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131.
Minghuo Wu Jie Du Zhijun An Yufeng Hu Xianliang Yi Hao Zhou Jingjing Zhan 《环境科学学报(英文版)》2022,34(12):227-235
Sulfonamides (SAs) are one of the most widely used antibiotics and their residuals in the environment could cause some negative environmental issues. Advanced oxidation such as Fenton-like reaction has been widely applied in the treatment of SAs polluted water. Degradation rates of 95%-99.7% were achieved in this work for the tested 8 SAs, including sulfisomidine, sulfameter (SME), phthalylsulfathiazole, sulfamethoxypyridazine, sulfamonomethoxine, sulfisoxazole, sulfachloropyridazine, and sulfadimethoxine, in the Fe3O4/peroxodisulfate (PDS) oxidation system after the optimization of PDS concentration and pH. Meanwhile, it was found that a lot of unknown oxidation products were formed, which brought up the uncertainty of health risks to the environment, and the identification of these unknown products was critical. Therefore, SME was selected as the model compound, from which the oxidation products were never elucidated, to identify these intermediates/products. With liquid chromatography-high resolution tandem mass spectrometry (LC-HRMS/MS), 10 new products were identified, in which 2-amino-5-methoxypyrimidine (AMP) was confirmed by its standard. The investigation of the oxidation process of SME indicated that most of the products were not stable and the degradation pathways were very complicated as multiple reactions, such as oxidation of the amino group, SO2 extrusion, and potential cross-reaction occurred simultaneously. Though most of the products were not verified due to the lack of standards, our results could be helpful in the evaluation of the treatment performance of SAs containing wastewater. 相似文献
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This study was a preliminary step to evaluate the acute toxicity of 1-methyl-3-octylimidazolium chloride ([C8mim]Cl) on loach (Misgurnus anguillicaudatus) by determining the effects on hepatic antioxidant enzyme activities and by the comet assay. The results showed that [C8mim]Cl had acute toxicity at concentrations above 20 mg L?1, inducing oxidative stress and genotoxicity on fish liver cells. In respect to enzyme activities, [C8mim]Cl induced changes in the activities of superoxide dismutase, catalase, and glutathione content the livers of fish exposed at 20–80 mg L?1. [C8mim]Cl at the same exposure level caused a remarkable increase in malondialdehyde level. The comet assay indicated that [C8mim]Cl at 20–80 mg L?1 induced genotoxicity in liver cells. With increased exposure concentration and time, the two comet parameters trailing rate and tail moment were significantly increased, with significant differences (P < 0.05) observed between control group and each treatment group. The present study shows that ionic liquids can be a threat to the health of aquatic organism when accidentally released to aquatic ecosystems. 相似文献
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Surface clogging process modeling of suspended solids during urban stormwater aquifer recharge 总被引:1,自引:0,他引:1
Aquifer recharge,which uses urban stormwater,is an effective technique to control the negative effects of groundwater overexploitation,while clogging problems in infiltration systems remain the key restricting factor in broadening its practice.Quantitative understanding of the clogging process is still very poor.A laboratory study was conducted to understand surface physical clogging processes,with the primary aim of developing a model for predicting suspended solid clogging processes before aquifer recharge projects start.The experiments investigated the clogging characteristics of different suspended solid sizes in recharge water by using a series of one-dimensional fine quartz sand columns.The results showed that the smaller the suspended particles in recharge water,the farther the distance of movement and the larger the scope of clogging in porous media.Clogging extents in fine sand were 1 cm,for suspended particle size ranging from 0.075 to 0.0385 mm,and 2 cm,for particles less than 0.0385 mm.In addition,clogging development occurred more rapidly for smaller suspended solid particles.It took 48,42,and 36 hr respectively,for large-,medium-,and small-sized particles to reach pre-determined clogging standards.An empirical formula and iteration model for the surface clogging evolution process were derived.The verification results obtained from stormwater recharge into fine sand demonstrated that the model could reflect the real laws of the surface clogging process. 相似文献
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Contaminant transport through the clay liner and the underIying secondary leachate drain layer (SLDL) in landfills was studied through a laboratory test, and analysis method on the transport of K+ in a two-layer soil system. The soils used for this study were Ariake clay and the underlying layer, Shirasu soil from the Kyushu region of Japan, representing the clay liner material and SLDL material, respectively. The effective diffusion coefficients (De) of the selected target chemical species, potassium (K+) for the Ariake clay and Shirasu soil were back-calculated using a computer program, and it was found that values of De derived from this study were consistent with those previously published. The hypothesis that the mechanical dispersion process can be negligible has been proved to be reasonable based on both the observation that the predicted values fit the experimental data and the analyses of two dimensionless parameters. Parametric analysis showed the transport of K+ through the soils is controlled by advection-diffusion rather than diffusion only, whereas at low Darcy velocity (i.e. < or = 10(-9) m s(-1)), transport of K+ would be controlled by diffusion. The test results and parametric analysis may be applied in design of landfill liners and SLDLs, particularly in coastal areas. 相似文献
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湖北省湖泊水环境化学特征及其与人类活动的关系 总被引:6,自引:0,他引:6
通过对湖北省近30个湖泊水环境化学的分析,探讨了湖北省湖泊水质状况和湖水的化学稳定性,指出远离工业区和居民生活区的湖泊水质一般较好,城区或城效型湖泊在不同程度上受到了工业废水和生活污水的影响。控制,消除湖泊污染是今后经济、社会和环境建设不可忽视的重要工作。 相似文献