氯苯嘧啶醇在水体中的光解机制研究

以太阳光为实验光源研究了氯苯嘧啶醇在水溶液中的光解,考察了pH、水体类型、溶解氧及卤素离子等对其光解的影响.结果表明,氯苯嘧啶醇在水溶液中的光解符合一级动力学方程,在不同水体中氯苯嘧啶醇光解的速率大小顺序为:重蒸水>水库水>湖水>池塘水;氯苯嘧啶醇光解的半衰期随着溶液pH的增大而延长,当pH为5、7、9、11时光解半衰期分别为5.00、6.86、7.45、7.53 h;3种卤素离子对氯苯嘧啶醇光解有很大的影响,均表现出强的猝灭作用,3种离子的猝灭能力的大小顺序为Ⅰ->Br->Cl-;溶解氧和三重态光猝灭剂山梨酸均对氯苯嘧啶醇在水中的光解没有影响,而三重态光敏剂丙酮则对其光解有较强的猝灭作用,表明氯苯嘧啶醇在水中的光解主要以直接光解为主,光解过程不经历三重态.     

碱渣对锌(Ⅱ)离子吸附特性的研究

研究了锌在碱渣表面的吸附特征.结果表明,碱渣总吸附量随体系温度的升高而降低;随体系 pH 值的升高而增加;随吸附质初始浓度的增加而增大.在 pH<5.51 时其等温吸附能较好地符合 Freudlich 等温吸附规律,而在 pH5.51 时,能较好地符合 Langmuir 等温吸附规律,吸附热随 pH 的增大而升高.当pH≤5.51时,碱渣的吸附力以范德华力平和疏水键力的作用为主,而当 pH6.17 时,以化学键力为主.在 pH 为 5.05、6.07和7.03时,碱渣对 Zn26 的吸附动力学方程都以 Langmuir 方程的拟合效果最优.     

气相色谱法测定水和废水中丙烯腈

本文通过采用气相色谱法,以ＧＤＸ－５０２为固定相,ＦＩＤ为检测器测定水和废水中的丙烯腈,精密度和回收率高．方法简便易行,能满足行业废水和地面水的监队是水和废水中丙烯腈分析的较理想方法。     

Spatio-temporal characteristics of adaptability between crop water requirements for summer maize and rainfall in Henan Province,China

Environmental Science and Pollution Research - It is very important to master the rainfall utilization efficiency and spatial-temporal distribution characteristics in order to improve the...     

Up-regulation of contractile endothelin receptors by airborne fine particulate matter in rat mesenteric arteries via activation of MAPK pathway

Fine particle matters (PM_2.5) is a well-known risk factor for cardiovascular diseases. However, the underlying molecular mechanisms are largely unknown. Vascular hyper-reactivity plays an important roles in the pathogenesis of cardiovascular diseases. The present study was designed to investigate a hypothesis that PM_2.5 up-regulated endothelin receptors in mesenteric artery and the potential underlying mechanisms. Rat mesenteric arteries were cultured with PM_2.5. The artery contractile responses were recorded by a sensitive myograph. ET_B and ET_A receptor expressions of mRNA and protein were assessed by quantitative real-time PCR, Western blotting, and immunohistochemistry, respectively. Results showed that ET_B receptor agonist, sarafotoxin 6c induced a negligible contraction in fresh artery segments, while ET_A receptor agonist, ET-1 induced an obvious contraction. After organ culture, the contraction curve mediated by ET_B and ET_A receptors were shifted toward the left. PM_2.5 1.0 μg/ml cultured for 16 h further enhanced ET_B and ET_A receptor-mediated contractile responses with a markedly increased maximal contraction. The organ culture enhanced ET_B and ET_A receptor mRNA and protein levels from fresh arteries, which were further increased by PM_2.5. The U0126 (MEK/ERK1/2 inhibitor) and SB203580 (p38 inhibitor) significantly attenuated both organ cultured-induced and PM_2.5-induced up-regulation of ET_B receptor. U0126 also suppressed organ culture-increased and PM_2.5-increased expressions of ET_A receptor. SB203580 only suppressed PM_2.5-induced enhanced expressions of ET_A receptor In conclusion, airborne PM_2.5 up-regulates ET_B and ET_A receptors of mesenteric artery via p38 MAPK and MEK/ERK1/2 MAPK pathways.

     

Occurrence,spatial distribution,source, and ecological risk assessment of organochlorine pesticides in Dongting Lake,China

Environmental Science and Pollution Research - The occurrence, distribution, sources, and ecological risks of organochlorine pesticides in Dongting Lake of China were investigated. The average...     

几个涉外火电厂环境影响评价的探讨

近年来我们陆续承接了一些发展中国家电力工程中环境影响评价的招标，议标工作和世界银行（以下简称世行）在国内贷款项目的环境影响评价。本文就工作中所涉及的环境影响评价的深度和广度，执行标准，以及今后工作中有待加强的方面作了一些探讨。     

Prenatal diagnosis of thalassemia major by fetal blood analysis: Experience with 1000 cases

In this report we have summarized our experience with the prenatal diagnosis of β-thalassemia in 1000 pregnancies followed at least until 12 months after birth. In the majority of these cases, the thalassemia lesion was the nonsense mutation at the codon corresponding to amino acid 39, which produces the hematological phenotype of β-thalassemia. Fetal blood sampling was carried out by placental aspiration, by which a sufficient amount of fetal blood for analysis was obtained in the majority of cases (99 per cent). The fetal mortality associated with fetal blood sampling was 6·3 per cent. Those placental samples contaminated by maternal cells were successfully purified by Ørskov lysis. Fetal blood was analysed by globin chain synthesis on CM–52 columns, which gave reliable results. Two misdiagnoses (0·2 per cent) have been made of which one was due to a non-globin protein co-migrating with the β-chains while the other resulted from a misclassification of the type of thalassemia segregating in the family.     

堡子湾金矿同位素及稀土元素地球化学研究

通过对堡子湾金矿矿石、海西期二长花岗 (斑 )岩 -石英二长 (斑 )岩及燕山期花岗班岩的硫、氢、氧、铅同位素及稀土元素地球化学的研究后认为 ,二长花岗 (斑 )岩 -石英二长 (斑 )岩为堡子湾金矿的成矿母岩。     

铁还原中和沉淀法处理TNT酸性废水的研究

研究了处理TNT酸性废水的铁还原中和方法。该法用铁将硝基苯类还原成苯胺类，然后通过石灰乳中和生成Fe(OH)2胶体，吸附苯胺类，达到去除硝基苯类的目的。在过量铁还原60min，中和沉淀pH8—9的最佳条件下，可将废水中的硝基苯类从82．0mg/L降到未检出程度(＜0．2mg/L)，CODcr从394．0mg/L降到94．8mg/L。处理后的废水中的苯胺类也未检出(＜0．03mg/L)。该法的物料消耗费用约为传统的活性碳吸附法的17．5％。