Solid waste treatment within the framework of life-cycle assessment

Traditionally, treatment of solid waste has been given limited attention in connection with life-cycle assessments (LCAs). Often, only the amounts of solid wastes have been noted. This is unsatisfactory since treatment of solid waste, e.g. by landfilling or incineration, is an operation, requiring inputs and producing outputs, which should be described in the inventory of an LCA, in parallel to other operations. However, there are difficulties in describing emissions from solid waste treatments and there is a need for development of such methods. In this paper an approach for describing emissions from incineration and landfilling is outlined. Methodological questions concerning the time-frame and allocation principles are discussed. Methods for estimating potential emissions from landfilling of municipal solid waste and industrial wastes are suggested. The methods are used for calculating potential emissions from landfilling of some typical wastes. These emissions are compared with the emissions from other stages in the life cycle for some materials and wastes. it is shown that the potential emissions from landfilling are, for some products, of importance for the final results. Hence, if emissions from landfilling are neglected, or underestimated, results and conclusions in an LCA may be misleading.     

Ökotoxikologische Untersuchung von Sedimenten und Schwebstoffen

The potential risk of ground-water contamination through the infiltration of contaminants originating from suspended matter and sediments deposited within flood retention areas in the Upper Rhine valley, as well as subsequent problems for drinking water production, were analyzed by means of the bacterial dehydrogenase activity (DHA; sediment contact test) assay with Arthrobacter globiformis and in a prolonged embryo toxicity assay using zebrafish (Danio rerio). Since the direct uptake of contaminants from particle-bound sources has usually been assumed to play only a minor role in bioaccumulation, the availability of organic extracts to biota has generally been regarded as being overestimated. In order to confirm or discard this hypothesis, organic (acetone) extracts of recently suspended, freeze-dried matter, as well as freeze-dried sediments collected from Rhine flood plains (i.e. soil samples) were compared to corresponding native samples in order to screen for the relative availability of particle-bound contaminants. Whereas a significantly higher ecotoxicological burden was observed for some native soil samples, organic extracts of suspended matter proved to be more toxic than corresponding native samples when compared to organic extracts using each test system. With respect to organic extracts, the suspended matter samples were more toxic than soil samples taken from a rarely flooded site. In contrast to the native samples, the rarely flooded soils revealed a higher toxicity than suspended matter. Therefore, organic extracts did not necessarily overestimate the toxicity of soil and suspended matter samples. Moreover, considerable toxicity of particle-bound contaminants to both bacteria and fish embryos, even in native samples, corroborate the hypothesis that particle-bound contaminants may be more readily available than is generally assumed.     

Sensitivity of the zebrafish (Danio rerio) early life stage test for compounds with different modes of action

The sensitivity of the early life stage (ELS) toxicity test for two compounds with different modes of action was determined, and related to other toxicity tests with the same compounds. The zebrafish. Danio rerio, was used as a test organism, and the two model compounds were 1,2,3-trichlorobenzene (123TCB), a non-polar narcotic, and parathion, an acetylcholinesterase (AChE) inhibitor. Hatching and survival after 28 days were significantly reduced in the highest 123TCB treatment (263 microg/l), but not in any of the parathion treatments. Growth of the larvae was negatively affected at parathion concentrations above 20 microg/l, while AChE was only significantly inhibited at the highest concentration, 93 microg/l. No effects on growth were found in the 123TCB treatments. In comparison with acute and chronic studies with both compounds, the ELS test turned out to be less sensitive than chronic studies and more sensitive than acute studies. The difference in sensitivity between the tests systems seems however, to depend on the mode of action of the compound.     

Spatial variations and correlations in the distribution of PCDDs, PCDFs and related compounds in sediments from the river Rhine — Western Europe

PCDDs, PCDFs and some related aromatic compounds were determined isomer specifically in sediments from the river Rhine and its tributaries, in order to study sources and environmental fate of these compounds. Additionally, waste water effluents from industries that unintentionally might coproduce PCDDs or PCDFs were analyzed. In all sediments and in some waste water effluents these compounds could be detected. Variations of the isomeric patterns of the PCDFs enabled a distinct industrial area, that was associated with PCB contamination to be identified. The contamination of sediments and organisms from the Dutch river Rhine delta with these compounds mainly could be attributed to the transboundary pollution of the river Rhine.     

The effect of surfactants on oxygen mass-transfer through the air-water interface

The aim of the current study was to investigate the oxygen transfer rate through the water-air interface in the presence of different concentrations of various surfactants. The surfactants used in the current study were methanol, ethanol, 1-propanol and 1-butanol. The measurements were performed with an apparatus based on the electrochemical oxygen sensor. Theresults obtained showed that the impediment to oxygen mass-transfer through the water-air interface depends on the molecular structure and concentration of the surfactant used. A simple mathematical model was proposed, which allowed us to calculate the characteristic constants of surfactantsK’ and δk starting from the experimental results.K’ is the reciprocal of the equilibrium constant of adsorption process and δk characterizes the influence of the surfactant to oxygen mass-transfer through the air-water interface.     

