COALBED METHANE PRODUCT WATER CHEMISTRY IN THREE WYOMING WATERSHEDS1

ABSTRACT: The Powder River Basin in Wyoming has become one of the most active areas of coalbed methane (CBM) development in the western United States. Extraction of methane from coalbeds requires pumping of aquifer water, which is called product water. Two to ten extraction wells are manifolded into one discharge point and product water is released into nearby unlined holding ponds. The objective of this study was to evaluate the chemistry, salinity, and sodicity of CBM product water at discharge points and associated holding ponds as a function of watershed. The product water samples from the discharge points and associated holding ponds were collected from the Cheyenne River (CHR), Belle Fourche River (BFR), and Little Powder River (LPR) watersheds during the summers of 1999 and 2000. These samples were analyzed for pH, electrical conductivity (EC), total dissolved solids (TDS), alkalinity, sodium (Na), calcium (Ca), magnesium (Mg), potassium (K), sulfate (SO₄^2‐), and chloride (C^1‐). From the chemical data, practical sodium adsorption ratio (SARp) and true sodium adsorption ratio (SARt) were calculated for the CBM discharge water and pond water. The pH, EC, TDS, alkalinity, Na, Ca, Mg, K, SARp, and SARt of CBM discharge water increased significantly moving north from the CHR watershed to the LPR watershed. CBM discharge water in associated holding ponds showed significant increases in EC, TDS, alkalinity, Na, K, SARp, and SARt moving north from the CHR to the LPR watershed. Within watersheds, the only significant change was an increase in pH from 7.21 to 8.26 between discharge points and holding ponds in the LPR watershed. However, the LPR and BFR exhibited larger changes in mean chemistry values in pH, salinity (EC, TDS), and sodicity (SAR) between CBM product water discharges and associated holding ponds than the CHR watershed. For instance, the mean EC and TDS of CBM product water in LPR increased from 1.93 to 2.09 dS/m, and froml,232 to 1,336 mg/L, respectively, between discharge and pond waters. The CHR exhibited no change in EC, TDS, Na, or SAR between discharge water and pond water. Also, while not statistically significant, mean alkalinity of CBM product water in BFR and LPR watersheds decreased from 9.81 to 8.01 meq/L and from 19.87 to 18.14 meq/L, respectively, between discharge and pond waters. The results of this study suggest that release of CBM product water onto the rangelands of BFR and LPR watersheds may precipitate calcium carbonate (CaCO₃) in soils, which in turn may decrease infiltration and increase runoff and erosion. Thus, use of CBM product water for irrigation in LPR and BFR watersheds may require careful planning based on water pH, EC, alkalinity, Na, and SAR, as well as local soil physical and chemical properties.     

STREAM DISCHARGE PREDICTION VIA A GRID BASED SOIL WATER ROUTING WITH PADDY FIELDS1

ABSTRACT: A grid based daily hydrologic model for a watershed with paddy fields was developed to predict the stream discharge. ASCII formatted elevation, soil, and land use data supported by the GRASS Geographic Information System are used to generate distributed results such as surface runoff and subsurface flow, soil water content, and evapotranspiration. The model uses a single flow path algorithm and simulates a water balance at each grid element. A linear reservoir assumption was used to predict subsurface runoff components. The model was applied to a 75.6 km² watershed located in the middle of South Korea, and observed stream flow hydrographs from 1995 and 1996 were compared to model predictions. The stream flow predictions of 1995 and 1996 generally agreed with the observed flow, resulting in a Nash‐Sutcliffe efficiency R² of 0.60 and 0.62, respectively. The hydraulic conductivity for percolating water through the saturated layer affected baseflow generation. The levee height of the paddy influenced the time and magnitude of the surface runoff, depending on irrigation management. The model will be used for making low flow management decisions by evaluating the role of each land use to stream flow, especially in case of paddy decrease by gradual urbanization of a watershed.     

GROUND WATER NITRATE REDUCTION IN GIANT CANE AND FOREST RIPARIAN BUFFER ZONES1

ABSTRACT: Ground water contamination by excess nitrate leaching in row‐crop fields is an important issue in intensive agricultural areas of the United States and abroad. Giant cane and forest riparian buffer zones were monitored to determine each cover type's ability to reduce ground water nitrate concentrations. Ground water was sampled at varying distances from the field edge to determine an effective width for maximum nitrate attenuation. Ground water samples were analyzed for nitrate concentrations as well as chloride concentrations, which were used as a conservative ion to assess dilution or concentration effects within the riparian zone. Significant nitrate reductions occurred in both the cane and the forest riparian buffer zones within the first 3.3 m, a relatively narrow width. In this first 3.3 m, the cane and forest buffer reduced ground water nitrate levels by 90 percent and 61 percent, respectively. Approximately 40 percent of the observed 99 percent nitrate reduction over the 10 m cane buffer could be attributed to dilution by upwelling ground water. Neither ground water dilution nor concentration was observed in the forest buffer. The ground water nitrate attenuation capabilities of the cane and forest riparian zones were not statistically different. During the spring, both plant assimilation and denitrification were probably important nitrate loss mechanisms, while in the summer nitrate was more likely lost via denitrification since the water table dropped below the rooting zone.     

