Preconcentration technique for the determination of trace elements in natural water samples by ICP-AES

A procedure was developed for the determination of Cd, Cu, Zn, Co, Ni, Mn, Pb and Mo in water samples by inductively coupled plasma atomic emission spectrometry (ICP-AES) after preconcentration on a morpholine dithiocarbamate (mor-DTC) supported by bagasse (Saccharam aphisinaram). The sorbed elements were subsequently eluted with 4,M HNO₃ and the acid eluates were analysed by ICP–AES. The influence of various parameters such as pH, flow rate of sample, eluent concentration, volume of the sample and volume of eluent were investigated to enhance the sensitivity of the present method. A 20,mL disposable syringe served as preconcentration column. Under the optimal conditions Cd, Cu, Zn, Co, Ni, Mn, Pb and Mo in aqueous sample was concentrated about 100-fold. The sorption recoveries of elements were higher than 99.6%. The method is also applied for the analysis of natural and spiked water samples.     

Approach for the use of MSW settlement predictions in the assessment of landfill capacity based on reliability analysis

In the analysis and design of municipal solid waste (MSW) landfills, there are many uncertainties associated with the properties of MSW during and after MSW placement. Several studies are performed involving different laboratory and field tests to understand the complex behavior and properties of MSW, and based on these studies, different models are proposed for the analysis of time dependent settlement response of MSW. For the analysis of MSW settlement, it is very important to account for the variability of model parameters that reflect different processes such as primary compression under loading, mechanical creep and biodegradation. In this paper, regression equations based on response surface method (RSM) are used to represent the complex behavior of MSW using a newly developed constitutive model. An approach to assess landfill capacities and develop landfill closure plans based on prediction of landfill settlements is proposed. The variability associated with model parameters relating to primary compression, mechanical creep and biodegradation are used to examine their influence on MSW settlement using reliability analysis framework and influence of various parameters on the settlement of MSW are estimated through sensitivity analysis.     

Effect of hydrogen addition on performance,emission, and combustion characteristics of Deccan hemp oil and its methyl ester–fuelled CI engine

Environmental Science and Pollution Research - A vegetable oil–fueled diesel engine operation is characterized by low brake thermal efficiency and relatively high smoke emission. Conversion...     

Biochemical changes in plant leaves as a biomarker of pollution due to anthropogenic activity

The air pollution due to anthropogenic activities seriously affected human life, vegetation, and heritage as well. The vegetation cover in and around the city mitigates the air pollution by acting as a sink for pollution. An attempt was made to evaluate biochemical changes occurred in four selected plant species, namely Azadirachta indica, Mangifera indica, Delonix regia, and Cassia fistula of residential, commercial, and industrial areas of Nagpur city in India. It was observed that the correlated values of air pollutants and plant leaves characteristics alter foliar biochemical features (i.e., chlorophyll and ascorbic acid content, pH and relative water content) of plants due to air pollution. The changes in air pollution tolerance index of plants was also estimated which revealed that these plants can be used as a biomarker of air pollution.     

Non-steroidal anti-inflammatory drugs in Indian rivers

Pharmaceutical concentration data for Indian surface waters are currently scarce. Sewage often enters Indian rivers without prior treatment, and so previously reported environmental concentrations from regions with routinely implemented sewage treatment cannot simply be used to predict concentrations in Indian surface water. Improved knowledge of pharmaceutical concentrations in Indian waters would enable determination of potential risks posed to aquatic wildlife and human health in this region. The concentrations of five common non-steroidal anti-inflammatory drugs (NSAIDs; diclofenac, ketoprofen, naproxen, ibuprofen, and acetylsalicylic acid) were determined in surface waters from 27 locations of the Kaveri, Vellar, and Tamiraparani Rivers in southern India. The samples were extracted by solid-phase extraction and analyzed by GC-MS. The measured concentrations of four of the five drugs in this reconnaissance were relatively similar to those reported elsewhere (ND–200 ng/l); however, acetylsalicylic acid, the most readily degradable of the investigated drugs, was found at all sites and at considerably higher concentrations (up to 660 ng/l) than reported in European surface waters. This is the first report on the occurrence of NSAIDs in Indian rivers. The finding of elevated concentrations of acetylsalicylic acid is most likely a result of direct discharges of untreated sewage. Therefore, readily degradable pharmaceuticals may present larger concern in regions without consistent sewage treatment. Based on measured environmental concentrations, the risks of direct toxicity to aquatic wildlife and of humans consuming the water are discussed.     

