Economics of an integrated approach to control SO2, NOX,HCl, and particulate emissions from power plants

An integrated approach for the simultaneous reduction of major combustion-generated pollutants from power plants is presented along with a simplified economic analysis. With this technology, the synergistic effects of high-temperature sorbent/coal or sorbent/natural gas injection and high-temperature flue gas filtration are exploited. Calcium-based (or Na-based, etc.) sorbents are sprayed in the post-flame zone of a furnace, where they react with S- and Cl-containing gases to form stable salts of Ca (or Na, etc.). The partially reacted sorbent is then collected in a high-temperature ceramic filter, which is placed downstream of the sorbent injection point, where it further reacts for a prolonged period of time. With this technique, both the likelihood of contact and the length of time of contact between the solid sorbent particles and the gaseous pollutants increase, because reaction takes place both in the furnace upstream of the filter and inside the filter itself. Hence, the sorbent utilization increases significantly. Several pollutants, such as SO2, H2S, HCl, and particulate (soot, ash, and tar), may be partially removed from the effluent. The organic content of the sorbents (or blends) also pyrolyzes and reduces NOx. Unburned carbon in the ash may be completely oxidized in the filter. The filter is cleaned periodically with aerodynamic regeneration (back pulsing) without interrupting furnace operation. The effectiveness of this technique has been shown in laboratory-scale experiments using either rather costly carboxylic salts of Ca or low- to moderate-cost blends of limestone, lime, or sodium bicarbonate with coal fines. Injection occurred in the furnace at 1150 degrees C, while the filter was maintained at 600 degrees C. Results showed that 65 or 40% SO2 removal was obtained with calcium formate or a limestone/coal blend, respectively, at an entering calcium-to-sulfur molar ratio of 2. A sodium bicarbonate/coal blend resulted in 78% SO2 removal at a sodium-to-sulfur molar ratio of 2. HCl removal efficiencies have been shown to be higher than those for SO2. NOx reductions of 40% have been observed with a fuel (coal)-to-air equivalence ratio, phi, around 2. The filter has been shown to be 97-99% efficient in removing PM2.5 particulates. Calculations herein show that this integrated sorbent/filter method is cost-effective, in comparison with current technologies, on both capital cost ($/kW) and levelized cost ($/ton pollutant removed) bases, if a limestone/coal mixture is used as the sorbent for fossil fuel plants. Capital costs for the filter/sorbent combination are estimated to be in the range of $61-$105/kW for a new plant. Because current technologies are designed for removing one pollutant at a time, both their cost and space requirements are higher than those of this integrated technique. At the minimum projected removal efficiencies for HCl/SO2/NOx of about 40%, the levelized costs are projected to be $203-$261/ton of combined pollutant SO2/HCl/NOx and particulates removed from coal-fired power plants.     

Management and valuation of an environmentally sensitive area: Norfolk Broadland,England, case study

Wetlands, like any other environmentally sensitive resource, require very careful evaluation. While it is accepted that all wetlands may be equally valuable in terms of maintaining global life-support systems, individual areas may be ranked according to their uniqueness or the irreplaceability of the resource should the wetland be developed. The various techniques available for evaluating the wetland resource in the development versus conservation conflict situation are critically assessed. Indirect appraisal via the opportunity cost method can generate valuable data which have contributed to the mitigation of such conflict situations.The Broadland, in Norfolk, England, recently designated an environmentally sensitive area (ESA), provides a case study example of wetland management. The search for an acceptable flood alleviation strategy for the ESA is examined in detail. The economic and environmental asset structure of the study area is examined at two levels. A basic screening system is applied to each of the identified flood protection planning units to enable the rank ordering of the units. A more detailed appraisal is then made of the value of selected units so that the cost-effectiveness of any planned expenditure on flood protection works can be assessed. Specific management issues and their likely effect on the environment, in terms of land use for example, are also addressed. The 1986 Agriculture Act marks a potential watershed in British conservation policy. The ESA policy encompasses a dual management strategy that attempts to stimulate compatible agricultural and conservation practices and activities. Other countries that still retain significant unspoiled wetland resources may find that preemptive regulatory government intervention in favor of conservation would help to avoid the worst aspects of the British experience.     

