Elemental mobility in sulfidic mine tailings reclaimed with paper mill by-products as sealing materials

Environmental Science and Pollution Research - Sealing layers made of two alkaline paper mill by-products, fly ash and green liquor dregs, were placed on top of 50-year-old sulfide-containing...     

Protease production by the keratinolytic Bacillus sp. CL18 through feather bioprocessing

Bacillus sp. CL18 was investigated to propose a bioprocess for protease production using feathers as organic substrate. In feather broth (FB), containing feathers as sole organic substrate (1–100 g l^?1), maximal protease production was observed at 30 g l^?1 (FB30) after 6 days of cultivation, whereas increased feather concentrations negatively affected protease production and feather degradation. Protease production peaks were always observed earlier during cultivations than maximal feather degradation. In FB30, 80% of initial feathers mass were degraded after 7 days. Addition of glucose, sucrose, starch, yeast extract (2 g l^?1), CaCl₂, or MgCl₂ (10 mmol l^?1) to FB30 decreased protease production and feather degradation. FB30 supplementation with NH₄Cl (1 g l^?1) resulted in less apparent negative effects on protease production, whereas peptone (2 g l^?1) increased protease yields earlier during cultivations (3 days). Through a central composite design employed to investigate the effects of peptone and NH₄Cl (0.5–4.5 g l^?1) on protease production and feather degradation, FB30 supplementation with peptone and NH₄Cl (0.5–1.1 g l^?1) increased protease production within a shorter cultivation time (5 days) and hastened complete feather degradation (6 days). Feather bioconversion concurs with sustainable production of value-added products.

     

Sediments as a sink for UV filters and benzotriazoles: the case study of Upper Iguaçu watershed,Curitiba (Brazil)

Ingredients in home and personal care products, including UV filters and benzotriazoles, are high production volume chemicals extensively used in our daily life, despite several studies revealed their potential eco-toxicity and endocrine-disrupting capacity. Due to some features, such as high lipophilicity, low degradability, and persistence of many of these compounds, sediments can be considered a sink for them in the aquatic environment. In the present study, nine organic UV filters and three benzotriazoles were investigated for the first time in sediments from four urban rivers in Brazil. The contaminants were analyzed by liquid chromatography-tandem mass spectrometry (LC-MS/MS). The results revealed that octocrylene (OC), etylhexyl-methoxycinnamate (EHMC), benzophenone-3 (oxybenzone, BP3), and benzotriazole (BZT) were the predominant compounds adsorbed on the sediments, with concentrations ranging from 5.6 to 322.2 ng g⁻¹ dry weight. The results reported in this work constitute the first data on the accumulation of polar benzotriazoles and lipophilic organic UV filters in sediments from Brazil.

     

Long-term land-cover/use change in a traditional farming landscape in Romania inferred from pollen data,historical maps and satellite images

Regional Environmental Change - Traditional farming landscapes in the temperate zone that have persisted for millennia can be exceptionally species-rich and are therefore key conservation targets....     

Effectiveness of short-term knowledge communication on Baltic Sea marine genetic biodiversity to public managers

The aim of this study is to assess the impact of two forms of short-term knowledge communication—lectures and group deliberations—on public managers’ policy beliefs regarding genetic biodiversity in the Baltic Sea. Genetic biodiversity is a key component of biological variation, but despite scientific knowledge and far-reaching political goals, genetic biodiversity remains neglected in marine management. Previous research highlights lack of knowledge among managers as one explanation to the implementation deficit. This multidisciplinary study builds on the identified need for an improved knowledge transfer between science and ongoing management. A basic knowledge package on genetic biodiversity in the Baltic Sea was presented as either a lecture or a deliberative group discussion to two separate samples of public managers who are involved in Baltic Sea and other biodiversity management at the regional level in Sweden. The empirical findings show that the communicated information has an impact on the public managers’ beliefs on genetic biodiversity of the Baltic Sea. Lectures seem more efficient to transfer knowledge on this theme. Those who received information through a lecture strengthen their confidence in area protection as a management tool to conserve genetic diversity. They were also more convinced of the obligation of authorities at national and regional level to take on larger responsibility for genetic conservation than those managers who participated in a deliberative discussion.

     

Long-term change in drivers of forest cover expansion: an analysis for Switzerland (1850-2000)

Regional Environmental Change - The spatial distribution of forests in Europe represents the legacy of centuries of human land use decisions. Due to the limited availability of historical data,...     

