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761.
Ikechukwu D. Anyaogu Paul M. Ejikeme John A. Ibemesi 《Journal of Polymers and the Environment》2010,18(2):104-115
Soybean oil (SBO) was dimerized and the crude dimer acid product reacted with 1,2-phenylene diamine at 210 ± 5 °C under inert
atmosphere to obtain fatty polyamide (FPA). The FPA was used to modify a commercial alkyd resin by reacting a mixture of the
alkyd resin with 5 wt% of FPA at 120 °C for 80 min under inert atmosphere. The FTIR spectrum of the FPA modified resin showed
evidence of higher degree of H-bonding than was found for the unmodified alkyd. White gloss coatings of 15, 20, 25, and 30%
solids were formulated from the modified and unmodified resins and examined for performance with respect to: leveling, sag
resistance, drying time, pigment settling, skinning tendency and film hardness. Results showed that the unmodified alkyd coatings
exhibited good leveling but poor sag resistance at all solid contents. In contrast, FPA modified alkyd coatings combined good
leveling with high sag resistance indicating their thixotropic nature. A strong tendency to pigment settling was observed
for unmodified alkyd coatings but was not observed in the FPA modified alkyd coatings. The modified alkyd coatings showed
skinning while the unmodified alkyd coatings did not skin. A 30% solids coating formulation of the FPA modified resin showed
shorter surface dry time but longer hard dry time than the unmodified alkyd resin coating. 相似文献
762.
Romeu Casarano Denise F. S. Petri Michael Jaffe Luiz H. Catalani 《Journal of Polymers and the Environment》2010,18(1):33-44
A new aliphatic block copolyester was synthesized in bulk from transesterification techniques between poly((R)-3-hydroxybutyrate)
(PHB) and poly(isosorbide succinate) (PIS). Additionally, other two block copolyesters were synthesized in bulk either from
transesterification reactions involving PHB and poly(l-lactide) (PLLA) or from ring-opening copolymerization of l-lactide and hydroxyl-terminated PHB, as result of a previous transesterification reactions with isosorbide. Two-component
blends of PHB and PIS or PLLA were also prepared as comparative systems. SEC, MALDI-TOF mass spectrometry (MALDI-TOFMS), 1H and 13C NMR spectroscopy, WAXD, solubility tests, and TG thermal analysis were used for characterization. The block copolymer structures
of the products were evidenced by MALDI-TOFMS, 13C NMR, and WAXD data. The block copolymers and the corresponding binary blends presented different solubility properties,
as revealed by solubility tests. Although the incorporation of PIS sequences into PHB main backbone did not enhance the thermal
stability of the product, it reduced its crystallinity, which could be advantageous for faster biodegradation rate. These
products, composed of PHB and PIS or PLLA sequences, are an interesting alternative in biomedical applications. 相似文献
763.
Rachana Bhatt K. C. Patel Ujjval Trivedi 《Journal of Polymers and the Environment》2010,18(2):141-147
An extracellular poly(3-hydroxybutyrate) (PHB) depolymerase produced by a thermotolerant fungal soil isolate, Aspergillus fumigatus 202, was purified and characterized. Maximum PHB depolymerase production was obtained at the end of 48 h with initial medium
pH 7.0 and 45 °C in Bushnell Haas Minerals medium containing PHB as sole source of carbon. The PHB depolymerase was purified
using size exclusion chromatography to a fold purification of 20.62 and 61.62% yield. SDS-PAGE and isoelectric focusing revealed
the molecular weight and pI of the purified enzyme as 63,744 Da and 4.2, respectively. N-terminal amino acid sequence of purified
enzyme was HAXDAYLVK. This non-glycosylated enzyme was most active at pH 9.0 and 45 °C. Purified enzyme was inactivated by
N-bromosuccinimide and dithiothreitol suggesting the involvement of tryptophan residues and disulfide bonds at its active
site. Nonionic detergents like Tween 20, Tween 80 and Triton X-100 inhibited the enzyme activity. Ions like Ca+2 and Mg+2 (5 mM) increased the enzyme activity 1.5 times. Fe+2 effectively inhibited the enzyme activity to 88% whereas Hg+2 completely inhibited the enzyme. 相似文献
764.
Bernadett Bartha Christian Huber Rudolf Harpaintner Peter Schröder 《Environmental science and pollution research international》2010,17(9):1553-1562
Purpose
Besides classical organic pollutants and pesticides, pharmaceuticals and their residues have nowadays become recognized as relevant environmental contaminants. The risks of these chemicals for aquatic ecosystems are well known, but information about the pharmaca-plant interactions and metabolic pathways is scarce. Therefore, we investigate the process of uptake of acetaminophen (N-Acetyl-4-aminophenol) by Brassica juncea, drug-induced defense responses and detoxification mechanisms in different plant parts. 相似文献765.
Ika Paul-Pont Xavier de Montaudouin Patrice Gonzalez Philippe Soudant Magalie Baudrimont 《Environmental science and pollution research international》2010,17(4):987-998
Introduction
Within the last decade, numerous studies have investigated the role of environmental history on tolerance to stress of many organisms. This study aims to assess if Manila clams Ruditapes philippinarum may react differently to cadmium exposure and trematode parasite infection (Himasthla elongata) depending on their origin and environmental history in Arcachon Bay (France). 相似文献766.
实验发现,铁氧化物或铁的羟基氧化物对As(V)有较好的吸附性能,而锆氧化物或锆水合氧化物则对As(Ⅲ)有优异的吸附选择性,但其使用的pH通常要在〉9的条件下。通过简单的共沉淀法制备了Zr-Fe双组分复合吸附剂,在制备过程中通过优化制备条件如:沉淀剂浓度、金属离子总浓度、金属离子配比、反应温度、反应时间及吸附剂价格等因素,最终合成出了对As(V)和As(Ⅲ)都具有良好吸附能力的吸附剂。这种吸附剂在中性条件下对As(V)和As(Ⅲ)的最大吸附量为62mg/g和118mg/g。 相似文献
767.