Capturing the lost phosphorus

Minable phosphorus (P) reserves are being depleted and will need to be replaced by recovering P that currently is lost from the agricultural system, causing water-quality problems. The largest two flows of lost P are in agricultural runoff and erosion (∼46% of mined P globally) and animal wastes (∼40%). These flows are quite distinct. Runoff has a very high volumetric flow rate, but a low P concentration; animal wastes have low flow rates, but a high P concentration together with a high concentration of organic material. Recovering the lost P in animal wastes is technically and economically more tractable, and it is the focus for this review of promising P-capture technologies. P capture requires that organic P be transformed into inorganic P (phosphate). For high-strength animal wastes, P release can be accomplished in tandem with anaerobic treatment that converts the energy value in the organic matter to CH₄, H₂, or electricity. Once present as phosphate, the P can be captured in a reusable form by four approaches. Most well developed is precipitation as magnesium or calcium solids. Less developed, but promising are adsorption to iron-based adsorbents, ion exchange to phosphate-selective solids, and uptake by photosynthetic microorganisms or P-selective proteins.     

Performance Assessment of Rain Gardens1

Abstract: The most widely used approach for evaluating the performance of stormwater best management practices (BMPs) such as rain gardens is monitoring, but this approach can involve a long time period to observe a sufficient number and variety of storm events, a high level of effort, and unavoidable uncertainty. In this paper, we describe the development and evaluation of three approaches for performance assessment of rain gardens: visual inspection, infiltration rate testing, and synthetic drawdown testing. Twelve rain gardens in Minnesota underwent visual inspection, with four determined to be nonfunctional based on one or more of the following criteria: (1) presence of ponded water, (2) presence of hydric soils, (3) presence of emergent (wetland) vegetation, and (4) failing vegetation. It is believed that these rain gardens failed due to a lack of maintenance. For the remaining eight rain gardens, an infiltrometer was used to determine the saturated hydraulic conductivity (K_sat) of the soil surface at several locations throughout each basin in what is termed infiltration rate testing. The median K_sat values for the rain gardens ranged from 3 to 72 cm/h. Synthetic drawdown testing was performed on three rain gardens by filling the basins with water to capacity where possible and recording water level over time. The observed drain times for two of those rain gardens were in good agreement with predictions based on the median of the infiltrometer measurements. The observed drain time for the third rain garden was much greater than predicted due to the presence of a restrictive soil layer beneath the topsoil. The assessment approaches developed in this research should prove useful for determining whether the construction of the rain garden was performed properly, a rain garden is functioning properly, and for developing maintenance tasks and schedules.     

3D-QSAR of fungal quorum-sensing inhibiting analogs of farnesol

Thirty-four analogs with variable antifungal activity were selected to develop models for establishing three-dimensional quantitative structure-activity relationships (3D-QSAR). Comparative molecular field analysis (CoMFA) and comparative similarity indices analyses (CoMSIA) were conducted on the group of analogs to determine the structural requirements for selectivity and potency in inhibiting biofilm formation and fungal growth. The best CoMFA model predicted a q(2) = 0.5 and an r(2) = 0.991, and revealed that electrostatic properties play a significant role in potency and selectivity. The best CoMSIA model combined electrostatics, hydrogen bond acceptor and donor, and hydrophobic fields with a q(2) = 0.664 r(2) = 0.952, S = 0.099, and F = 139.892. The analyses of the contour maps from both models provide significant insight into the structural necessities for a potent compound. Therefore, manipulating various chemical properties of the substituted groups on the farnesol chain can be used to enhance the fungicidal properties of the target compound.     

Reconsidering priorities for forest conservation when considering the threats of mining and armed conflict

Many threats to biodiversity can be predicted and are well mapped but others are uncertain in their extent, impact on biodiversity, and ability for conservation efforts to address, making them more difficult to account for in spatial conservation planning efforts, and as a result, they are often ignored. Here, we use a spatial prioritisation analysis to evaluate the consequences of considering only relatively well-mapped threats to biodiversity and compare this with planning scenarios that also account for more uncertain threats (in this case mining and armed conflict) under different management strategies. We evaluate three management strategies to address these more uncertain threats: 1. to ignore them; 2. avoid them; or 3. specifically target actions towards them, first individually and then simultaneously to assess the impact of their inclusion in spatial prioritisations. We apply our approach to the eastern Democratic Republic of the Congo (DRC) and identify priority areas for conserving biodiversity and carbon sequestration services. We found that a strategy that avoids addressing threats of mining and armed conflict more often misses important opportunities for biodiversity conservation, compared to a strategy that targets action towards areas under threat (assuming a biodiversity benefit is possible). We found that considering mining and armed conflict threats to biodiversity independently rather than simultaneously results in 13 800–14 800 km² and 15 700–25 100 km² of potential missed conservation opportunities when undertaking threat-avoiding and threat-targeting management strategies, respectively. Our analysis emphasises the importance of considering all threats that can be mapped in spatial conservation prioritisation.Supplementary InformationThe online version contains supplementary material available at 10.1007/s13280-022-01724-0.     

