High-resolution mapping of acid sulfate soils in Northern Australia through predictive models

Environmental Chemistry Letters - Acid sulfate soils can form when pyrite-rich marshes are drained or tidal influence decreases, naturally or anthropogenically. Often they are vegetated by...     

Bioconcentration and depuration of endosulfan sulfate in mosquito fish (Gambusia affinis)

Endosulfan is an insecticide which has been widely used in agriculture. The technical grade material consists of two isomers (alpha and beta). Under natural environmental conditions, endosulfan is metabolized through oxidation and the main metabolite in the environment is endosulfan sulfate. Most ecotoxicology research has been conducted with technical grade endosulfan to determine effects on non-target aquatic organisms. Little data on the effects of endosulfan sulfate on aquatic organisms are available in the literature. This study characterizes endosulfan sulfate bioconcentration and depuration in mosquito fish (Gambusia affinis). During the study, G. affinis was exposed to an environmentally relevant endosulfan sulfate concentration of 0.25 μg L⁻¹ for 5 weeks (uptake phase) followed by a 3-week period (depuration phase) in clean water. This study found that G. affinis bioconcentrated endosulfan sulfate. During the exposure phase, fish tissue concentrations of endosulfan sulfate increased with time up to 730 μg kg⁻¹ dw or 215 μg kg⁻¹ ww. The bioconcentration data followed Michaelis-Menten kinetics better than the one-compartment first order kinetics (1-CFOK). Using these models, the bioconcentration factors for endosulfan sulfate-exposed G. affinis were from 687 to 888  L kg⁻¹ in wet weight or 2263 to 2936 L kg⁻¹ in dry weight. During the depuration phase, endosulfan sulfate concentrations in tissue significantly decreased and the data followed first order kinetics. The half-life of endosulfan sulfate in G. affinis was about 9 d. There was no significant difference in standard length or weight between control and exposed fish. The growth data followed the von Bertalanffy growth model. However, the condition factor of exposed fish increased with time during the exposure phase.     

A survey on municipal solid waste and residents’ awareness in Da Nang city, Vietnam

A survey on solid waste generation and residents’ awareness was conducted in Da Nang city, Vietnam in 2010. We took samples from residents, hotels, restaurants, and city markets. Data reveals that each resident generates on average 0.71 kg/capita/day (3 kg/household/day). Regarding the composition, organic waste (food, flowers, leaves, grass) accounts for about 70 % of residents’ waste followed by plastics. Likewise, about 14 % of residents’ waste can be recycled. Furthermore, we find that middle income households in the suburbs have the largest waste generation with 4.9 kg/household/day. We consider that this finding is explained by their dedication to agricultural activities, such as planting fruit trees and vegetables, and gardening. Finally, we find that only about 60 % of interviewees have knowledge of how to segregate waste, however more than 90 % of them are willing to cooperate with the introduction of a waste segregation program in the city.     

Sustainability indicators for clean development mechanism projects in Vietnam

The Clean Development Mechanism (CDM) is one of the flexible instruments of the Kyoto Protocol designed to combat climate change so as to bring advantages to developing countries and developed countries alike. Indeed, CDM projects have a two-fold objective: to offset greenhouse gas emissions and to contribute to sustainable development in the host country. However in many cases, the latter objective appears to be marginalized. This is at least partly due to the difficulties surrounding the definition and the measurement of sustainability, in particular in a developing country context. To assess CDM projects’ contribution to sustainable development in the host country, scholars and practitioners need adapted indicator sets. A set of indicators were developed by way of an iterative Delphi approach amongst selected Vietnamese experts. The Delphi approach allowed a systematic collection of the experts’ judgements on the sustainability indicators through a set of sequentially applied questionnaires, interspersed with feedback from earlier responses. This exercise resulted in the selection of a set of 36 indicators, which emphasise economic efficiency, public health and pollution issues. The exercise yielded a locally supported and context-specific set of sustainability indicators that will allow Vietnamese decision-makers to enhance the sustainability of the approved CDM projects. In the future this set should be continually improved through real-life application and further participation from local stakeholders. This study is a first step in a long-term process towards developing an adapted toolkit for sustainability assessment of CDM projects in Vietnam.     

How do local communities adapt to climate changes along heavily damaged coasts? A Stakeholder Delphi study in Ky Anh (Central Vietnam)

The Central Vietnamese coast faces increasing impacts on the local livelihoods of coastal communities as a result of the increasing natural hazards which include tropical storms, heavy rains, and floods. A challenge for the local populations is improving their adaptation capacity to climate change hazards in a sustainable way. This study deals with the impacts of climate change-associated hazards and adaptation capacity in coastal communes of the Ky Anh district, Ha Tinh province along the coast in Central Vietnam. A combination of the Stakeholder Delphi technique and the DPSIR (drivers–pressures–states–impacts–responses) framework was used. Delphi questionnaires allowed assessing the consensus among the respondents of a stakeholder group. Twenty questions and 20 statements were listed reflecting the DPSIR components. Thirty-six panel members, which were randomly selected from four stakeholder groups which included local authorities, farmers, fishermen, and fish traders, were involved in a two-round Delphi process. The results show that, both agricultural and non-agricultural sectors are main drivers (D); migration, calamities, population growth, mineral mining, aquaculture processing, and agriculture are main pressures (P); changes in the frequency of extreme weather events, increasing intensity of storms, floods, and droughts indicate main states (S); changes in agricultural land use and productivity are main impacts (I); construction of and upgrading dykes and irrigation systems should be the principal responses (R) in the vision of the local stakeholders. The Kendall’s W value for the second round is 0.681, indicating a high degree of consensus among the panel members and confidence in the ranks. Overall, the study advocates developing sustainable ecosystems, an upgraded New Rural Planning, and renewable energy strategies as the main local adaptations to climate change hazards in this area.     

