Roadside Measurements of Deforestation in the Amazon Area of Bolivia

This study describes the deforestation impact from three settlements, 5 de Junio, El Tigre, and 30 de Agosto, near the Madidi National Park in Bolivia. First deforestation rates along the road that connects the settlements and then deforestation within each settlement are examined. Landsat Thematic Mapper (TM) imagery from 1987, 1997, and 2000 were used to measure the deforestation. Face-to-face interviews were also used to collect detailed social and land-use information. Road-building and farming have been the major causes of deforestation in this region. The TM measurements indicate a high increase in the deforestation rate along the road in the area of study. The results also show a rapidly escalating deforestation rate in 5 de Junio, a potential high future deforestation rate in El Tigre, and a gradual deforestation increase in 30 de Agosto. The information provided by the settlers about clearing was compared with the imagery analysis. Generally, the settlers estimates were lower than the deforestation as derived from the imagery.     

Formation of chlorinated hydrocarbons from the reaction of chlorine atoms and activated carbon

The reactions of chlorine atoms and activated carbon have been studied over the temperature range of 200-400 degrees C using an isothermal flow reactor in conjunction with 337 nm laser photolysis of Cl2. These studies have shown that carbon tetrachloride is the major product, with chloroform, methylene chloride, and methyl chloride being formed in progressively decreasing yields. Trace quantities of methane, ethane, and dichloroethylenes were also observed. Mechanisms of carbon fragmentation by successive addition of chlorine atoms are proposed. The formation of small chlorinated hydrocarbons by the direct reaction of chlorine with carbon may be a key link in both the de novo and precursor pathways of formation of PCDD/F.     

Vanadium uptake by higher plants: Some recent developments

The occurrence of vanadium in the biosphere, and the possible roles this element may play in the metabolism of living organisms, especially higher plants, are discussed. The aqueous chemistry of the element is reviewed, and the chemical properties of the element are related to those of soils and plants. Evidence is present for a biotransformation of vanadium from vanadate (VO ₃ ^– ) to vanadyl (VO²⁺) during uptake by plants, based on tissue analysis and ESR spectra. The significance of this process on the potential impact of vanadium in the biosphere is discussed.     

Electrical Resistance Heating of Volatile Organic Compounds in Sedimentary Rock

Electrical resistance heating (ERH) is a common method of remediation for volatile organic compounds in unconsolidated soils, both above and below the water table. In the past eight years, ERH has been used to successfully treat 10 or more contaminated sedimentary bedrock sites. Sedimentary bedrock treatment has recently expanded to greater depths and into karst limestone environments. This article describes the implementation issues for rock remediation and provides case studies of three sites remediated by ERH in Pennsylvania and Alabama. With proper design, the remediation of sedimentary bedrock can be completed as effectively as the remediation of overburden materials. © 2014 Wiley Periodicals, Inc.     

Groundwater models and wellfield management: a case study

The highly permeable sand and gravel of the Little Miami River Valley Aquifer System near Milford, Ohio provide the community with a high-yielding source of drinking water. While this hydrogeologic setting is ideal from a water quantity standpoint, it is greatly vulnerable to contamination. The future viability of the well-field came into question when it was discovered that the wellfield was contaminated with volatile organic contaminants, leaving the City with the costly cleanup. Milford’s perseverance is also challenged by having to deal with a deteriorating treatment plant. Furthermore, larger water suppliers in the area have threatened the community’s independence. The question facing this community, and many other smaller communities, was whether to surrender its independence or invest in their future. The city has decided to keep their wellfield and to conduct a groundwater study. The objectives of the study were to: (a) collect and evaluate hydrogeological data; (b) develop a conceptual model of the groundwater system; (c) construct groundwater flow and geochemical models; (d) delineate wellhead protection area; and (e) develop a comprehensive management program. Collected hydro-geologic data served as a basis for the conceptual model. The U.S. Geological Survey (USGS) three-dimensional groundwater flow model MODFLOW was used in conjunction with MODPATH, a particle-tracking program, to identify travel times and paths of contaminants. This approach ultimately lead to the delineation of the wellhead protection area (WHPA). Geochemical mixing models were constructed using the USGS PHREEQC to verify the flow model results. The use of both flow and geochemical models to delineate the WHPA and to manage groundwater resources is a unique approach. The modeling results provide the City of Milford a management tool in making difficult policy decisions regarding future land use, siting for new monitoring and production wells, and identification of potential pollution sources.     

