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61.
Yoshiaki Mitsui Noriyuki Imada Hirofumi Kikkawa Atsushi Katagawa 《International Journal of Greenhouse Gas Control》2011
Oxy-fuel combustion systems have been under development to reduce CO2 emissions from coal-fired power plants. In oxy-fuel combustion system, Hg in the flue gas causes corrosion in CO2 purification and compression units. Also, SO3 in the flue gas corrodes the equipment and ducts of oxy-fuel combustion system. Therefore, Hg and SO3 need to be removed.Babcock-Hitachi conducted tests using a 1.5 MWth Combustion & Air Quality Control System (AQCS) test facility which consists of oxygen supply unit, furnace, Selective Catalytic Reduction (SCR) catalyst, Clean Energy Recuperator (CER), Dry Electrostatic Precipitator (DESP), flue gas recirculation system, Wet Flue Gas Desulfurization (WFGD), and CO2 Compression and Purification Unit (CPU). In both cases of air and oxy-fuel combustion, the Hg removal across the DESP could be improved, and SO3 concentration at the DESP outlet could be reduced to less than 1 ppm by installing a CER upstream of the DESP and reducing the gas temperature at the DESP inlet. Hg was not dissolved in the drain recovered from CO2 compressor, and may be adsorbed at an inner part of CO2 compressor. This indicated that Hg needs to be removed at a location upstream of the CO2 compressor to prevent corrosion of the compressor. 相似文献
62.
Aikawa M Hiraki T Tamaki M Kasahara M Kondo A Uno I Mukai H Shimizu A Murano K 《Environmental monitoring and assessment》2006,122(1-3):61-79
An intensive field survey, with 6-h measurement intervals, of concentrations of chemical species in particulate matter and gaseous compounds was carried out at coastal sites on the Sea of Japan during winter. The concentration variation of SO2(g) and HNO3(g) were well correlated, whereas the NH3(g) concentration variation had no correlation with those of SO2(g) and HNO3(g). The NH4
+ (p)/non-sea-salt- (nss-)SO4
2 −(p) ratio in particulate matter was mainly affected by the location of the sampling site. One or more concentration peaks of nss-Ca2 + for survey period were observed. Backward trajectories analyses for the highest nss-Ca2 + concentration peaks showed some inconsistency in pathways. We consider that insufficient mixing of the atmosphere and/or insufficient time for the transported air pollutants to react with those discharged locally are the most likely explanations for the discrepancies between the measured products [HNO3][NH3] and the calculated values. 相似文献
63.
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65.
Correlations between flash points and vapor pressures at 25 °C for pure organic compounds were investigated. It was found that classification of organic compounds according to their chemical-structural characteristics (e.g., functional groups) was necessary for the correlation study. Under this classification, linearity seems to be the most appropriate correlation to explain the relationship between the inverse of flash points (°K) and the logarithm of vapor pressures (mm Hg) at 25°C for pure organic compounds. A test study to evaluate the validity of a regression line as an estimation of an unknown flash point from a known vapor pressure was carried out with a data set containing 31 alkanes and aromatics; 55% of the flash points were predicted within ±5°Cand89% were within ±10°C. Within limits of ± 5 to 10°C the procedure is useful but should be improved. 相似文献
66.
Dechlorination of polychlorinated organic compounds by electrochemical reduction with naphthalene radical anion as mediator 总被引:1,自引:0,他引:1
Electrochemical reduction with electrochemically generated naphthalene radical anion in N,N-dimethylformamide was applied to the dechlorination of five representative POPs, namely HCB, lindane, DDT, PCP and aldrin. Rapid and complete dechlorination was possible for lindane and DDT to give nearly quantitative yields of benzene and 1,1-diphenylethane, respectively. HCB was reduced through complex reaction pathways to yield unknown products. Dechlorination of PCP and aldrin beyond dichlorinated compounds was difficult because of their very negative reduction potential. The reaction pathways for each dechlorination were proposed with the identification of intermediates. 相似文献
67.
