全文获取类型
收费全文 | 4237篇 |
免费 | 68篇 |
国内免费 | 495篇 |
专业分类
安全科学 | 146篇 |
废物处理 | 261篇 |
环保管理 | 385篇 |
综合类 | 1065篇 |
基础理论 | 907篇 |
环境理论 | 2篇 |
污染及防治 | 1467篇 |
评价与监测 | 286篇 |
社会与环境 | 232篇 |
灾害及防治 | 49篇 |
出版年
2023年 | 35篇 |
2022年 | 113篇 |
2021年 | 75篇 |
2020年 | 53篇 |
2019年 | 70篇 |
2018年 | 155篇 |
2017年 | 94篇 |
2016年 | 122篇 |
2015年 | 123篇 |
2014年 | 145篇 |
2013年 | 359篇 |
2012年 | 154篇 |
2011年 | 243篇 |
2010年 | 204篇 |
2009年 | 205篇 |
2008年 | 216篇 |
2007年 | 246篇 |
2006年 | 186篇 |
2005年 | 162篇 |
2004年 | 172篇 |
2003年 | 170篇 |
2002年 | 145篇 |
2001年 | 257篇 |
2000年 | 180篇 |
1999年 | 95篇 |
1998年 | 67篇 |
1997年 | 73篇 |
1996年 | 57篇 |
1995年 | 53篇 |
1994年 | 57篇 |
1993年 | 47篇 |
1992年 | 42篇 |
1991年 | 46篇 |
1990年 | 42篇 |
1989年 | 36篇 |
1988年 | 22篇 |
1987年 | 19篇 |
1986年 | 21篇 |
1985年 | 18篇 |
1984年 | 20篇 |
1983年 | 23篇 |
1982年 | 23篇 |
1981年 | 16篇 |
1980年 | 11篇 |
1979年 | 13篇 |
1978年 | 12篇 |
1977年 | 8篇 |
1975年 | 12篇 |
1973年 | 9篇 |
1972年 | 10篇 |
排序方式: 共有4800条查询结果,搜索用时 15 毫秒
121.
122.
123.
124.
Xiuying Zhao Xinming Wang Xiang Ding Quanfu He Zhou Zhang Tengyu Liu Xiaoxin Fu Bo Gao Yunpeng Wang Yanli Zhang Xuejiao Deng Dui Wu 《环境科学学报(英文版)》2014,26(1):110-121
Organic acids as important constituents of organic aerosols not only influence the aerosols' hygroscopic property, but also enhance the formation of new particles and secondary organic aerosols. This study reported organic acids including C14–C32fatty acids, C4–C9dicarboxylic acids and aromatic acids in PM2.5collected during winter 2009 at six typical urban, suburban and rural sites in the Pearl River Delta region. Averaged concentrations of C14–C32fatty acids, aromatic acids and C4– C9 dicarboxylic acids were 157, 72.5 and 50.7 ng/m3, respectively. They totally accounted for 1.7% of measured organic carbon. C20–C32fatty acids mainly deriving from higher plant wax showed the highest concentration at the upwind rural site with more vegetation around, while C14–C18fatty acids were more abundant at urban and suburban sites, and dicarboxylic acids and aromatic acids except 1,4-phthalic acid peaked at the downwind rural site. Succinic and azelaic acid were the most abundant among C4–C9dicarboxylic acids, and 1,2-phthalic and 1,4-phthalic acid were dominant aromatic acids. Dicarboxylic acids and aromatic acids exhibited significant mutual correlations except for 1,4-phthalic acid, which was probably primarily emitted from combustion of solid wastes containing polyethylene terephthalate plastics. Spatial patterns and correlations with typical source tracers suggested that C14–C32fatty acids were mainly primary while dicarboxylic and aromatic acids were largely secondary. Principal component analysis resolved six sources including biomass burning, natural higher plant wax, two mixed anthropogenic and two secondary sources; further multiple linear regression revealed their contributions to individual organic acids. It turned out that more than 70% of C14–C18fatty acids were attributed to anthropogenic sources, about 50%–85% of the C20–C32fatty acids were attributed to natural sources, 80%–95% of dicarboxylic acids and 1,2-phthalic acid were secondary in contrast with that 81% of 1,4-phthalic acid was primary. 相似文献
125.