Overview of surface measurements and spatial characterization of submicrometer particulate matter during the DISCOVER-AQ 2013 campaign in Houston,TX

The sources of submicrometer particulate matter (PM₁) remain poorly characterized in the industrialized city of Houston, TX. A mobile sampling approach was used to characterize PM₁ composition and concentration across Houston based on high-time-resolution measurements of nonrefractory PM₁ and trace gases during the DISCOVER-AQ Texas 2013 campaign. Two pollution zones with marked differences in PM₁ levels, character, and dynamics were established based on cluster analysis of organic aerosol mass loadings sampled at 16 sites. The highest PM₁ mass concentrations (average 11.6 ± 5.7 µg/m³) were observed to the northwest of Houston (zone 1), dominated by secondary organic aerosol (SOA) mass likely driven by nighttime biogenic organonitrate formation. Zone 2, an industrial/urban area south/east of Houston, exhibited lower concentrations of PM₁ (average 4.4 ± 3.3 µg/m³), significant organic aerosol (OA) aging, and evidence of primary sulfate emissions. Diurnal patterns and backward-trajectory analyses enable the classification of airmass clusters characterized by distinct PM sources: biogenic SOA, photochemical aged SOA, and primary sulfate emissions from the Houston Ship Channel. Principal component analysis (PCA) indicates that secondary biogenic organonitrates primarily related with monoterpenes are predominant in zone 1 (accounting for 34% of the variability in the data set). The relevance of photochemical processes and industrial and traffic emission sources in zone 2 also is highlighted by PCA, which identifies three factors related with these processes/sources (~50% of the aerosol/trace gas concentration variability). PCA reveals a relatively minor contribution of isoprene to SOA formation in zone 1 and the absence of isoprene-derived aerosol in zone 2. The relevance of industrial amine emissions and the likely contribution of chloride-displaced sea salt aerosol to the observed variability in pollution levels in zone 2 also are captured by PCA.

Implications: This article describes an urban-scale mobile study to characterize spatial variations in submicrometer particulate matter (PM₁) in greater Houston. The data set indicates substantial spatial variations in PM₁ sources/chemistry and elucidates the importance of photochemistry and nighttime oxidant chemistry in producing secondary PM₁. These results emphasize the potential benefits of effective control strategies throughout the region, not only to reduce primary emissions of PM₁ from automobiles and industry but also to reduce the emissions of important secondary PM₁ precursors, including sulfur oxides, nitrogen oxides, ammonia, and volatile organic compounds. Such efforts also could aid in efforts to reduce mixing ratios of ozone.     

Marginal abatement cost curve for nitrogen oxides incorporating controls,renewable electricity,energy efficiency,and fuel switching

A marginal abatement cost curve (MACC) traces out the relationship between the quantity of pollution abated and the marginal cost of abating each additional unit. In the context of air quality management, MACCs are typically developed by sorting control technologies by their relative cost-effectiveness. Other potentially important abatement measures such as renewable electricity, energy efficiency, and fuel switching (RE/EE/FS) are often not incorporated into MACCs, as it is difficult to quantify their costs and abatement potential. In this paper, a U.S. energy system model is used to develop a MACC for nitrogen oxides (NO_x) that incorporates both traditional controls and these additional measures. The MACC is decomposed by sector, and the relative cost-effectiveness of RE/EE/FS and traditional controls are compared. RE/EE/FS are shown to have the potential to increase emission reductions beyond what is possible when applying traditional controls alone. Furthermore, a portion of RE/EE/FS appear to be cost-competitive with traditional controls.

Implications: Renewable electricity, energy efficiency, and fuel switching can be cost-competitive with traditional air pollutant controls for abating air pollutant emissions. The application of renewable electricity, energy efficiency, and fuel switching is also shown to have the potential to increase emission reductions beyond what is possible when applying traditional controls alone.     

Adaptation policy and community discourse: risk,vulnerability, and just transformation

How can public engagement assist in the development of just processes and outcomes in adaptation discourse and policymaking? A concern with justice is at the center of thinking about adaptation that is not only resilient, but also public, engaging, and transformative. Theoretically, the intersection of adaptation, transformation, and environmental and climate justice is examined, before exploring the specific concerns and normative foundations for adaptation policy articulated by local governments, environmental groups, and local residents engaged in adaptation planning in Australia. Despite a discursive disconnect between governmental focus on a risk or resilience-based approach and a community concern with the vulnerability of basic needs and capabilities of everyday life, deliberative engagement in adaptation planning can both address issues of justice and represent a transformative practice.     

Convergence in carbon dioxide emissions and the role of growth and institutions: a parametric and non-parametric analysis

Environmental Economics and Policy Studies - This paper examines convergence of per capita carbon dioxide (CO2) emission for a panel of 124 countries taking into account the impact of economic...