Snappers (Lutjanidae) are one of the important fisheries resources in tropical and subtropical waters. However, there have
been few studies clarifying the ecology of newly settled juvenile snappers. The aims of the present study were to clarify
the seasonality and lunar periodicity of the larval settlement, and the microhabitat association of newly settled juveniles
for Lutjanus gibbus in an Okinawan coral reef. Fifteen coral patches were chosen and underwater visual surveys were conducted during a 2-year
period. The larval settlement of the species mainly occurred between May and October during the 2-year survey period. In terms
of lunar periodicity of the settlement, the newly settled juveniles were mainly found between the last quarter moon and new
moon during the main settlement season. Back calculations of settlement dates based on otolith microstructure showed that
most juveniles settled during the last quarter moon and new moon. Stepwise multiple regression analyses revealed that the
newly settled juveniles were mainly found on coral patches with a large number of holes on the top of the coral patch and
this tendency was mainly consistent during the study period. The volume of holes at the base of coral patches had also a positive
effect on the abundance of newly settled juveniles in some cases. The results of the present study suggest that larval settlement
has a strong seasonal and lunar periodicity, and newly settled juveniles select coral patches with available refuge spaces. 相似文献
68.
Anaerobic biodegradation of 4-alkylphenols in a paddy soil microcosm supplemented with nitrate 总被引:1,自引:0,他引:1
Anaerobic degradation of phenol, p-cresol, 4-n-propylphenol (n-PP), 4-i-propylphenol (i-PP), 4-n-butylphenol (n-BP) and 4-sec-butylphenol (sec-BP) was observed in a paddy soil supplemented with nitrate. We detected the metabolites 4′-hydroxypropiophenone (HPP) from n-PP, 4-i-propenylphenol from i-PP, and 4-(1-butenyl)phenol and 4′-hydroxybutyrophenone (HBP) from n-BP. Compared with the original soils, Betaproteobacteria became predominant in the microcosm during the degradation of phenol and p-cresol whereas no remarkable change was observed in the community degrading propylphenols and butylphenols. The microcosm, however, did not degrade 4-t-butylphenol (t-BP), 4-t-octylphenol (t-OP) and 4-n-octylphenol (n-OP). Paddy soil supplemented with sulfate or iron (III) as electron acceptors did not degrade phenol and 4-alkylphenols with the exception of the degradation of p-cresol in sulfate-reducing conditions. It was demonstrated for the first time that anaerobic microbial degradation of alkylphenols, in a paddy soil supplemented with nitrate as an electron acceptor, occurred via oxidation of the alpha carbon in the alkyl chain. 相似文献
69.
Kuzuhara Shunsuke Akimoto Yuta Shibata Kazu Oguchi Masahiro Terazono Atsushi 《Journal of Material Cycles and Waste Management》2018,20(1):431-438
Journal of Material Cycles and Waste Management - Our objective was to provide the information necessary to efficiently recover metals from end-of-life lithium-ion secondary batteries by assessing... 相似文献
70.
Osamu Abe Wenshou Wei Masao Mikami Kenji Kosugi Junrong Xu Takeshi Sato Mingzhe Liu Masujiro Shimizu Atsushi Sato 《Water, Air, & Soil Pollution: Focus》2005,5(3-6):3-13
Four automatic weather stations (AWS) were installed on the slopes and foot areas of the Tianshan and Kunlun Mountains along
a longitude of 80 degrees east: (1) Taglak 2400 m a.s.l., (2) Aksu 1000 m, (3) Kartash 2800 m, and (4) Qira 1700 m. These
two slopes face the Taklimakan Desert. Tagliak lies on the southern slope of Tianshan, and Kartash on the northern slope of
Kunlun. The meteorological characteristics of the mountainous regions were investigated using surface data obtained during
an intensive observation period (IOP) in spring 2002. It was found that visibility on the slopes decreases in the daytime,
and there is no relationship between visibility and wind speed in the mountainous areas. Two snow layers containing dust particles
were observed in the snow cover in Taglak during the IOP in spring 2003. These results suggest that a warm air parcel containing
aeolian dust climbs over the slopes of the mountainous areas, and dust particles in the mountainous areas are transported
from the foot areas. 相似文献