Titanium dioxide as photocatalyst on porous nickel: adsorption and the photocatalytic degradation of sulfosalicylic acid

The commonly used photocatalyst, TiO2 (anatase), has been immobilized on porous nickel using 3 wt.% polyvinyl alcohol (PVA) as the binder. The results show that sulfosalicylic acid (SSal) can be degraded on the developed catalytic system. The adsorption characteristics on TiO2-Ni system have been investigated. The observance of photocalytic degradation of SSal under pH values and initial concentrations can be explained by the adsorption behavior of SSal. The parameters of the Langmuir-Hinshelwood expression have been determined by different experimental ways and the results are satisfactory.     

Fractionation of heavy metals in surface sediments of Taihu Lake, East China

The BCR (European Communities Bureau of Reference) three-step sequential extraction procedure was applied to fractionate heavy metals in the sediment of Taihu Lake. For the determination of total metal concentration of the sediments, sample digestion was achieved by using HF/H2O2/HNO3 (2/1/1) acid mixture in a microwave-irradiated closed vessel system. The concentrations of Cd, Ni, Cr, Zn, Cu and Pb in various extracts solutions were analyzed by Inductively Coupled Plasma Atomic Emission Spectrometry (ICP-AES). The results obtained from the BCR three-step sequential extraction indicated relatively high mobility of Zn, Cu, Pb and Ni in the sediments while Cd and Cr were poorly mobile. Enrichment of heavy metals was found in the sediments collected in the northern parts of Taihu Lake. In the sediments collected in the southern and western sides of the Lake, heavy metal concentrations were relatively low. The relationship between total organic carbon (TOC) and heavy metals concentrations in the sediments is discussed.     

Degradation of benzo[a]pyrene in soil with arbuscular mycorrhizal alfalfa

Mycorrhizal and non-mycorrhizal alfalfa (Medicago sativa) was grown in pots containing soil artificially contaminated with various levels of benzo[a]pyrene (B[a]P) (0, 1, 10 and 100 mg kg(-1)). Soil and plants were sampled after 30, 40, 50, 60 and 90 days and compared with unlanted pots. The percentage of mycorrhizal root length colonized by Glomus caledoniun was not significantly affected by the addition of B[a]P up to 10 mg kg(-1) but was significantly lower at 100 mg kg(-1)B[a]P compared with low concentrations (p < 0.05). There was no difference in soil polyphenol oxidase and dehydrogenase activity among the controls and applications of 1 and 10 mg kg(-1) of B[a]P. However, enzyme activities were significantly higher at 100 mg kg(-1) B[a]P compared with the other three treatments, and there was no mycorrhizal effect. Over a period of 90 days the concentration of B[a]P in soil in which alfalfa was grown was significantly lower than in unplanted soil (p < 0.05). Degradation rates of B[a]P added at 1, 10 and 100 mg kg(-1) without G. caledonium were 76, 78 and 53%, and with mycorrhizal inoculation were 86, 87 and 57%. The degradation rate in unplanted soil was significantly lower than in planted soil, and was significantly higher in medium- and low-B[a]P treatments than in the high B[a]P concentration tested. There is a possibility of enhancement phytoremediation of PAHs in rhizosphere soil with arbuscular mycorrhizal fungi.     

Degradation of Benzo[a]Pyrene in Soil with Arbuscular Mycorrhizal Alfalfa

Mycorrhizal and non-mycorrhizal alfalfa (Medicago sativa) was grown in pots containing soil artificially contaminated with various levels of benzo[a]pyrene (B[a]P)(0, 1, 10 and 100 mg kg^–1). Soil and plants were sampled after 30, 40, 50, 60 and 90 days and compared with unlanted pots. The percentage of mycorrhizal root length colonized by Glomus caledoniun was not significantly affected by the addition of B[a]P up to 10 mg kg^–1 but was significantly lower at 100 mg kg^–1B[a]P compared with low concentrations (p < 0.05). There was no difference in soil polyphenol oxidase and dehydrogenase activity among the controls and applications of 1 and 10 mg kg^–1 of B[a]P. However, enzyme activities were significantly higher at 100 mg kg^–1B[a]P compared with the other three treatments, and there was no mycorrhizal effect. Over a period of 90 days the concentration of B[a]P in soil in which alfalfa was grown was significantly lower than in unplanted soil (p < 0.05). Degradation rates of B[a]P added at 1, 10 and 100 mg kg^–1 without G. caledonium were 76, 78 and 53%, and with mycorrhizal inoculation were 86, 87 and 57%. The degradation rate in unplanted soil was significantly lower than in planted soil, and was significantly higher in medium- and low-B[a]P treatments than in the high B[a]P concentration tested. There is a possibility of enhancement phytoremediation of PAHs in rhizosphere soil with arbuscular mycorrhizal fungi.     

浅谈浮雕装饰件成型落料复合工艺

论述聚氨脂橡胶及锌合金用于浮雕件成型落料工艺特点,模具设计和制造特点.     

ADMS仿真模拟在总量控制中的应用

ADMs是新一代的大气扩散模型，用来评估空气污染扩散的问题。抚顺市2004年采取了大气污染治理措施并使用ADMs模型予以评估。仿真模拟的结果表明各项措施的效果并不和治理时的投资成比例，也不和污染物的削减总量成比例．说明治理过程中的科学性和经济性不够理想，也表明总量控制方针在实施中有许多实际问题需要解决。     

弯头拉延模的设计

弯头是某产品上的关键零件之一,用冲模成形为最佳方案。此文分析弯头的拉延工艺性,介绍弯头拉延模的结构特点,并提出在设计、制造、使用弯头拉延模时应重视的几个问题。对成批生产同类零件的单位具有较高的参考价值。     

离子强度、pH值和Ca2+/Al3+对马尾松幼苗的铝毒影响

测定了在不同溶液酸度、不同离子强度和Ca²⁺/Al³⁺比下,铝对马尾松幼苗生长状况的影响。结果表明,溶液酸度增加,离子强度减小时,铝的毒害作用增大。钙对铝毒有明显缓解作用,当Ca²⁺/Al³⁺增大时,铝的毒性减小,但其缓解作用与铝浓度有关,当铝浓度增加,钙的缓解能力下降。     

小清河流域地下水水质状况评价与对策

对滨州市境内小清河流域地下水水质状况进行分析评价.结果表明,滨州市境内小清河流域地下水水质总体较差.在评价滨州市境内小清河流域地下水水质状况的基础上,提出了保护地下水的对策和建议.     

轧钢废水全循环综合利用经济效益分析

轧钢厂废水全循环综合利用改造项目的确定，从项目设备投资，运转费用投资以及项目建成后节约用水，减少排污费等方面，阐述微观产生的经济效益，宏观产生的环境效益，揭示了该项目带来的积极影响。