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101.
Douglas W. Kuehl Philip M. Cook Allan R. Batterman Douglas B. Lothenbach Brian C. Butterworth Darcy L. Johnson 《Chemosphere》1985,14(5):427-437
The bioavailability of 2,3,7,8-TCDD from municipal incinerator fly ash to freshwater fish was determined. It was observed that carp exposed to fly ash containing all 22 TCDD isomers, or the solvent extract of the fly ash, retain only 2,3,7,8-TCDD. Exposures with fly ash appears to follow a dose response relationship for bioconcentration, however, the bioavailability of 2,3,7,8-TCDD was not directly related to the level of 2,3,7,8-TCDD in fly ash for two fly ash samples studied. 相似文献
102.
Lowenthal DH Kumar N Hand J Day D Kreidenweis S Collett J Lee T Ashbaugh L 《Journal of the Air & Waste Management Association (1995)》2003,53(10):1273-1279
The hygroscopic properties of the organic fraction of aerosols are poorly understood. The ability of organic aerosols to absorb water as a function of relative humidity (RH) was examined using data collected during the 1999 Big Bend Regional Aerosol and Visibility Observational Study (BRAVO). (On average, organics accounted for 22% of fine particulate matter with an aerodynamic diameter less than 2.5 microm (PM2.5) mass). Hourly RH exceeded 80% only 3.5% of the time and averaged 44%. BRAVO aerosol chemical composition and dry particle size distributions were used to estimate PM2.5 light scattering (Bsp) at low and high ambient RH. Liquid water growth associated with inorganic species was sufficient to account for measured Bsp for RH between 70 and 95%. 相似文献
103.
Douglas W. Kononen 《Chemosphere》1989,18(9-10):2065-2068
Fillets from 25 white suckers (
) obtained from the Saginaw Bay, Lake Huron commercial fishery were analyzed for PCBs and ∑DDT (DDE-DDD-DDT). PCB levels ranged from 0.01 – 0.18 ppm while ∑DDT levels ranged from < 0.001 – 0.044 ppm. These results, combined with previous survey data, indicate steady declines in the levels of these contaminants in Saginaw Bay suckers. 相似文献
104.
Emission rates and comparative chemical composition from selected in-use diesel and gasoline-fueled vehicles 总被引:3,自引:0,他引:3
Zielinska B Sagebiel J McDonald JD Whitney K Lawson DR 《Journal of the Air & Waste Management Association (1995)》2004,54(9):1138-1150
Emission samples for toxicity testing and detailed chemical characterization were collected from a variety of gasoline- and diesel-fueled in-use vehicles operated on the Unified Driving Cycle on a chassis dynamometer. Gasoline vehicles included normal particle mass (particulate matter [PM]) emitters (tested at 72 and 30 degrees F), "black" and "white" smokers, and a new-technology vehicle (tested at 72 degrees F). Diesel vehicles included current-technology vehicles (tested at 72 and 30 degrees F) and a high PM emitter. Total PM emission rates ranged from below 3 mg/mi up to more than 700 mg/mi for the white smoker gasoline vehicle. Emission rates of organic and elemental carbon (OC/EC), elements (metals and associated analytes), ions, and a variety of particulate and semi-volatile organic compounds (polycyclic aromatic hydrocarbons [PAH], nitro-PAH, oxy-PAH, hopanes, and steranes) are reported for these vehicles. Speciated organic analysis also was conducted on the fuels and lube oils obtained from these vehicles after the emissions testing. The compositions of emissions were highly dependent on the fuel type (gasoline vs. diesel), the state of vehicle maintenance (low, average, or high emitters; white or black smokers), and ambient conditions (i.e., temperature) of the vehicles. Fuel and oil analyses from these vehicles showed that oil served as a repository for combustion byproducts (e.g., PAH), and oil-burning gasoline vehicles emitted PAH in higher concentrations than did other vehicles. These PAH emissions matched the PAH compositions observed in oil. 相似文献
105.
A reverse-phase high pressure liquid chromatography/mass spectrometry (HPLC/MS method was developed for estimating n-octanol/water partition coefficients (Kow) of anthropogenic molecules in complex chemical mixtures (e.g., complex effluents and solid waste leachates). The average error for an estimated log Kow was ca. 0.5 and this error was similar for both aliphatic and aromatic compounds. The minimum level of detection using the total ion current profile generally decreased with increasing molecular weight between 100 and 600 daltons. Results obtained demonstrate that the HPLC/MS method is a viable technique for estimating log Kow's of anthropogenic chemicals in complex environmental samples. 相似文献
106.
Mallory E. Flowers Daniel C. Matisoff Douglas S. Noonan 《Journal of Environmental Planning and Management》2019,62(5):843-861
In a case study that examines the outcomes of a flexible information-based policy, we observe how organizations obtain Leadership in Energy and Environmental Design certification. We use a regression discontinuity analysis to identify practices used to upgrade certification tiers. This analysis reveals preferences for green certification strategies and, we argue, intimates the perceived motivations for green certification. We distinguish practices that potentially confer private gains through returns to efficiency and productivity investments, from practices that only provide public benefits. Data show that organizations strategically certify to avoid high-cost resource use, appeal to key stakeholders, and communicate building and organization quality. Builders upgrading to the highest tiers are more likely to deploy practices with private gains. Results suggest a willingness to extend short time horizons associated with energy-efficiency investments in exchange for marketing benefits. Our discussion notes the capacity for certifications to mitigate market barriers associated with the energy-efficiency gap. 相似文献
107.
Douglas S. Kenney 《Journal of the American Water Resources Association》1999,35(3):493-503
ABSTRACT: The 1990s have featured a rapid proliferation of “watershed initiatives” in the western United States and elsewhere. Watershed initiatives are ad hoc, voluntary associations typically featuring both governmental and non-governmental actors organized together to collaboratively seek new strategies for addressing water and related natural resource problems at physically relevant regional scales. These efforts are a response to historical and sociopolitical trends that have resulted in increasingly ineffective forums and processes of resource management decision-making, and that have subordinated the role of local stakeholders in problem-solving efforts. In most cases, watershed initiatives appear to provide a pragmatic vehicle for resource managers and stakeholders to address common concerns in a more efficient manner than is otherwise possible, and as such, deserve further application and continued support. 相似文献
108.
The grand skink, Oligosoma grande, is a diurnal rock-dwelling lizard from the tussock grasslands of Central Otago, New Zealand, whose diet includes a variety
of arthropods and fruit. We conducted a field experiment to examine the influence of prey distribution on foraging behavior
and spacing patterns. On sites where prey distribution was unaltered (control sites), males and females differed in diet and
foraging behavior. Most male feeding attempts were directed at large strong-flying insects, and males used a saltatory search
pattern that involved relatively infrequent moves of long duration. Females spent more effort catching small weak-flying insects
and visiting fruiting plants. Their search behavior involved frequent moves of short duration. The placement of meat-bait
on experimental sites led to a redistribution of large flies without influencing other prey types. Experimental females switched
foraging strategy by adopting a search pattern of relatively infrequent moves of long duration, increasing the frequency of
attempts to capture large prey, and reducing the importance of fruit in their diet. The experimental manipulation appeared
to influence space use. On control sites, both sexes had comparably sized home ranges. On experimental sites, male home ranges
were significantly larger than female home ranges.
Received: 3 November 1997 / Accepted after revision: 13 December 1998 相似文献
109.
Order and simplification are the first steps toward the mastery of a subject—the actual enemy is the unknown.
相似文献
110.