国家体育馆性能化消防火灾场景设计介绍

本文介绍了国家体育馆性能化消防设计中火灾场景设计情况,主要包括场馆各典型场所火灾危险性分析及确定火灾规模的方法,并基于此讨论了国家体育馆火灾场景的确定,为人员安全疏散、防排烟等专项性能化设计提供了火灾场景前提。     

预测有机化合物对水蚤EC50值的片段常数法

根据217种化合物建立了估算有机化合物对水蚤EC50值（48h半数影响浓度）的片段常数模型,分析了模型的误差及稳健性。研究结果表明,有机化合物的片段常数和结构因子与水蚤的EC50值倒数的对数（lg1/EC50)显著相关,可以根据片段常数法估算有机化合物对水蚤的EC50。模型的可决系数为0.9687,平均绝对误差0.40个对数单位,其中68.7%化合物的误差小于0.5个对数单位。     

聚苯乙烯基硫代磺酸钾树脂的合成及其与卤代烃的反应

由聚苯乙烯基磺酰氯树脂与硫化氢钾反应制备聚苯乙烯基硫代磺酸钾树脂（Ｉ）,树脂Ｉ与亲电的卤代烃反应,生成聚苯乙烯基硫代磺酸酯树脂（Ⅱ）,树脂Ⅱ经过乙硫醇处理,使卤代烃结构部分以不对称二硫醚的形式游离下来,用ＧＣ／ＭＳ对其结构进行鉴定。从不对称二硫醚的结构可推导出原卤代烃的结构,所制备的聚苯乙烯基硫代磺酸钾树脂的转化效率为１．１１ｍｍｏｌ·ｇ＾－１。     

Pollution characteristics and ecological risk assessment of heavy metals in three land-use types on the southern Loess Plateau,China

The accumulation of heavy metals in agricultural soils has been the subject of great concern because these metals have the potential to be transferred to soil solutions and subsequently accumulate in the food chain. To study the persistence of trace metals in crop and orchard soils, representative surface soil samples were collected from terrace farmland that had been cultivated for various numbers of years (3, 8, 12, 15, and >20 years), terrace orchard land that had been cultivated for various numbers of years (4, 7, 10, 12, 15, 18, 25, and >30 years), and slope farmland with various gradients (3°, 5°, 8°, 12°, 15°, and 25°) and analyzed for heavy metals (As, Cr, Cu, Hg, Ni, and Zn). These samples were collected from Nihegou catchment of Chunhua county in the southern Loess Plateau of China. The six heavy metals demonstrated different trends with time or gradient in the three land-use types. The Cu and Zn contents of the soil were higher than the referee background values of the loessal soil, and the contents of Cr and Ni, and especially those of As and Hg, were lower. Cu was the only heavy metal that just met the Grade III Environmental Quality Standard for Soils of China, while the others reached grade I. Cu and Hg were considered contaminant factors and Hg was a moderate potential ecological risk factor in the catchment. Of the sites investigated, 89.5% fell into the category with a low degree of contamination (C _d ) and rest were moderate, while all three land-use types had low potential ecological risk (RI). Changes of C _d and RI were consistent with the cultivated time in the terrace farmland and terrace orchard land. Values of RI increased while C _d decreased with the increasing of slope gradient in the slope farmland. Evaluating the ecological risk posed by heavy metals using more soil samples in a larger study area is necessary on the Loess Plateau of China.     

Seasonal variations of monocarbonyl and dicarbonyl in urban and sub-urban sites of Xi’an,China

