Effect of some environmentally degradable materials on the pyrolysis of plastics II: influence of cellulose and lignin on the pyrolysis of complex mixtures

Pyrolysis of polymer mixtures with a composition similar to that of municipal plastic waste containing polyvinyl chloride (PVC) and of municipal plastic waste free of PVC was performed in the presence of components of biomass, namely lignin, cellulose, or both. The pyrolysis products were characterized by standard methods utilized in the petrochemical industry, i.e., paraffins-isoparaffinsolefins-naphthenes-aromatics analysis, proton nuclear magnetic resonance and infrared spectroscopy, and gas chromatography-mass spectrometry. Up to 3 wt% lignin, cellulose, or both in mixed polymers changed the material balance of pyrolysis by decreasing the amount of waxy products. The presence of both PVC and biomass components significantly changed the material balance by decreasing the waxy product yield and increasing the gas and coke yield. The composition of all pyrolysis products was also modified with the addition of PVC, components of biomass, or both.     

Feedstock recycling from plastic and thermoset fractions of used computers (I): pyrolysis

The increasing production of computers, the progress in their performance, and the shorter time between innovation and production has led to increasing numbers of obsolete products. It has thus become necessary to recover some materials from old computers and to protect the environment from a new type of pollution. Such recycling is difficult because of the diversity of polymeric materials used, e.g., thermoplastics (polystyrene or acrylonitrile-butadiene-styrene) and thermosets (epoxy resins), and the relatively high levels of flame retardants (halogen- and nitrogen-containing compounds) added during production. Pyrolysis seems to be a suitable way to recover materials and energy from such waste without component separation if an efficient method for reducing toxic compounds can be applied. In this study, the pyrolysis of plastic and thermoset fractions (keyboards, casings, printed circuit boards, and mixtures thereof) of used computers was studied by thermogravimetry and batch reactor pyrolysis. The degradation products were separated into three fractions, solid, liquid, and gaseous, each of them being characterized by suitable methods such as gas chromatography (GC-MSD, gas chromatography-mass spectrometry detection; GC-AED, gas chromatography-atomic emission detection), infrared (FT-IR) and 1H-NMR (nuclear magnetic resonanace) spectroscopy, and elemental analysis. It has been established that most of the halogens, nitrogen, and sulfur is concentrated in the residue. However, the elimination of hazardous toxic compounds, mainly those containing bromine, is necessary before being able to safely use the pyrolysis oils as fuels or in refinery or petrochemical industry flows.     

Ten years of international scientific cooperation in fisheries,aquaculture and coastal zones: some preliminary lessons

The paper examines preliminary experiences with international scientific cooperation in fisheries, aquaculture and coastal zone issues through 90 projects in successive European Research Framework Programmes (FP4–FP6: 1994–2006). FPs had increasingly ambitious objectives in response to international commitments, such as the Convention on Biological Diversity, the Millennium Development Goals, the Johannesburg Plan of Implementation and dialogue with partner regions. Sustainable aquatic food production in the context of respect for ecosystems was a central concern. Engagement with different social actors and attention to investment in education, people and institutions enabled uptake of research results in education, innovation and some impact. The emphasis in several recent projects on more integrated analyses and knowledge products in the public domain is an encouraging response to the growing crisis of aquatic resource systems. It is suggested that significant up-scaling will be required. This might be done through institutional internalisation and better translation of research results into policy developments supportive of transitions towards sustainable production systems and ecosystem rehabilitation. Capacity building to use research in novel ways and other enabling mechanisms need to be put in place to increase societal and environmental benefits of the research.

From meso- to macro-scale dynamic water quality modelling for the assessment of land use change scenarios

The implementation of the European Water Framework Directive requires reliable tools to predict the water quality situations in streams caused by planned land use changes at the scale of large regional river basins. This paper presents the results of modelling the in-stream nitrogen load and concentration within the macro-scale basin of the Saale river (24,167 km²) using a semi-distributed process-based ecohydrological dynamic model SWIM (Soil and Water Integrated Model). The simulated load and concentration at the last gauge of the basin show that SWIM is capable to provide a satisfactory result for a large basin. The uncertainty analysis indicates the importance of realistic input data for agricultural management, and that the calibration of parameters can compensate the uncertainty in the input data to a certain extent. A hypothesis about the distributed nutrient retention parameters for macro-scale basins was tested aimed in improvement of the simulation results at the intermediate gauges and the outlet. To verify the hypothesis, the retention parameters were firstly proved to have a reasonable representation of the denitrification conditions in six meso-scale catchments. The area of the Saale region was classified depending on denitrification conditions in soil and groundwater into three classes (poor, neutral and good), and the distributed parameters were applied. However, the hypothesis about the usefulness of distributed retention parameters for macro-scale basins was not confirmed. Since the agricultural management is different in the sub-regions of the Saale basin, land use change scenarios were evaluated for two meso-scale subbasins of the Saale. The scenario results show that the optimal agricultural land use and management are essential for the reduction in nutrient load and improvement of water quality to meet the objectives of the European Water Framework Directive and in view of the regional development plans for future.     