COLD WATER PATCHES IN WARM STREAMS: PHYSICOCHEMICAL CHARACTERISTICS AND THE INFLUENCE OF SHADING1

ABSTRACT: Discrete cold water patches within the surface waters of summer warm streams afford potential thermal refuge for cold water fishes during periods of heat stress. This analysis focused on reach scale heterogeneity in water temperatures as influenced by local influx of cooler subsurface waters. Using field thermal probes and recording thermistors, we identified and characterized cold water patches (at least 3°C colder than ambient streamflow temperatures) potentially serving as thermal refugia for cold water fishes. Among 37 study sites within alluvial valleys of the Grande Ronde basin in northeastern Oregon, we identified cold water patches associated with side channels, alcoves, lateral seeps, and floodplain spring brooks. These types differed with regard to within floodplain position, area, spatial thermal range, substrate, and availability of cover for fish. Experimental shading cooled daily maximum temperatures of surface waters within cold water patches 2 to 4°C, indicating a strong influence of riparian vegetation on the expression of cold water patch thermal characteristics. Strong vertical temperature gradients associated with heating of surface layers of cold water patches exposed to solar radiation, superimposed upon vertical gradients in dissolved oxygen, can partially restrict suitable refuge volumes for stream salmonids within cold water patches.     

秦皇岛市开发区生活污水利用可行性分析

本文通过对秦皇岛经济技术开发区居民小区生活污水进行处理并回用的可行性分析,得出城市生活污水经过适当处理后,完全可以再利用,从而达到节约水资源的目的,实现经济效益与环境效益的统一。     

提高化学需氧量质控合格率的研究

大庆油田化工总厂废水中化学需氧量（COD）的测定采用库仑法。为了提高质控合格率，从人员素质、仪器设备、电级内液等9个方面分析寻找导致误差的主要影响因素并制定对策。同时对影响电极内液及消解的因素进行正交实验确定最佳条件。结果使库仑法质控合格率由90％提高到95％，测定38次标样全部合格。     

Climate Convention Implementation: An Opportunity for the Pacific Island Nations to Move Toward Sustainable Energy Systems

This article does not focus on adaptation or mitigation policy directly but on an allied opportunity that exists for the Pacific Islands via the auspices of the Climate Convention, because the existing very costly energy systems used in the Pacific Island region are fossil-fuel dependent. It is argued here that efforts can be made towards the development of energy systems that are ecologically sustainable because Pacific Island nations are eligible to receive assistance to introduce renewable energy technology and pursue energy conservation via implementation mechanisms of the Climate Convention and, in particular, through transfer of technology and via joint implementation. It is contended that assistance in the form of finance, technology, and human resource development from developed countries and international organizations would provide sustainable benefits in improving the local Pacific Island environments. It is also emphasized that mitigation of greenhouse gas emissions is not the responsibility of the Pacific Islands as they contribute very little on a per capita global scale and a tiny proportion of total global greenhouse gas emissions.     

Environmental reporting for global higher education institutions using the World Wide Web

Voluntary environmental reporting on the progress achieved against policy objectives is an emerging trend in industry and business and is recognized as a valuable aid in implementing policy and improving environmental management systems. Environmental reporting in the UK, has a whole range of formats including PERI, GEMI, WICE and EMAS, with the last, in particular, aiming to improve the level of environmental stewardship and to increase the flow of environmental information to audiences both internally and externally. Higher education institutions globally have been slow to respond in this respect and there is much that they can learn from corporate environmental reporting. An environmental policy is not sufficient proof of commitment for those institutions who have signed the global Talloires Declaration or the European COPERNICUS Charter: demonstrable progress in policy implementation is essential. The environmental management systems that higher education institutions adopt or create and the ways in which their environmental information is collated are of great significance, but the medium selected for the report is perhaps one of the most important aspects to consider. Those institutions such as the University of Sunderland, UK who are using the World Wide Web have been able to produce a flexible, hypertext-linked service on request with inbuilt feedback mechanisms containing varied, up-to-date, comprehensive and well-structured environmental information signposted to external pro-active institutions and agencies. These reports have unique educational angles and reveal links and networks that are naturally more pervasive and far-reaching in their scope and impact and could well provide a key way forward to practical and sustainable environmental reporting into the millennium.     

A Sensitivity Analysis of Nitrogen Losses from Dairy Farms

International attention has focused on agricultural production systems as non-point sources of pollution affecting the quality of streams, estuaries and ground water resources. The objective of the current study was to develop a model of nitrogen management on the dairy farm, and to perform sensitivity analyses in order to determine the relative importance of manipulating herd nutrition, manure management and crop selection in reducing nitrogen (N) losses from the farm. The importance of the method of N input to the farm (purchased feed, legume fixation, inorganic fertilizer, imported manure) was investigated, and the potential to reduce N losses from dairy farms was evaluated. Nitrogen balance equations were derived, and related efficiency coefficients were set to reference values representing common management practices. Total farm N efficiency (animal product N per N input), and N losses per product N were determined for different situations by solving the set of simultaneous equations. Improvements in animal diet and management that increase the conversion of feed N to animal product by 50% would increase total farm N efficiency by 48% and reduce N losses per product by 36 to 40%. In contrast, reducing losses from manure collection, storage and application to improve the percentage of manure N that becomes available in soil by 100% would only improve total farm N efficiency by 13% and reduce total N losses by 14%. Selecting crops and management that can use soil nutrients 50% more efficiently would improve total farm efficiency by up to 59% and reduce N losses by up to 41% depending on the predominant nitrogen sources to the farm. Legume production would reduce N losses per product compared with non-legumes. There was more than a five fold difference in N losses per animal product N between the most extreme scenarios suggesting considerable opportunity to reduce N losses from dairy farms.     

新型混凝剂SLB的制备及应用

新型混凝剂SLB是将聚铝和阳离子改性淀粉在一定条件下直接复配而成的一种无机-有机复合型混凝剂，通过对炼油厂及钠土污水的混凝处理实验，反映出SLB具有较好的净化效果。此外，SLB原料易得，成本低，有广阔的应用前景。