Seventeen airborne carbonyls including monocarbonyls and dicarbonyls were determined in urban and sub-urban sites of Xi’an, China in three seasons in 2010. In winter, acetone was the most abundant carbonyl in the urban site due to usage of organic solvents in constructions and laboratories and its slower atmospheric removal mechanisms by photolysis and reaction with hydroxyl radical than those of formaldehyde and acetaldehyde. In the sub-urban site, acetaldehyde was the most abundant carbonyl, followed by formaldehyde and acetone. During summer, however, formaldehyde was the most dominant carbonyl in both sites. The photooxidations of a wide range of volatile organic compounds (VOCs) yielded much more formaldehyde than other carbonyls under high solar radiation and temperature. In the urban site, the average concentrations of dicarbonyls (i.e., glyoxal and methyglyoxal) in spring and summer were higher than that in winter. Transformation of aromatic VOCs emitted from fuel evaporation leads to the formation of 1,2-dicarbonyls. A reverse trend was observed in sub-urban sites, as explained by the relatively low abundances and accumulations of VOC precursors in the rural atmosphere during warm seasons. Moreover, cumulative cancer risk based on measured outdoor carbonyls (formaldehyde and acetaldehyde) in Xi’an Jiaotong University and Heihe was estimated (8.82?×?10^?5 and 4.96?×?10^?5, respectively). This study provides a clear map on the abundances of carbonyls and their source interpretation in the largest and the most economic city in Northwestern China.     

不同天气型下武汉城市圈PM2.5污染及大气层结特征分析

利用2015—2019年PM_2.5和气象要素观测资料、NCEP和ERA5再分析资料,分析不同天气型下武汉城市圈PM_2.5区域污染时空分布、天气尺度环流和大气层结特征.结果表明,城市圈污染以武汉为中心,多为轻度-中度污染,西部重于东部.造成武汉城市圈区域污染增长的天气形势包括4类,分别为冷高压底前部型、高压后部型、均压场型和低压倒槽型.4类污染天气型均有较低的混合层高度和地表通风系数,且边界层存在弱下沉运动和逆温,抑制污染垂直扩散.但气象要素影响PM_2.5污染的机理各异：冷高压底前部型主要为大气压梯度引导偏北大风带来污染物远程输送,边界层冷平流导致低温、锋面逆温和浅薄高湿层(65%～80%),强输入性污染配合吸湿性累积增长造成严重污染,逆温厚度对PM_2.5增幅作用明显;低压倒槽型东南风输入污染弱,但高温、低压引起气流辐合导致本地污染汇积,边界层暖平流带来平流逆温和深厚湿层(1000～750 hPa),逆温层底高偏低、厚度偏厚,促进污染物在近地面吸湿增长;高压后部和均压场型均为浅薄湿层(1000～975...     

走出环境污染的怪圈——就环境论环境不能解决环境问题

历史的经验告诉我们，就环境论环境不能解决环境问题。本文从分析当今时代的特点出发，剖析了我国环境污染形势，最后论述如何走出环境污染的怪圈．经济增长不等于经济发展，但可持续发展却是永恒的主题．解决环境问题必须改变传统发展战略，发展是硬道理，但我们讲的发展是全社会的持续、协调、全面发展。解振华局长说：“工业污染是环境污染的主要来源”。经济增长的源泉在企业，经济增长的动力是企业利益，经济增长的压力是市场的竞争，经济增长的持续是协调发展。只顾产值不讲效益的观念必须改变，环境问题的解决必须和国家的经济发展、科学技术、社会稳定统一考虑，必须纳入国家整体战略，环境问题才能进步解决。     

论代表性的涵义及工业废水重点源采样方案的设计原则

数据代表性是指监测结果在表征被监测对象特性时所能达到的真实程度;样品代表性是指局部体现整体时所能达到的真实程度。加密监测是重点原调查的质量基础,不能简化行事。监督性监测中,通过测定流量比例混合样来获取总量控制所必需的漉量加权平均值浓度数据,并以此来减小工作量。为满足浓度控制需要,时间—浓度确定型废水的峰浓度样应单独测定。     

长江流域的鱼类资源及其保护对策

长江水系的鱼类约有300种,其中鲤科鱼类占半数以上,主要的经济鱼类多数属于鲤科。对不同江段的鱼类资源作了简介,并提出了相应的保护措施。上游江段以维护生物多样性,保护特有种为主,需要建立鱼类自然保护区;中游应保证主要经济鱼类的自然繁殖条件,加强珍稀鱼类的人工繁殖放流工作,同时对湖泊幼鱼资源进行保护;下游应注意保持江水质量,严格遵守工业废水排放标准;河口江段应规定幼鲟保护期,建议每年6月15日至7月31日停止一切损害幼鲟资源的渔捞作业。