双膜技术在印染废水回用工程的应用

以盛虹集团印染废水回用工程为例,分析了＂SMF＋HAPRO＂双膜技术在印染废水深度处理中的应用。应用情况表明,印染废水经该技术处理后,产水水质优良,满足了生产用水的要求,同时给应用企业带来了经济、环境和社会效益。     

Efficient degradation of Rhodamine B by magnetically recoverable Fe3O4-modified ternary CoFeCu-layered double hydroxides via activating peroxymonosulfate

Environment-friendly nano-catalysts capable of activating peroxymonosulfate (PMS) have received increasing attention recently. Nevertheless, traditional nano-catalysts are generally well dispersed and difficult to be separated from reaction system, so it is particularly important to develop nano-catalysts with both good catalytic activity and excellent recycling efficiency. In this work, magnetically recoverable Fe₃O₄-modified ternary CoFeCu-layered double hydroxides (Fe₃O₄/CoFeCu-LDHs) was prepared by a simple co-precipitation method and initially applied to activate PMS for the degradation of Rhodamine B (RhB). X-ray diffraction (XRD), fourier transform infrared spectrometer (FT-IR), scanning electron microscope (SEM), transmission electron microscopy (TEM), Brunauer-Emmett-Teller method (BET), and vibrating sample magnetometer (VSM) were applied to characterize morphology, structure, specific surface area and magnetism. In addition, the effects of several key parameters were evaluated. The Fe₃O₄/CoFeCu-LDHs exhibited high catalytic activity, and RhB degradation efficiency could reach 100% within 20 min by adding 0.2 g/L of catalyst and 1 mmol/L of PMS into 50 mg/L of RhB solution under a wide pH condition (3.0-7.0). Notably, the Fe₃O₄/CoFeCu-LDHs showed good super-paramagnetism and excellent stability, which could be effectively and quickly recovered under magnetic condition, and the degradation efficiency after ten cycles could still maintain 98.95%. Both radicals quenching tests and electron spin resonance (ESR) identified both HO? and SO₄^?? were involved and SO₄^?? played a dominant role on the RhB degradation. Finally, the chemical states of the sample's surface elements were measured by X-ray photoelectron spectroscopy (XPS), and the possible activation mechanism in Fe₃O₄/CoFeCu-LDHs/PMS system was proposed according to comprehensive analysis.     

Numerical simulation of overtopping breach processes caused by failure of landslide dams

Environmental Fluid Mechanics - Based on the mechanism of landslide dam failure caused by overtopping, a simplified mathematical model for simulating dam breach overtopping flow processes was...     

Biocompatible self-healing hydrogels based on boronic acid-functionalized polymer and laponite nanocomposite for water pollutant removal

Environmental Chemistry Letters - Global water pollution by organic dyes and metals may be solved by adsorption. In particular, hydrogel adsorbents display unique...     

Highly efficient photocatalytic oxidation of antibiotic ciprofloxacin using TiO2@g-C3N4@biochar composite

Environmental Science and Pollution Research - In this present study, a novel indirect Z-scheme TiO2@g-C3N4@biochar (TiO2@g-C3N4@BC) composite photocatalyst was successfully fabricated and...     

Characteristics,decoupling effect,and driving factors of regional tourism’s carbon emissions in China

Environmental Science and Pollution Research - By revealing the temporal and spatial differentiation of China’s regional tourism carbon emissions and its decoupling relationship with tourism...     

How does power technology innovation affect carbon productivity? A spatial perspective in China

Power technology innovation has been positioned as an effective way to contribute to China’s carbon productivity. However, limited empirical evidence exists on the impact of power technology innovation on carbon productivity. Thus, based on the annual panel dataset of 30 China’s provinces from 2001 to 2019, this study explored whether and how power technology innovation promotes or impedes the improvement of carbon productivity. First, carbon productivity in the framework of total factor was calculated based on the metafrontier Malmquist-Luenberger productivity index. Second, the effect of power technology innovation on carbon productivity was investigated using the spatial Durbin model. And we also examined whether heterogeneous power technology innovations have a synergistic effect on carbon productivity. Third, influence mechanism of power technology innovation affecting carbon productivity was identified. Results show that (1) there are notable differences in China’s provincial carbon productivity, which is characterized by the spatial correlation. (2) Local power technology innovation has a promotion effect on carbon productivity in both local and neighboring provinces. Moreover, the promotion effect of breakthrough power technology innovation is stronger than that of incremental power technology innovation. (3) Catching-up Effect and Innovation Effect are important transmission channels through which power technology innovation improves carbon productivity. Finally, policy recommendations are provided.

     

酸化油水解废水脱酸处理工艺研究

酸化油是生产生物柴油的原料,其生产过程中产生的水解废水有机物含量高且具有强酸性,直接排放会严重污染环境。因此,对酸化油水解废水处理工艺进行研究有重要意义。通过对酸化油水解废水脱酸处理的条件及影响因素进行研究,并通过L9(34)正交实验确定了脱酸的最佳工艺条件。pH值为10,搅拌时间为15 min,温度为30℃是脱酸处理的最佳条件。     

水解酸化-SBR-BAF工艺处理中药废水

分析现有中药废水处理工艺及废水特点,并考虑到废水处理技术改造的要求,采用水解酸化-SBR-BAF法联合处理该中药废水,研究了SBR反应器的曝气时间、温度及原水pH值对系统处理效果的影响。系统进水ρ(COD)为1 249.4~1 444.5 mg/L、ρ(BOD5)为201.2~292.8 mg/L、ρ(SS)为208.7~310.6 mg/L、色度为70~100倍,曝气时间为14 h、温度为20℃、pH值为7时,出水ρ(COD)为123.4~140.8 mg/L、ρ(BOD5)为19.4~26.1 mg/L、ρ(SS)为32.7~60.4 mg/L、色度为36~50倍,COD、BOD5、SS的平均去除率分别达到90.3%、90.7%、81.8%,表明HAT-SBR-BAF法处理该中药废水是可行的。     

丘陵区坡面土壤有机碳及颗粒有机碳分布特征

测定了紫色丘陵区疏林地、荒草地和坡耕地三种土地利用方式下土壤有机碳和颗粒有机碳含量,探讨不同利用方式与坡位下土壤有机碳和土壤颗粒有机碳的分布特征.结果表明:不同土地利用方式下上坡位和中坡位土壤有机碳和颗粒有机碳含量均为疏林地＞坡耕地＞荒草地,而在下坡位两者含量变化差异较大;不同土地利用方式下各坡位土壤剖面有机碳含量均是在0～5 cm层富集,颗粒有机碳的含量也表现出一定在剖面分异性;不同土地利用方式土壤颗粒有机碳分配比例为(0.74±0.01)～(0.34±0.02),不同土地利用方式之间土壤颗粒有机碳分配比例差异较小.相关分析表明,不同利用方式下土壤有机碳、全氮和颗粒有机碳含量之间均呈显著的相关性.