Mark Hixson Abdullah Mahmud Jianlin Hu Song Bai Debbie A. Niemeier Susan L. Handy Shengyi Gao Jay R. Lund Dana Coe Sullivan Michael J. Kleeman 《Atmospheric environment (Oxford, England : 1994)》2010,44(4):552-562
Future air pollution emissions in the year 2030 were estimated for the San Joaquin Valley (SJV) in central California using a combined system of land use, mobile, off-road, stationary, area, and biogenic emissions models. Four scenarios were developed that use different assumptions about the density of development and level of investment in transportation infrastructure to accommodate the expected doubling of the SJV population in the next 20 years. Scenario 1 reflects current land-use patterns and infrastructure while scenario 2 encouraged compact urban footprints including redevelopment of existing urban centers and investments in transit. Scenario 3 allowed sprawling development in the SJV with reduced population density in existing urban centers and construction of all planned freeways. Scenario 4 followed currently adopted land use and transportation plans for the SJV. The air quality resulting from these urban development scenarios was evaluated using meteorology from a winter stagnation event that occurred on December 15th, 2000 to January 7th 2001. Predicted base-case PM2.5 mass concentrations within the region exceeded 35 μg m?3 over the 22-day episode. Compact growth reduced the PM2.5 concentrations by ~1 μg m?3 relative to the base-case over most of the SJV with the exception of increases (~1 μg m?3) in urban centers driven by increased concentrations of elemental carbon (EC) and organic carbon (OC). Low-density development increased the PM2.5 concentrations by 1–4 μg m?3 over most of the region, with decreases (0.5–2 μg m?3) around urban areas. Population-weighted average PM2.5 concentrations were very similar for all development scenarios ranging between 16 and 17.4 μg m?3. Exposure to primary PM components such as EC and OC increased 10–15% for high density development scenarios and decreased by 11–19% for low-density scenarios. Patterns for secondary PM components such as nitrate and ammonium ion were almost exactly reversed, with a 10% increase under low-density development and a 5% decrease under high density development. The increased human exposure to primary pollutants such as EC and OC could be predicted using a simplified analysis of population-weighted primary emissions. Regional planning agencies should develop thresholds of population-weighted primary emissions exposure to guide the development of growth plans. This metric will allow them to actively reduce the potential negative impacts of compact growth while preserving the benefits. 相似文献
768.
X.X. Zhang P.J. Shi L.Y. Liu Y. Tang H.W. Cao X.N. Zhang X. Hu L.L. Guo Y.L. Lue Z.Q. Qu Z.J. Jia Y.Y. Yang 《Atmospheric environment (Oxford, England : 1994)》2010,44(13):1641-1648
Based on environmental monitoring data in 93 major cities and meteorological records at 398 weather stations in China from 1981 to 2007, total suspended particle (TSP) concentration, the intensity of dustfall, and sand and dust storm frequency (Fd) were analysed. During the past 27 years, the annual average TSP concentration (CTSP) in 93 cities was 402 μg m?3. Annual average CTSP decreased from the north to the south and from inland to the coast areas with a peak value of 628.8 μg m?3 in Lanzhou. In the 1980s, 1990s and 2000s, annual average CTSP was 628.7, 319.2, and 250.1 μg m?3, respectively. Annual average intensity of dustfall (Id) was 240.5 t km?2 a?1, decreased from northern to southern China and from inland to the coast areas with the maximum value of 717.2 t km?2 a?1 in Baotou. In the 1980s, 1990s and 2000s, annual average Id was 334.8, 220.9, 146 t km?2 a?1 respectively. Annual average Id in the Loess Plateau region was commonly higher than 200 t km?2 a?1. The annual average Fd decreased from arid regions in northwestern China to humid areas in southeastern China with two sand and sand storm centers existing in Xinjiang Taklamakan Desert and western Inner Mongolia. The annual average Fd in the 1980s, 1990s, 2000s was 16, 8, 6 days respectively, decreased steadily from 18 days in 1981–5 days in 2007. Annual average Id had a positive linear relation to annual average CTSP (R2 = 0.96). Annual average Fd had a positive relation with annual average CTSP (R2 = 0.97) as well as annual average Id (R2 = 0.94). TSP was the chief pollutant influencing Air Pollution Index (API) in northern China in spring and winter seasons. Sand and dust storm might be a major factor affecting the temporal variability and spatial distribution of TSP and dustfall in China. 相似文献
769.
770.
According to various reports, climate change is responsible for the change in rainfall amount and pattern accompanied by the
various degrees of extreme events in Sahelian West Africa in recent years. Other reports also suggest that there has been
a “recovery” of the rainy season (Nicholson 2005). In this study, temporal characteristics of meteorological droughts in the Volta basin, a semi-arid region in West Africa,
are investigated in order to provide a guide for sustainable water resource management. For this purpose, drought intensity,
areal extent and recurrence frequency is analysed using the standardised precipitation index (SPI) for a time series between
1961 and 2005 from 52 meteorology stations across the Volta basin. Using this analysis the severity of the historical droughts
of 1961, 1970, 1983, 1992 and 2001 that occurred in the region are assessed and their intensity, areal extent and return periods
are obtained. The drought intensity is lower than −2.0 over nearly 75% of the region, meaning that a major part of the region
was under extreme drought conditions during this year. The drought of 1983/1984 has a probability of occurrence of up to 0.1
from records spanning 44 years. The areal extent of extreme drought conditions is about 90% during this drought period. 相似文献