Fouling distribution in forward osmosis membrane process

Fouling behavior along the length of membrane module was systematically investigated by performing simple modeling and lab-scale experiments of forward osmosis （FO） membrane process. The flux distribution model developed in this study showed a good agreement with experimental results, validating the robustness of the model. This model demonstrated, as expected, that the permeate flux decreased along the membrane channel due to decreasing osmotic pressure differential across the FO membrane. A series of fouling experiments were conducted under the draw and feed solutions at various recoveries simulated by the model. The simulated fouling experiments revealed that higher organic （alginate） fouling and thus more flux decline were observed at the last section of a membrane channel, as foulants in feed solution became more concentrated. Furthermore, the water flux in FO process declined more severely as the recovery increased due to more foulants transported to membrane surface with elevated solute concentrations at higher recovery, which created favorable solution environments for organic adsorption. The fouling reversibility also decreased at the last section of the membrane channel, suggesting that fouling distribution on FO membrane along the module should be carefully examined to improve overall cleaning efficiency. Lastly, it was found that such fouling distribution observed with co-current flow operation became less pronounced in counter- current flow operation of FO membrane process.     

泰国和越南的产业改革和养虾业通向生态、社会及经济可持续发展的道路

越南的养虾业正处在对生产体系的基础改造,使其转变成一个重要产业的过程中.该地区其他国家的经验,特别是高投入生产体系占主导地位的泰国的经验表明,现在正是通过干预使养虾业改道进入在生态、社会和经济上更可持续的道路.在泰国,实施强化的体系和复杂的产业组织的多年经验并没有获得可持续的解决办法.这里所面临的任务是使社会重新赢得控制并沿着更有效和良性发展的道路改变改革的发展方向.我们的分析结果表明,这两个国家的现行方法不可能使养虾业可持续的发展,需要对整个对虾的生产、喂养、加工、供销及管理的方式进行全面改革.     

Evaluation of the relationship between two different methods for enumeration fecal indicator bacteria： Colony-forming unit and most probable number

Most probable number (MPN) and colony-forming unit (CFU) estimates of fecal indicator bacteria (FIB) concentration are common measures of water quality in aquatic environments. Thus, FIB intensively monitored in Yeongsan Watershed in an attempt to compare two di erent methods and to develop a statistical model to convert from CFU to MPN estimates or vice versa. As a result, the significant di erence was found in the MPN and CFU estimates. The enumerated Escherichia coli concentrations in MPN are greater than those in CFU, except for the measurement in winter. Especially in fall, E. coli concentrations in MPN are one order of magnitude greater than that in CFU. Contrarily, enterococci bacteria in MPN are lower than those in CFU. However, in general, a strongly positive relationship are found between MPN and CFU estimates. Therefore, the statistical models were developed, and showed the reasonable converting FIB concentrations from CFU estimates to MPN estimates. We expect this study will provide preliminary information towards future research on whether di erent analysis methods may result in di erent water quality standard violation frequencies for the same water sample.     

Influence of Indian mustard （Brassicajuncea） on rhizosphere soil solution chemistry in long-term contaminated soils： A rhizobox study

This study investigated the influence of Indian mustard (Brassica juncea) root exudation on soil solution properties (pH, dissolved organic carbon (DOC), metal solubility) in the rhizosphere using a rhizobox. Measurement was conducted following the cultivation of Indian mustard in the rhizobox filled four di erent types of heavy metal contaminated soils (two alkaline soils and two acidic soils). The growth of Indian mustard resulted in a significant increase (by 0.6 pH units) in rhizosphere soil solution pH of acidic soils and only a slight increase (< 0.1 pH units) in alkaline soils. Furthermore, the DOC concentration increased by 17–156 mg/L in the rhizosphere regardless of soil type and the extent of contamination, demonstrating the exudation of DOC from root. Ion chromatographic determination showed a marked increase in the total dissolved organic acids (OAs) in rhizosphere. While root exudates were observed in all soils, the amount of DOC and OAs in soil solution varied considerably amongst di erent soils, resulting in significant changes to soil solution metals in the rhizosphere. For example, the soil solution Cd, Cu, Pb, and Zn concentrations increased in the rhizosphere of alkaline soils compared to bulk soil following plant cultivation. In contrast, the soluble concentrations of Cd, Pb, and Zn in acidic soils decreased in rhizosphere soil when compared to bulk soils. Besides the influence of pH and DOC on metal solubility, the increase of heavy metal concentration having high stability constant such as Cu and Pb resulted in a release of Cd and Zn from solid phase to liquid phase.     

Improving construction site safety through leader-based verbal safety communication

