Processing and Characterization of Short-Fiber Reinforced Jute/Poly Butylene Succinate Biodegradable Composites: The Effect of Weld-Line

Fabrication of complex injection molded parts often involves the use of multiple gates. In such situations, polymer melts from different gates meld to form the molded part (weld line). This paper reports on the fabrication and characterization of the mechanical and morphological properties of short fiber reinforced jute/poly butylene succinate (PBS) biodegradable composites. The effect of a dual gated mold in the fabrication of welded specimens was a key focus of the investigation. It was observed that incorporation of jute fiber (10 wt%) conferred drastic changes on the stress–strain properties of the matrix as the elongation at break (EB), dropped from 160% in the matrix to just 10% in the composite. The tensile strength of the composite was lower than that of the matrix. However, it is noteworthy that the tensile modulus of the composite increased. Bending test also revealed that both bending strength and modulus increased with the incorporation of jute. Morphological studies of the tensile fracture surface using SEM revealed two types of failure mode. Ductile failure was indicated by plastic deformation at the initiation of fracture followed by brittle failure. The good interfacial bonding indicated between jute and PBS was attributed to positive interaction between the two polar polymers. A comparison of the non-weld and weld-line samples revealed that the weld-line composites have better mechanical integrity than the corresponding polymer matrix with weld line. The results also revealed that elongation at break and toughness are most sensitive to the presence of the weld-line whereas flexural properties are least sensitive.     

Opportunities to reduce greenhouse gas emissions from households in Nigeria

Efforts to mitigate climate threats should not exclude the household as the household is a major driver of greenhouse gas (GHG) emissions through its consumption patterns. This paper derives an emission index that could be used to estimate inventories of carbon dioxide (CO₂) emissions from kerosene combustion for lighting in Nigeria and also looks at the implications of solar pv lighting replacing kerosene lamp in Nigeria. Findings indicate that (1) average CO₂ emissions from kerosene combustion for lighting in Nigeria is about 0.06 kg per hour per lamp, which can be taken as the kerosene lamp CO₂ emission index for Nigeria. (2) about 3 × 10W_p solar pv will be required to replace a kerosene lamp, while about 0.124 tonnes of CO₂ will be avoided per lamp per year, operating at 6 h daily. At the national level, under the kerosene lamp replacement projection assumptions made, between 0.4 and 1.0 million tonnes of CO₂ will be avoided per year. The household investment required to owe a solar pv, including the capital cost of switching from kerosene lamp, is about US356, while the national capital investment outlay is between 1,138.265 and US356, while the national capital investment outlay is between 1,138.265 and US2,848 million. (3) Certified Emission Reduction (CER) units, assuming CO₂ is traded, will generate significant annual revenues on the order of 6.96 to almost US17.4 million per year, while earnings from unspent household kerosene fuel could amount to between 2,520 and US17.4 million per year, while earnings from unspent household kerosene fuel could amount to between 2,520 and US6,300 million over the life span of the solar pv. The micro-economic assessment carried out indicates the non-attractiveness of solar pv use at the household level, and (4) to promote solar pv use, both long and short term policy measures that aim at cost reduction were suggested. The paper concludes that, factoring the suggested measures into the climate, energy, and financial policy decision discourse in Nigeria could empower the households to play a significant role in achieving global CO₂ emission reduction, but at the local level.