Fate of disinfection by-products in groundwater during aquifer storage and recovery with reclaimed water

Knowledge on the behaviour of disinfection by-products (DBPs) during aquifer storage and recovery (ASR) is limited even though this can be an important consideration where recovered waters are used for potable purposes. A reclaimed water ASR trial in an anoxic aquifer in South Australia has provided some of the first quantitative information at field-scale on the fate and transport of trihalomethanes (THMs) and haloacetic acids (HAAs). The results revealed that THM half-lives varied from <1 to 65 days, with persistence of chloroform being highest and bromoform lowest. HAA attenuation was rapid (<1 day). Rates of THM attenuation were shown to be highly dependent on the geochemical environment as evidenced by the 2-5 fold reduction in half-lives at the ASR well which became methanogenic during the storage phase of the trial, as compared to an observation well situated 4 m away, which remained nitrate-reducing. These findings agree with previous laboratory-based studies which also show persistence declining with increased bromination of THMs and reducing redox conditions. Modelling suggests that the chlorinated injectant has sufficient residual chlorine and natural organic matter for substantial increases in THMs to occur within the aquifer, however this is masked in some of the field observations due to concurrent attenuation, particularly for the more rapidly attenuated brominated compounds. The model is based on data taken from water distribution systems and may not be representative for ASR since bromide and ammonia concentrations in the injected water and the possible role of organic carbon in the aquifer were not taken into consideration. During the storage phase DBP formation potentials were reduced as a result of the removal of precursor material despite an increase in the THM formation potential per unit weight of total organic carbon. This suggests that water quality improvements with respect to THMs and HAAs can be achieved through ASR in anoxic aquifers.     

Ecotoxicological assessment of diffuse pollution using biomonitoring tool for sustainable land use in Thailand

As a developing country, Thailand has a significant issue with diffuse pollution of the soil ecosystem due to an indiscriminate use of agrichemicals and poorly regulated disposal of a wide variety of hazardous wastes. Practical risk assessment tools based on locally-occurring species are needed to assess the effects of diffuse pollutants on the soil ecosystem in Thailand because reliance on soil criteria developed for overseas conditions may provide inadequate protection. Native soil organisms in Thailand may be more or less sensitive to contaminants compared to overseas test species. This article described a biological indicator approach for ecological risk assessment of diffuse pollution in the soil ecosystem of Thailand from pesticide application with the aim of developing standardized protocols using native species and locally generated data to better evaluate the ecological risks of non-point source soil pollution. It was found that ecotoxicological assessment provided a better understanding of the ecological impacts that diffuse pollution induced on Thai environmental conditions. Thai soil biota species were more sensitive to soil contaminants than similar species overseas. Soil series also had an influence on the ecotoxicology of contaminants to soil biota. Collembolan, Cyphoderus sp., was demonstrated as a useful alternative test species to Folsomia Candida (international test species) for terrestrial ecotoxicological testing of Thai soils. In addition, the soil biota activities such as soil respiration and earthworm avoidance including soil biodiversity and the litter bag decomposition technique are also good tools to assess the effects of diffuse pollution by pesticides on the soil ecosystem of Thailand.     

The relationship between blend miscibility and biodegradation of cellulose acetate and poly(ethylene Succmate) blends

The miscibility of cellulose acetate (CA; degree of substitution = 2.5) and poly(ethylene succinate) (PES) has been investigated using a variety of thermal techniques and by solid-state carbon13 NMR spectroscopy. The blends containing greater than ca. 70% CA were found to be miscible. In the case of blends containing less than ca. 70% CA, a combination of thermal and NMR analyses suggests that these blends are not fully miscible on a 2.5- to 5-nm scale. On the scale which can be probed by dynamic mechanical thermal analysis (15 nm), the low-percentage CA blends exhibit “significant local concentration fluctuations≓. Investigation of the biodegradation of the blend components and of the blends revealed that PES degraded relatively rapidly and that CA degraded slowly. The blends degraded at a rate essentially identical to that of CA. Miscibility (75% CA blend) or crystallization of PES (30% CA blend) had no significant effect. These data suggest that a significant mode of degradation ófPES during composting involves chemical hydrolysis of the polymer followed by biological assimilation of monomers. Degradation of the blends is initiated in the amorphous phase. Because CA is a significant component of the amorphous phase, a small amount of CA significantly impacts the biodegradation rates of the blends.