Mengnjo J. Wirmvem Takeshi Oh Wilson Y. Fantong Samuel N. Ayonghe Jonathan N. Hogarh Justice Y. Suil Asobo Nkengmatia E. Asaah Seigo Ooki Gregory Tanyileke Joseph V. Hell 《环境科学学报(英文版)》2014,26(4):801-809
Rainwater characteristics can reveal emissions from various anthropogenic and natural sources into the atmosphere. The physico-chemical characteristics of 44 monthly rainfall events (collected between January and December 2012) from 4 weather stations (Bamenda, Ndop plain, Ndawara and Kumbo) in the Bamenda Highlands (BH) were investigated. The purpose was to determine the sources of chemical species, their seasonal inputs and suitability of the rainwater for drinking. The mean pH of 5 indicated the slightly acidic nature of the rainwater. Average total dissolved solids (TDS) were low (6.7 mg/L), characteristic of unpolluted atmospheric moisture/air. Major ion concentrations (mg/L) were low and in the order K+ 〉 Ca2+ 〉 Mg2~ 〉 Na+ for cations and NO3 〉〉 HCO3 〉 SO] 〉 CI- 〉 PO3- 〉 F- for anions. The average rainwater in the area was mixed Ca-Mg-SO4-CI water type. The CI-/Na+ ratio (1.04) was comparable to that of seawater (1.16), an indication that N a+ and CI originated mainly from marine (Atlantic Ocean) aerosols. High enrichments of Ca2+, Mg2+ and SO2- to Na+ ratios relative to seawater ratios (constituting 44% of the total ions) demonstrated their terrigenous origin, mainly from Saharan and Sahelian arid dusts. The K+/Na+ ratio (2.24), which was similar to tropical vegetation ash (2.38), and NO3 was essentially from biomass burning. Light (〈 100 mm) pre-monsoon and post-monsoon convective rains were enriched in major ions than the heavy (〉 100 mm) monsoon rains, indicating a high contribution of major ions during the low convective showers. Despite the acidic nature, the TDS and major ion concentrations classified the rainwater as potable based on the WHO guidelines. 相似文献
126.
Removal of noxious dyes is gaining public and technological attention. Herein grafting polymerization was employed to produce a novel adsorbent using acrylic acid and carboxymethyl cellulose for dye removal. Scanning electron microscopy and Fourier-transform infrared spectroscopy verified the adsorbent formed under optimized reaction conditions. The removal ratio of adsorbent to Methyl Orange, Disperse Blue 2BLN and malachite green chloride reached to 84.2%, 79.6% and 99.9%, respectively. The greater agreement between the calculated and experimental results suggested that pseudo second-order kinetic model better represents the kinetic adsorption data. Equilibrium adsorptions of dyes were better explained by the Temkin isotherm. The results implied that this new cellulose-based absorbent had the universaiity for removal of dyes through the chemical adsorption mechanism. 相似文献
127.
改性氢氧化镁制备及其去除地下水中Cr3+性能研究 总被引:1,自引:0,他引:1
氢氧化镁作为一种可缓慢释放OH-的碱,能使多数重金属离子转换为沉淀,而且不会引起太大的pH变化.但氢氧化镁难溶于水,在含水层中的迁移能力很差.若要用于地下水重金属污染修复,需要对氢氧化镁进行改性.因此,本文利用表面活性剂对氢氧化镁粉末进行改性,合成了氢氧化镁胶体,并对改性氢氧化镁的稳定性、粒度及其对Cr3+的稳定化效果进行了分析.结果表明,复配表面活性剂改性的氢氧化镁悬浮液稳定性好,粒径小,0.6~8.4μm的颗粒占82.41%.利用改性氢氧化镁对Cr3+污染地下水进行处理,其对Cr3+的去除机理主要为沉淀反应,氢氧化镁和Cr3+反应的质量比约为1.333∶1,氢氧化镁和初始Cr3+浓度对Cr3+的去除效果都有较大的影响. 相似文献
128.
129.
130.
两种喹诺酮类抗生素对亚心形扁藻的毒性效应研究 总被引:1,自引:0,他引:1
研究了恩诺沙星和盐酸环丙沙星两种喹诺酮类抗生素对亚心形扁藻的毒理学效应。经多组不同浓度的两种抗生素处理后,分别对扁藻的96EC50、叶绿素和胞外聚合物(EPS)进行分析。结果表明,两种抗生素在低浓度时对扁藻生长具有促进作用,而在高浓度时体现抑制毒性作用。高浓度时,抗生素浓度越高对扁藻的生长、叶绿素和胞外聚合物抑制效果越明显,但当浓度达到一定高度后,抑制会达到其阈值。恩诺沙星和盐酸环丙沙星对扁藻的半生长抑制率分别为19.8 mg/L和28.7 mg/L。 相似文献