A washing procedure to mobilize mixed contaminants from soil: I. Polychlorinated biphenyl compounds

We conducted a laboratory study to assess the feasibility of a washing process with nonionic and anionic surfactants in combination with ethylenediaminetetraacetate (EDTA) for the simultaneous mobilization of heavy metals and polychlorinated biphenyls (PCBs) from a field-contaminated soil. Unit processes consisting of complexometric extraction and surfactant-assisted mobilization were combined with reagent regeneration and detoxification steps to generate innocuous products. Ten minutes of ultrasonic mixing of the soil with a combination of 30 mL L(-1) surfactant suspension and a sparing quantity (2 mmol) of EDTA mobilized appreciable quantities of PCBs, virtually all of the available Cd, Cu, Mn, and Pb, and lesser amounts of the Zn, Ni, and Cr but only small quantities of Al and Fe. Relative to individual reagents, combinations of surfactant (Brij 98, Triton X-301, or Triton XQS-20) with EDTA did not influence PCB extraction efficiencies perceptibly. Of the three surfactants, the Brij 98 proved to be the most efficient for three successive extractions with a single charge, mobilizing 83% of the PCBs, whereas companion extractions that used fresh reagent each time mobilized 87% of the soil PCB content. The decreased PCB mobilization with the same quantity of anionic surfactant (71 or 68%) resulted from losses during the EDTA regeneration process with zero-valent Mg. In toto, these studies demonstrate that PCB compounds and selected heavy metals can be coextracted efficiently from soil with three successive washes with the same washing suspension containing EDTA and a nonionic surfactant.     

Can corporate environmental responsibility improve environmental performance? An inter-temporal analysis of Chinese chemical companies

The empirical research on the relationship between corporate environmental responsibility and environmental performance remains in the one-way positive impact and lacks the research on nonlinear relationship between them. Based on the stakeholder theory, this paper selects A-share chemical–listed companies in China from 2006 to 2017 as the research samples and uses generalized method of moments (GMM) model to investigate the impact mechanism between corporate environmental responsibility and environmental performance. The results showed that corporate environmental responsibility positively impacted on environmental performance; however, the impact was not significant. The corporate environmental performance positively and significantly impacted on environmental responsibility. Moreover, results reported that industry competition played a positive regulatory role in corporate environmental responsibility affecting environmental performance and has played a positive role in corporate environmental impact on environmental responsibility. A nonlinear relationship (inverted “U” shape) between environmental responsibility and environmental performance was found. The study results stress to establish a fair and perfect market competition mechanism to improve the environmental performance of chemical industries in China.

     

Future production of rainfed wheat in Iran (Khorasan province): climate change scenario analysis

Projecting staple crop production including wheat under future climate plays a fundamental role in planning the required adaptation and mitigation strategies for climate change effects especially in developing countries. The main aim of this study was to investigate the direction and magnitude of climate change impacts on grain yield of rainfed wheat (Triticum aestivum L.) production and precipitation within growing season. This study was performed for various regions in Khorasan province which is located in northeast of Iran. Climate projections of two General Circulation Models (GCM) for four locations under three climate change scenarios were employed in this study for different future time periods. A stochastic weather generator (LARS-WG5) was used for downscaling to generate daily climate parameters from GCMs output. The Decision Support System for Agrotechnology Transfer (DSSAT) Version 4.5 was employed to evaluate rainfed wheat performance under future climate. Grain yield of rainfed wheat and precipitation during growth period considerably decreased under different scenarios in various time periods in contrast to baseline. Highest grain yield and precipitation during growth period was obtained under B1 scenario but A1B and A2 scenarios resulted in sharp decrease (by ?57 %) of grain yield. Climate change did not have marked effects on evapotranspiration during the rainfed wheat growth. A significant correlation was detected between grain yield, precipitation and evapotranspiration under climate change for both GCMs and under all study scenarios. It was concluded, that rainfed wheat production may decline during the next 80 years especially under A2 scenario. Therefore, planning the comprehensive adaptation and mitigation program is necessary for avoiding climate change negative impact on rainfed wheat production.     

Comparison of API650-2008 provisions with FEM analyses for seismic assessment of existing steel oil storage tanks

API650-2008 is one of the prominent codes consisting of seismic specifications to design steel storage tanks for earthquakes resistance. In spite of the code's broad application, there are some failure modes such as slide bottom, elephant-foot buckling, sloshing and uplift needing more evaluation. In this paper, 161 existing tanks in an oil refinery complex have been classified into 24 groups and investigated using both API650-2008 rules and numerical FEM models. Failure modes and dynamic characteristics of studied models have been calculated by numerical FEM analysis and compared with code requirements. The results demonstrate that, in some cases, there are some imperfections in the code requirements that require further investigation.     

An overview on the enhanced gas condensate recovery with novel and green methods

Environmental Science and Pollution Research - A consideration of the negative environmental aspects of fossil fuels has made natural gas the best choice to meet the human demand for energy. The...     

A washing procedure to mobilize mixed contaminants from soil: II. Heavy metals

We conducted a laboratory study to assess the efficiency of nonionic and anionic surfactants in combination with a sparing quantity of ethylenediaminetetraacetate (EDTA) to simultaneously extract heavy metals (HMs) and polychlorinated biphenyl (PCB) compounds from a field-contaminated soil. A soil wash that mobilized both HMs and PCBs was combined with back-extraction with hexane to remove PCBs from the aqueous wash. The aqueous washing suspension was then regenerated by precipitation of the HMs induced by corrosion and hydrolysis of zero-valent Mg to provide a cleaned soil and innocuous extract. Finally, the washing suspension was recycled twice to mobilize more contaminants from the soil particulate fraction. After ultrasonic equilibration, EDTA in admixture with a nonionic surfactant did not appreciably change the efficiency of mobilization of most heavy metals (Al, Cd, Cr, Fe Mn, Ni, and Zn), but did increase the recovery of Cu and Pb. The release of EDTA from HM complexes was efficient for most metals (99%) but was influenced by the chemical characteristics of the surfactant. The EDTA recovery (62-65%) after three cycles of soil washing, hexane back-extraction, and Mg(0) treatment was similar for all reagent combinations. In toto, these studies demonstrate that after treatment with ultrasound, selected heavy metals can be coextracted efficiently from soil with a single washing suspension containing EDTA and a nonionic surfactant.     

Remediation of pharmaceuticals from contaminated water by molecularly imprinted polymers: a review

Environmental Chemistry Letters - The release of pharmaceuticals into the environment induces adverse effects on the metabolism of humans and other living species, calling for advanced remediation...     

Evolution of spatial–temporal characteristics and financial development as an influencing factor of green ecology

Environment, Development and Sustainability - This study aims to determine the impact of financial development on green ecology to promote cleaner production. Particularly, it estimates the...     

Porous materials for the recovery of rare earth elements,platinum group metals,and other valuable metals: a review

Environmental Chemistry Letters - The demand for valuable metals such as rare earth elements and platinum group metals is rising fast in the context of the depletion of natural resources...