Reverse quantitative structure-activity relationship for modelling the sorption of esfenvalerate to dissolved organic matter. A multivariate approach

The sorption of the pyrethroid, esfenvalerate, to the dissolved and/or dispersed fraction of eight different natural humic compounds has been investigated. The dissolved organic matters (DOMs) included in this study originate from ground water, soil pore water, and surface waters. Sorption was modelled at DOM concentration levels where equilibrium partitioning of esfenvalerate between DOM and the aqueous bulk phase prevails. The inherent characteristics of the eight different humic materials, quantified in the preceding paper by Thomsen et al. (2002, this issue (PII: S0045-6535(02)00335-1)), have been used as explanatory variables for modelling this equilibrium partitioning. Using a reverse QSAR approach based on by projection-into-latent-structure regression (PLS-R) inherent sorbent properties determining for the sorption affinity of esfenvalerate to DOM were analysed. For all humic substances a decrease in the DOM-normalised equilibrium-partitioning coefficient, K_DOM, with increasing concentration of DOM was observed. Significant variations in K_DOM values, as function of the inherent characteristics of the individual humic substances, were found at DOM concentrations of 75 and 100 ppm, respectively. The latter is a strong indication of variations in sorption mechanisms of esfenvalerate to DOM of varying inherent properties. Groupings in the principal property space quantifying DOMs may indicate that separate models are needed for quantifying the equilibrium partitioning to different classes of DOM.     

Variation in biometry and population density of solitary corals with solar radiation and sea surface temperature in the Mediterranean Sea

The correlation between two environmental factors (solar radiation and sea surface temperature), biometry, and population density was assessed along a latitudinal gradient in the zooxanthellate coral Balanophyllia europaea and in the azooxanthellate coral Leptopsammia pruvoti. With increasing polyp size, the oral disc of B. europaea assumed an oval shape, while that of L. pruvoti retained a circular shape. In both species, biometric parameters varied more with temperature than with solar radiation. In the zooxanthellate species, temperature explained a higher percentage of biometric parameter variance than in the azooxanthellate species. While environmental factors did not co-vary with demographic characteristics in L. pruvoti, temperature was negatively related to the population density of B. europaea. It is hypothesized that the negative effect of temperature on biometry and population density of B. europaea depends on photosynthesis inhibition of symbiotic zooxanthellae at high temperatures, which would lower the calcification rate and availability of energetic resources.     

Stereoisomeric composition of the sex pheromone of the pine sawfly <Emphasis Type="Italic">Microdiprion pallipes</Emphasis> (Hym., Diprionidae)

Summary. The basic chemical structure of the sex pheromone of the pine sawfly Microdiprion pallipes (Fallén) has earlier been identified as the propionate ester of (2S,3S,7R/S,11R/S)/(2R,3R,7R/S,11R/S)-3,7,11- trimethyl-2-tridecanol. We now report the results from further investigations on the male response to individual stereoisomers and to blends of stereoisomers, both in electroantennographic (EAG) recordings and in field trapping experiments. We also present our attempts to determine the stereochemistry of the compounds present in females of M. pallipes. By comparing gas chromatograms and mass spectra obtained from natural extracts with those from synthetic compounds it was found that the females contain one or more of the four (2S,3S,7R/S,11R/S)-3,7,11-trimethyl-2- tridecanol isomers (SS++-1). The active pheromone component is the corresponding propionate ester 2. In EAG experiments, males responded most strongly to five propionate ester samples, namely two four-isomer blends: SS++-2 and SR++-2, and three individual stereoisomers: SSSR-, SRRR- and SRSR-2. In a series of field trapping experiments it was found that males were attracted to the SR++-2 four-isomer blend and to the individual isomer SSSR-2. Based on the EAG-recordings and field responses of males and the stereoisomers found in the females, we suggest that the propionate ester of (2S,3S,7S,11R)-3,7,11-trimethyl-2- tridecanol (SSSR-2) is used as a main component of the sex pheromone in M. pallipes. Apparently the males react to other stereoisomers in addition to that or those produced by the females.     

A model of fish growth

A fish model based upon mass balances is set up. Several of the parameters have been determined by experiments. The remaining parameters are based upon literature values and it was not necessray to find any parameter by calibration. The model was validated with a completely acceptable result.The model includes equations giving the fish growth, the production of ammonia and organic matter, the oxygen consumption, and the influence to the temperature.The model can be used for management of fish farms and as a submodel for a total aquatic system.