limitations should be considered and accommodated by those making instream flow planning and management decisions. Other factors affecting channel morphology and its associated wildlife habitat, such as threshold values and vegetation are not adequately considered by current concepts. If rivers are to be managed to provide wildlife habitat, these factors will have to be addressed.     

Characterization of Infiltration Rates from Landfills: Supporting Groundwater Modeling Efforts

The purpose of this paper is to review the literature to characterize infiltration rates from landfill liners to support groundwater modeling efforts. The focus of this investigation was on collecting studies that describe the performance of liners 'as installed' or 'as operated'. This document reviews the state of the science and practice on the infiltration rate through compacted clay liner (CCL) for 149 sites and geosynthetic clay liner (GCL) for 1 site. In addition, it reviews the leakage rate through geomembrane (GM) liners and composite liners for 259 sites. For compacted clay liners (CCL), there was limited information on infiltration rates (i.e., only 9 sites reported infiltration rates.), thus, it was difficult to develop a national distribution. The field hydraulic conductivities for natural clay liners range from 1 x 10(-9) cm s(-1) to 1 x 10(-4) cm s(-1), with an average of 6.5 x 10(-8) cm s(-1). There was limited information on geosynthetic clay liner. For composite lined and geomembrane systems, the leak detection system flow rates were utilized. The average monthly flow rate for composite liners ranged from 0-32 lphd for geomembrane and GCL systems to 0 to 1410 lphd for geomembrane and CCL systems. The increased infiltration for the geomembrane and CCL system may be attributed to consolidation water from the clay.     

Chronosequence analysis of two enclosure management strategies in degraded rangeland of semi-arid Kenya

The establishment of enclosures has become an important measure to combat land degradation in many of the world's semi-arid rangelands. In view of the increased pressure exerted by this land reclamation strategy on the neighbouring agricultural lands, knowledge of the time required for restoring vegetation cover and soil health, and of the potential positive impact of an adapted management strategy, is highly required. This paper assesses the vegetation and soil rehabilitation in a 23-year chronosequence of two different enclosure management types. In the severely degraded, semi-arid Njemps Flats plain of the Lake Baringo Basin in Kenya communal enclosures characterised by high quality inputs and strict control, and private enclosures managed by individual farmers, were installed since the 1980s. Six communal enclosures (3–17 years since establishment) and six private enclosures (13–23 years since establishment) were selected. Vegetation cover was estimated along three 50 m transects set within each enclosure and in the adjacent open grazing area using the point-to-line transect method. Five 0.5 m² quadrats systematically placed alongside each transect were sampled for herbaceous standing biomass and topsoil physical, chemical and biological analyses. Grass cover and herbaceous biomass production proved to be the most responsive biotic parameters under both management types, whereas the recovery of the forbs was unsuccessful. Under communal management, the biomass production fully recovered up to its optimal level as recorded in the neighbouring nature reserves. Within private enclosures however, the adopted management strategies seriously restricted biomass production to a significantly lower level. Soil quality generally recovered more slowly with time. Significant improvements compared to the open rangeland were recorded in topsoil bulk density, organic C and total N stocks, and microbial biomass C and N stocks of the communal enclosures. Unlike the communal enclosures, only topsoil bulk density and the microbial biomass C stock showed a significant difference in the private enclosures. With respect to C and total N stocks, and the microbial biomass N a non-significant improving trend was recorded. The level of chemical and biological soil quality obtained under both management types is still low and draws the attention to the importance of careful monitoring of grazing and grass cutting activities under both enclosure management strategies. The chronosequences further highlight the potential of some well-managed private enclosures, whereas intrinsic soil properties such as high alkalinity, as well as changes in management, limit the rehabilitation of some other private as well as communal enclosures.     

Survival Model for Foot and Leg High Rate Axial Impact Injury Data

Objectives: Understanding how lower extremity injuries from automotive intrusion and underbody blast (UBB) differ is of key importance when determining whether automotive injury criteria can be applied to blast rate scenarios. This article provides a review of existing injury risk analyses and outlines an approach to improve injury prediction for an expanded range of loading rates. This analysis will address issues with existing injury risk functions including inaccuracies due to inertial and potential viscous resistance at higher loading rates.

Methods: This survival analysis attempts to minimize these errors by considering injury location statistics and a predictor variable selection process dependent upon failure mechanisms of bone. Distribution of foot/ankle/leg injuries induced by axial impact loading at rates characteristic of UBB as well as automotive intrusion was studied and calcaneus injuries were found to be the most common injury; thus, footplate force was chosen as the main predictor variable because of its proximity to injury location to prevent inaccuracies associated with inertial differences due to loading rate. A survival analysis was then performed with age, sex, dorsiflexion angle, and mass as covariates. This statistical analysis uses data from previous axial postmortem human surrogate (PMHS) component leg tests to provide perspectives on how proximal boundary conditions and loading rate affect injury probability in the foot/ankle/leg (n = 82).

Results: Tibia force-at-fracture proved to be up to 20% inaccurate in previous analyses because of viscous resistance and inertial effects within the data set used, suggesting that previous injury criteria are accurate only for specific rates of loading and boundary conditions. The statistical model presented in this article predicts 50% probability of injury for a plantar force of 10.2 kN for a 50th percentile male with a neutral ankle position. Force rate was found to be an insignificant covariate because of the limited range of loading rate differences within the data set; however, compensation for inertial effects caused by measuring the force-at-fracture in a location closer to expected injury location improved the model's predictive capabilities for the entire data set.

Conclusions: This study provides better injury prediction capabilities for both automotive and blast rates because of reduced sensitivity to inertial effects and tibia–fibula load sharing. Further, a framework is provided for future injury criteria generation for high rate loading scenarios. This analysis also suggests key improvements to be made to existing anthropomorphic test device (ATD) lower extremities to provide accurate injury prediction for high rate applications such as UBB.