Conflict-involvement of male guinea pigs (<Emphasis Type="Italic">Cavia aperea</Emphasis> f. <Emphasis Type="Italic">porcellus</Emphasis>) as a criterion for partner preference

Polygynous mating systems can inflict considerable costs on males, often causing the emergence of alternative mating strategies to ensure reproductive success. These strategies can lead to different morphs of color, size, or behavior. The present work was done on guinea pigs, a polygynous rodent species. Some males can show a reduced readiness for conflict, perhaps employing an alternative mating strategy. To test this hypothesis, a two-stage experiment was set up, with males (N = 16) and females (N = 16) initially living in isosexual groups. Visual and olfactory contact was possible through a wire mesh. Male agonistic behavior was observed for 15 days, confirming the existence of less-conflict-involved (LCI, N = 7) and more-conflict-involved males (MCI, N = 9). Significant differences were found for a conditional parameter, body mass, and a morphometric one, testis width: LCI consistently surpassed MCI. Hormonally, cortisol was comparable, while testosterone was distinctly higher in MCI. Next, males and females were joined and observed for further 24 days. Males initially lost weight but reached original mass towards the end of the experiment. Testis width patterns were similar. Again, LCI had higher body mass. Cortisol was comparable, but testosterone release 3 days after merging was significantly higher in LCI. Behaviorally, LCI exhibited significantly less male–male aggression and more socio-sexual behavior than MCI. The former were more successful, with 57% capable of accessing females, in contrast to 11% of MCI. The existence of two distinct behavioral phenotypes in guinea pig males suggests that different reproductive strategies may exist in this species.     

Large males dominate: ecology,social organization,and mating system of wild cavies,the ancestors of the guinea pig

Ecological factors differently affect male and female animals and thereby importantly influence their life history and reproductive strategies. Caviomorph rodents are found in a wide range of habitats in South America and different social and mating systems have evolved in closely related species. This permits to study the impact of ecological factors on social evolution. In this study, we investigated the social organization and the mating system of the wild cavy (Cavia aperea), the ancestor of the domestic guinea pig, in its natural habitat in Uruguay. Based on our laboratory investigations, we expected a polygynous system with large males controlling access to females. Results from radiotelemetry and direct observations showed that females occupied small stable home ranges which were largely overlapped by that of one large male, resulting in a social organization of small harems. In some cases, small satellite males were associated with harems and intermediate-sized roaming males were occasionally observed on the study site. However, microsatellite analyses revealed that offspring were exclusively sired by large males of the same or neighboring harems, with a moderate degree of multiple paternity (13–27%). Thus, the mating system of C. aperea can be described as polygynous and contrasts with the promiscuous organization described for other species of cavies (Cavia magna, Galea musteloides and Microcavia australis) living under different ecological conditions. Our findings stress the strong impact of environmental factors on social evolution in Caviomorphs as resource distribution determines female space use and, thereby, the ability of males to monopolize females. Electronic supplementary material  The online version of this article (doi:) contains supplementary material, which is available to authorized users.     

Long-Term Effects of Grazing and Global Warming on the Composition and Carrying Capacity of Graminoid Marshes for Moulting Geese in East Greenland

Greening of the Arctic due to climate warming may provide herbivores with richer food supplies, resulting in higher herbivore densities. In turn, this may cause changes in vegetation composition and ecosystem function. In 1982-1984, we studied the ecology of non-breeding moulting geese in Jameson Land, low Arctic East Greenland. By then, geese consumed most of the graminoid production in available moss fens, and it appeared that the geese had filled up the available habitat. In 2008, we revisited the area and found that the number of moulting geese and the temperature sum for June-July had tripled, while the above-ground biomass in a moss fen ungrazed by geese had more than doubled. In a goose-grazed fen, the overall plant composition was unchanged, but the frequency of graminoids had decreased and the area with dead vegetation and open spots had increased. We suggest that climate warming has lead to increased productivity, allowing for higher numbers of moulting geese. However, the reduction of vegetation cover by grazing may have longer term negative consequences for the number of geese the habitat can sustain.     

Catalytic oxidation processes for removing dimethylsulfoxide from wastewater

An effective method for removing dimethylsulfoxide (DMSO) from wastewater, based on the mild selective catalytic sulfoxidation with H(2)O(2), is proposed in this study. The catalysts are W-containing layered double hydroxides (LDH), and they were obtained by ionic exchange of the nitrate anions from MAl-LDH precursors (M=Mg(2+) or Zn(2+)) with both WO(4)(2-) and W(7)O(24)(6-) species. Results of X-ray diffraction (XRD), N(2) adsorption, thermal gravimetric analysis (TGA), diffuse reflectance ultraviolet spectroscopy (DRUV) and Raman spectroscopy confirmed the formation of the W-oxospecies inside the interlayer space and the modification of the textural properties upon the exchange process. All catalysts showed very good activity and stability in the DMSO conversion into dimethylsulfone with dilute H(2)O(2) aqueous solution, at low temperatures (20-50 degrees C). The efficiency of the H(2)O(2) was higher than 95% and the behaviour of the water as solvent was very close to that of the organic solvents (ethanol, acetonitrile, 1,4-dioxane).