Impact of salinity and pH on phytoplankton communities in a tropical freshwater system: An investigation with pigment analysis by HPLC

An in vitro study was carried out to understand the effects of salinity shock and variation in pH on phytoplankton communities in a tropical freshwater system of the Godavari River (a major peninsular river in India). The distributions of, and variations in, phytoplankton communities were assessed by quantitative determination of their class specific marker pigments, using HPLC. Subtle changes in salinity of the freshwater by one practical salinity unit (PSU) completely removed green algae from the system and allowed the cyanobacteria to come into dominance. The cyanobacteria were found to tolerate higher osmotic stress until the salinity reached a PSU of 16. The higher salinity tolerance range of the cyanobacteria was attributed to the enhanced synthesis of zeaxanthin as protective xanthophylls against the osmotic stress. However, the effects of changing pH were not as dramatic as salinity where the green algae and the cyanobacteria from the same freshwater system showed a considerable acclimation towards the fluctuating pH. These findings are environmentally relevant to understand the likely impact of salt water intrusion and pH variation on phytoplankton communities in a tropical freshwater system.     

Utilization of rice husk ash for the treatment of leachate generated from Perungudi semi-urban solid waste dumping site of Chennai city,Tamil Nadu,India

Journal of Material Cycles and Waste Management - Leachate from the secured landfill sites and open dumpsite seems to be threat to environment, which requires an immediate attention to investigate...     

Biofabrication of ecofriendly copper oxide nanoparticles using Ocimum americanum aqueous leaf extract: analysis of in vitro antibacterial,anticancer, and photocatalytic activities

Environmental Science and Pollution Research - Nanotechnology tends to be a swiftly growing field of research that actively influences and inhibits the growth of bacteria/cancer. Noble metal...     

In vivo studies on the effect of Ocimum sanctum L. leaf extract in modifying the genotoxicity induced by chromium and mercury in Allium root meristems

In vivo cytogenetic assay in Allium cepa root tip cells has been carried out to detect the modifying effect of Ocimum sanctum aqueous leaf extract against chromium (Cr) and mercury (Hg) induced genotoxicity. It was observed that the roots post-treated with the leaf extract showed highly significant (p < 0.001) recovery in mitotic index (MI) and chromosomal aberrations (CA) when compared to pre-treated (Cr/Hg) samples and the lower doses of the leaf extract were found to be more effective than higher doses. The present study reveals that the Ocimum sanctum leaf extract possesses the protective effect against Cr/Hg induced genetic damage.     

Need for adaptation strategy against global sea level rise: an example from Saudi coast of Arabian gulf

This paper reports sea level rise (SLR) scenarios causing land loss, environmental degradation and destruction of infrastructure in the Saudi coast of the Arabian Gulf. Human development structures such as, sea ports, desalination plants, industrial establishments, commercial buildings, fish farms etc. will be impacted, leading to great economic losses. A systematic analysis on the current environmental setting of east coast of Kingdom of Saudi Arabia (KSA) versus the existing infrastructure assets indicates that a 1?m sea level rise in Arabian Gulf affects approximately 650?km² land area, along the Saudi coastline of ~1,800?km in 1:50,000 scale. Three simulation scenarios were created with respect to 1?m, 2?m and 3?m rises from the present mean sea level and its impacts were assessed. Maps depicting major infrastructure assets, ecologically sensitive elements, historical locations, anthropogenic zones, and Environmental Sensitivity Indices (ESI) were used for overlaying the sea level change map, in a Geographic Information System (GIS) platform. In general, the Jubail Marine Park area will have serious impact due to SLR. The inundation of low?Clying lands will affect the mangroves species of Dawhat Ad Dafi, coral reefs, coastal salt marshes, groundwater aquifers, and fish stocks. The risk of inundation on the Abu Ali Island, given their status as marine sanctuary of international importance, is particularly high. As an adaptation strategy, it is proposed that the KSA should implement Integrated Coastal Zone Management Plan (ICZMP) for the Arabian Gulf coast without further delay for the protection of its vulnerable resources and for sustainable development.