Interfacial-engineered CoTiO3-based composite for photocatalytic applications: a review

Environmental Chemistry Letters - Photocatalysis is a green chemical process that could partly solve energy and pollution issues. Catalysts such as cobalt titanate, CoTiO3, have intrigued...     

Polybrominated diphenyl ethers in plastic products,indoor dust,sediment and fish from informal e-waste recycling sites in Vietnam: a comprehensive assessment of contamination,accumulation pattern,emissions, and human exposure

Residue concentrations of polybrominated diphenyl ethers (PBDEs) in different kinds of samples including consumer products, indoor dust, sediment and fish collected from two e-waste recycling sites, and some industrial, urban and suburban areas in Vietnam were determined to provide a comprehensive assessment of the contamination levels, accumulation pattern, emission potential and human exposure through dust ingestion and fish consumption. There was a large variation of PBDE levels in plastic parts of obsolete electronic equipment (from 1730 to 97,300 ng/g), which is a common result observed in consumer plastic products reported elsewhere. PBDE levels in indoor dust samples collected from e-waste recycling sites ranged from 250 to 8740 ng/g, which were markedly higher than those in industrial areas and household offices. Emission rate of PBDEs from plastic parts of disposed electronic equipment to dust was estimated to be in a range from 3.4 × 10^?7 to 1.2 × 10^?5 (year^?1) for total PBDEs and from 2.9 × 10^?7 to 7.2 × 10^?6 (year^?1) for BDE-209. Some fish species collected from ponds in e-waste recycling villages contained elevated levels of PBDEs, especially BDE-209, which were markedly higher than those in fish previously reported. Overall, levels and patterns of PBDE accumulation in different kinds of samples suggest significant emission from e-waste sites and that these areas are potential sources of PBDE contamination. Intakes of PBDEs via fish consumption were generally higher than those estimated through dust ingestion. Intake of BDE-99 and BDE-209 through dust ingestion contributes a large proportion due to higher concentrations in dust and fish. Body weight normalized daily intake through dust ingestion estimated for the e-waste recycling sites (0.10–3.46 ng/day/kg body wt.) were in a high range as compared to those reported in other countries. Our results highlight the potential releases of PBDEs from informal recycling activities and the high degree of human exposure and suggest the need for continuous investigations on environmental pollution and toxic impacts of e-waste-related hazardous chemicals.     

Potential for the desalination of a brackish groundwater aquifer under a background of rising sea level via salt intrusion prevention river gates in the coastal area of the Red River Delta,Vietnam

Additional freshwater sources are required in many parts of the world, including the coastal areas of the Red River Delta (RRD), where the groundwater (GW) is generally brackish. Determining a feasible method for desalinating brackish aquifers would help provide additional freshwater sources. However, substantial desalination of brackish aquifers cannot be achieved under the natural conditions of GW flow and precipitation recharge. Although rainfall recharge to the shallow Holocene aquifer has occurred for hundreds of years, the aquifer still remains brackish since the natural hydraulic conditions do not allow a complete mixing between the fresh recharged water and aquifer salinized water or the discharging of the aquifer salinized water. The planned salt intrusion prevention gates in the Red River, Tra Ly River and Hoa River in the RRD coastal area, combined with increased GW abstraction and associated aquifer recharge with fresh river water, could result in the gradual desalination of the shallow Holocene aquifer. These effects would help improve the area’s resilience to freshwater shortages and sea level rises and would allow for the creation of a long-term sustainable water resource development plan to manage the salinization of water resources caused by sea level rises. Finite element (FE) modeling of GW flow, solute transport via GW flow and dynamic programming (DP) have been used to study the potential desalination of brackish aquifers, the magnitude of GW abstraction quantities and the spatial and temporal aspects of desalination. FE modeling of GW flow coupled with DP was utilized to identify the magnitude of sustainable abstraction quantities and the GW flow field, which is required in salt transport models. Multiple sizes of elements and time steps were used to adapt to the unsteady state of GW flow and hydraulic head variables between the elements in the FE meshes in order to ensure reasonable accuracy of numerical modeling. The GW flow and salt transport modeling and DP allowed determining quasi-steady-state GW abstraction rates and aquifer salinity levels for conditions that did and did not include the shallow Holocene unconfined aquifer recharge from rainfall. The aquifer modeled domain which is supposed to serve the pumping well field is 1.5 km². The results showed that the Holocene aquifer may provide a stable abstraction rate of 100 m³/day starting in the 6th year (for the worst-case scenario with zero aquifer recharge from rainfall) to 130 m³/day starting in the 3rd year (for the scenario with aquifer recharge equal to 3% of the rainfall levels). During the first years of GW abstraction, the desalination of the brackish upper Holocene aquifer will mainly occur in the area close to the river, and at the 18th year of abstraction, almost the entire area between the river and line of pumping wells would be desalinized. From the 10th year of abstraction, the abstracted water has a total dissolved solids content lower than 0.5 g/l for the worst-case scenario with zero aquifer recharge from rainfall and lower than 0.42 g/l for the scenario with aquifer recharge equal to 3% of the rainfall. The modeling results indicate the simulated process by which abstraction of groundwater adjacent to the Tra Ly River could desalinize the brackish aquifer via freshwater recharge from the river.