Environmental and social factors influence chorusing behaviour in a tropical frog: examining various temporal and spatial scales

Many animals use conspicuous display to attract mates, and there should be selection for displays to occur at times and places that maximise the probability of mating, while minimising energetic costs and predator attraction. To select the best times for display, individuals may use environmental cues, the presence of other individuals, or both, but few studies have examined these sources of variation in display activity. In this study, we examined physical environmental and social factors triggering displays in a tropical, terrestrially breeding frog, Cophixalus ornatus. To measure the influence of physical environmental conditions on calling activity, we recorded temperature, rainfall, moon illumination/visibility, humidity, barometric pressure and intensity of calling activity throughout a breeding season at six locations along a 560-m transect. The intensity of calling varied daily, seasonally, and at a small spatial scale. Variation in calling activity from day to day was large. There was also a strong seasonal trend in calling activity: few males called at the start of the season, activity peaked shortly after the beginning of the season, and then declined linearly from the peak to the end of the season. There was also consistent variation among sites along the transect, which may have been due to variations in frog density at each site, or to consistent microscale variations in physical conditions, or both. After statistically removing consistent local variation among sites, a principal components analysis suggested that a maximum of 35.8% of the variation in calling activity among days was due to factors common to all sites, such as weather, moon illumination, or large-scale social facilitation (e.g. of choruses by other choruses). The remainder of the variation among sites (64.2%) was due to site-specific factors, such as small-scale social facilitation or unmeasured, apparently stochastic effects, such as microenvironmental physical factors that do not vary consistently over sites. Regressions of environmental variables on residual calling activity (after removing consistent effects of site and season), alone or in combination, accounted for very little of the variation in the number of calling males (maximum 10%). Thus, our data, showing strong seasonal effects and consistent variation among sites combined with large amounts of variation in the number of calling males at small spatial scales, suggest that environmental conditions, such as temperature, rainfall, moon illumination and barometric pressure, which act over large spatial scales, may determine the overall environmental envelope within which calling can occur but do not account for most of the variation in the number of calling males on a day-to-day or site-to-site basis. Similarly, variations in the number of calling males at small spatial scales suggest that social facilitation is a relatively unimportant trigger for displays on a large scale in these frogs. On the other hand, our data suggest that social facilitation may have important effects on variation in the number of calling males on a day-to-day and site-to-site basis. We used playback experiments to assess whether the sound of calling could initiate displays. We played either a taped chorus or white noise in areas where few (zero to two) males were calling. The number of calling males increased both during and after the chorus stimulus, whereas there was no increase in calling in response to white noise. These data suggest that examining variation in calling activity at small spatial scales can reveal the sources of variation for the number of calling males, and indicate that, in these frogs, males tend to use the calling of other individuals as a cue to determine when to display. Received: 19 October 1999 / Revised: 30 June 2000 / Accepted: 26 August 2000     

A semi-automated tool for identifying agricultural roadway crashes in crash narratives

Objective: Crash reports contain precoded structured data fields and a crash narrative that can be a source of rich information not included in the structured data. The narrative can be useful for identifying vulnerable roadway users, such as agricultural workers. However, using the narratives often requires manual reviews that are time consuming and costly. The objective of this research was to develop a simple and relatively inexpensive, semi-automated tool for screening crash narratives and expediting the process of identifying crashes with specific characteristics, such as agricultural crashes.

Methods: Crash records for Louisiana from 2010 to 2015 were obtained from the Louisiana Department of Transportation (LaDOTD). Records with narratives were extracted and stratified by vehicle type. The majority of analyses focused on a vehicle type of farm equipment (Type T). Two keyword lists, an inclusion list and an exclusion list, were created based on the published literature, subject-matter experts, and findings from a pilot project. Next, a semi-automated tool was developed in Microsoft Excel to identify agricultural crashes. Lastly, the tool’s performance was assessed using a gold standard set of agricultural narratives identified through manual review.

Results: The tool reduced the search space (e.g., number of narratives that need manual review) for narratives requiring manual review from 6.7 to 59.4% depending on the research question. Sensitivity was high, with 96.1% of agricultural crash narratives being correctly classified. Of the gold standard agricultural narratives, 58.3% included an equipment keyword and 72.8% included a farm equipment brand.

Conclusion: This article provides information on how crash narratives can supplement structured crash data. It also provides an easy-to-implement method to facilitate incorporating narratives into safety research along with keyword lists for identifying agricultural crashes.