Background

The construction industry is one of the most injury-prone industries, in which production is usually prioritized over safety in daily on-site communication. Workers have an informal and oral culture of risk, in which safety is rarely openly expressed. This paper tests the effect of increasing leader-based on-site verbal safety communication on the level of safety and safety climate at construction sites. Method: A pre-post intervention-control design with five construction work gangs is carried out. Foremen in two intervention groups are coached and given bi-weekly feedback about their daily verbal safety communications with their workers. Foremen-worker verbal safety exchanges (experience sampling method, n = 1,693 interviews), construction site safety level (correct vs. incorrect, n = 22,077 single observations), and safety climate (seven dimensions, n = 105 questionnaires) are measured over a period of up to 42 weeks. Results: Baseline measurements in the two intervention and three control groups reveal that foremen speak with their workers several times a day. Workers perceive safety as part of their verbal communication with their foremen in only 6-16% of exchanges, and the levels of safety at the sites range from 70-87% (correct observations). Measurements from baseline to follow-up in the two intervention groups reveal that safety communication between foremen and workers increases significantly in one of the groups (factor 7.1 increase), and a significant yet smaller increase is found when the two intervention groups are combined (factor 4.6). Significant increases in the level of safety are seen in both intervention groups (7% and 12% increases, respectively), particularly in regards to 'access ways' and 'railings and coverings' (39% and 84% increases, respectively). Increases in safety climate are seen in only one of the intervention groups with respect to their 'attention to safety.' No significant trend changes are seen in the three control groups on any of the three measures. Conclusions: Coaching construction site foremen to include safety in their daily verbal exchanges with workers has a significantly positive and lasting effect on the level of safety, which is a proximal estimate for work-related accidents. It is recommended that future studies include coaching and feedback at all organizational levels and for all involved parties in the construction process. Building client regulations could assign the task of coaching to the client appointed safety coordinators or a manager/supervisor, and studies should measure longitudinal effects of coaching by following foremen and their work gangs from site to site.     

Development of conflict techniques for left-turn and cross-traffic at protected left-turn signalized intersections

To design comprehensive traffic safety measures, the risk of the occurrence of traffic accidents must be objectively evaluated. It is difficult, however, to evaluate the effects of traffic measures in terms of the change in the number of traffic accidents, because traffic accidents are unpredictable and rare events. Therefore, this study used a traffic conflict technique to objectively evaluate traffic safety at intersections. In this study, traffic conflicts that occur at the time of a signal violation were differentiated according to type, and a traffic conflict technology was developed that would consider the severity of each type of conflict. To apply this method, traffic images were collected from the Jungja intersection and the Naejung intersection in Sungnam City, Korea and were analyzed using traffic data by means of image procedure technology. The analyses showed that of the four levels of differentiated conflict conditions, the Level 1 condition occurred most often, followed by Level 2, which occurred much less frequently than Level 1. Level 3 (serious conflicts) and Level 4 (dangerous conflicts: accidents) conditions were not detected.     

Neanderthal medics? Evidence for food, cooking, and medicinal plants entrapped in dental calculus

Neanderthals disappeared sometime between 30,000 and 24,000?years ago. Until recently, Neanderthals were understood to have been predominantly meat-eaters; however, a growing body of evidence suggests their diet also included plants. We present the results of a study, in which sequential thermal desorption-gas chromatography-mass spectrometry (TD-GC-MS) and pyrolysis-gas chromatography-mass spectrometry (Py-GC-MS) were combined with morphological analysis of plant microfossils, to identify material entrapped in dental calculus from five Neanderthal individuals from the north Spanish site of El Sidrón. Our results provide the first molecular evidence for inhalation of wood-fire smoke and bitumen or oil shale and ingestion of a range of cooked plant foods. We also offer the first evidence for the use of medicinal plants by a Neanderthal individual. The varied use of plants that we have identified suggests that the Neanderthal occupants of El Sidrón had a sophisticated knowledge of their natural surroundings which included the ability to select and use certain plants.     

Toxic metals in amniotic fluid and altered gene expression in cell-free fetal RNA

Both exposures to toxic metals, as well as deficiencies in essential metals, during pregnancy has been linked to a variety of negative reproductive outcomes. The exact etiologies of such outcomes and the effects of fetal exposure to these metals are largely unknown. Therefore, the ability to assess levels of these elements is critical to determining the underlying causes of such conditions and the effects that both essential and nonessential metals have on fetal development. Thus, using cell-free fetal RNA from amniotic fluid, we set out to measure the association between amniotic fluid levels of toxic and essential metals and fetal gene expression. We find that arsenic was associated with increased expression of 3 genes known to play roles in both birth-related and reproductive effects. The results highlight the potential for detrimental health effects of prenatal metals exposure and the potential to identify biomarkers of environmental exposure during this critical developmental period.     

Mini-review on river eutrophication and bottom improvement techniques,with special emphasis on the Nakdong River

Water quality in rivers is vital to humans and to maintenance of biotic and ecological integrity. During the Four Major Rivers restoration of South Korea, remarkable attempts have been made to decrease external nutrient loads and moveable weirs were designed to discharge silt that may deposit in pools. However, recently eutrophication of the Nakdong River, which was limited to the lower reaches, is seen to be spreading upstream. The reduction of external nutrient loads to rivers is a long-term goal that is unlikely to lead to reductions in algal blooms for many years because of the time required to implement effective land management strategies. It would therefore be desirable to implement complementary strategies. Regulating the amount of water released is effective at preventing algae blooms in weir pools; so, the relationship between discharge, stratification and bloom formation should be understood in this regard. However, pollutants are likely to accumulate in the riverbed upstream from release points. Thus, to control phosphorus levels, total phosphorus density should be lowered by applying in-river techniques as well. As many ecosystem properties are controlled by multiple processes, simultaneous river bottom improvement techniques, such as combined dissolved oxygen supply and nutrient inactivation, are likely to be effective. The purpose of this review is to present a series of technological approaches that can be used to improve the river bottom area and hence sediment nutrient release, and to illustrate the application of these techniques to the Nakdong River.