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Patrizia Di Filippo Carmela Riccardi Donatella Pomata Francesca Buiarelli 《Atmospheric environment (Oxford, England : 1994)》2010,44(23):2742-2749
Size-segregated atmospheric particles were collected in Rome, Italy, using a low-pressure impactor.Twelve sampling campaigns were conducted under different meteorological conditions over a whole year covering 155 not consecutive days. The samples were analyzed for polycyclic aromatic hydrocarbons (PAHs) and their nitro- and methyl- derivatives known for their toxicity. An assessment of the carcinogenic potency of the particles known to penetrate into lungs, liver, heart and nervous system was performed.The distribution of the classes of compounds was unimodal and centrated at 0.4 μm size fraction for PAHs and bimodal and centrated at 0.1 and 0.4 μm for methyl- and nitro- derivatives. The 18% of toxic organic compounds we analyzed was distributed into the ultrafine fraction (PM0.1) and 76% in the fine fraction; but substituted PAH distribution in the ultrafine particles shifted toward higher values during warm periods. In July, the 50% of the total nitro-PAHs was found in PM0.1 and an average of 42% of the total methyl-PAHs was found in the same fraction in summer and intermediate seasons.An evaluation of the potential toxicity of the measured compounds was tentatively assessed based on Potency Equivalency Factors (PEF). 相似文献
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Vigni Lorenza Li Daskalopoulou Kyriaki Calabrese Sergio Kyriakopoulos Konstantinos Parello Francesco Brugnone Filippo D’Alessandro Walter 《Environmental geochemistry and health》2022,44(7):2111-2133
Environmental Geochemistry and Health - Geothermal areas of Greece are located in regions affected by recent volcanism and in continental basins characterised by elevated heat flow. Many of them... 相似文献
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Furlan Lorenzo Pozzebon Alberto Duso Carlo Simon-Delso Noa Sánchez-Bayo Francisco Marchand Patrice A. Codato Filippo Bijleveld van Lexmond Maarten Bonmatin Jean-Marc 《Environmental science and pollution research international》2021,28(10):11798-11820
Environmental Science and Pollution Research - Over-reliance on pesticides for pest control is inflicting serious damage to the environmental services that underpin agricultural productivity. The... 相似文献
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The need for new instruments and systems for environment monitoring encouraged the development of a network of coastal platforms combining a high versatility with ease of use and affordability. Almost every instrument can be fitted on the platforms, thanks to the large amount of available power provided by both solar panels and wind generators. All the platforms host a pumping system that pumps water from five depths into a measurement chamber where a multiparametric probe is fitted and from where other devices (e.g. samplers or analysers) can draw samples. In situ temperature measurements are provided at the same pumping depths. A colorimetric nutrient analyser and a meteorological station complete the basic equipment. On one of the platforms, a remotely controlled water sampler and an ADCP are also fitted. The data-acquisition and transmission system enables the platform to be controlled remotely using a special macro-commands set. Several examples of use are presented. 相似文献
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Maurizio Bevilacqua Filippo Emanuele Ciarapica Giovanni Mazzuto 《Journal of Loss Prevention in the Process Industries》2012,25(4):677-685
Issues related to health and safety at work, such as accidents at work, are one of the most important areas of action for global social policy. This paper presents a fuzzy cognitive map (FCM) approach to explore the importance of the relevant factors in industrial plants. For this purpose, industrial plants are described in terms of factors that affect injury risk and the causal relationships involved.In this work, the injuries in an Italian refinery have been studied. The company in this account has a system for monitoring and controlling the machinery but has a large number of minor injuries at work. The causes of these injuries have been found in human behaviours. To analyse the injuries, it is necessary to investigate what individual-level concerns are involved in the perception of risk. For this investigation, an FCM permits us to build a schema of the perception of risk. The resulting analysis of all of these schemas has allowed us to define a method that generically permits a determination of the causes for each type of injury. In fact, it has been possible to determine that factors such as poor attention and concentration or fatigue are the main causes of injuries at work.In light of the results obtained, managers can define appropriate control procedures to diminish the occurrences of the injuries. 相似文献
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Filippo Barbanera Chiara Marchi Monica Guerrini Panicos Panayides Christos Sokos Pantelis Hadjigerou 《Die Naturwissenschaften》2009,96(10):1203-1212
The chukar (Alectoris chukar, Galliformes) is a species hunted throughout its native range from the East Mediterranean to Manchuria and in the USA, which hosts the world’s largest introduced population. This study aims to investigate the genetic structure of Mediterranean chukar populations to aid management decisions. We genotyped 143 specimens at two regions of the mitochondrial DNA (mtDNA: cytochrome b, control region) and eight loci of the microsatellite DNA. Samples were collected in northern (Limnos, Lesvos, Chios) and southern (Crete) Aegean islands (Greece) and Cyprus. We also carried out mtDNA-based comparison with chukars (n?=?124) from Asia (16 countries) and the USA (five states). We propose six management units for Mediterranean populations. Given their genetic integrity, Limnos and Cyprus, which host different subspecies, proved to be of primary conservation interest. We found exotic A. chukar mtDNA lineages in Lesvos, Chios and Crete and produced definitive genetic evidence for the Asian origin of the US chukars. 相似文献
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Zara S Caboni P Orro D Farris GA Pirisi F Angioni A 《Journal of environmental science and health. Part. B》2011,46(6):491-497
The influence of fenamidone ((S)-1-anilino-4-methyl-2-methylthio-4-phenylimidazolin-5-one), pyraclostrobin (methyl 2-[1-(4-chlorophenyl)pyrazol-3-yloxymethyl]-N-methoxycarbanilate), indoxacarb (methyl 7-Chloro-2,5-dihydro-2-[[(methoxycarbonyl) [4- (trifluoromethoxy) phenyl] amino] carbonyl] indeno[1,2-e][1,3,4] oxadiazine-4a(3H)-carboxylate), and deltamethrin ([cyano-[3-(phenoxy)phenyl]methyl] 3-(2,2-dibromoethenyl)-2,2-dimethylcyclopropane-1-carboxylate) on spontaneous fermentation carried out by natural yeast grapes microflora, was studied during the wine-making process. Aliquots of pesticide standard solutions were added to the grapes before crushing, to reach a concentration equal or half the maximum residue limit (MRL). Vinifications were performed, with maceration (R), or without maceration (W). During the wine-making process, samples were taken at the beginning (one hour after grapes crushing), at the middle and at the end of the spontaneous fermentation process. At half the MRL concentration, deltamethrin affected Pichia sp. population with a decrease of almost 50 %, while fenamidone decreased Candida sp., Candida stellata at 83, and 36%, respectively. Metschnikowia pulcherrima population decreased in all samples when compared to the control. Experiments at MRL levels showed a strong reduction for all non-Saccharomyces yeast species, when grapes had been treated with pyraclostrobin, fenamidone, and deltamethrine, except for Candida sp. which was found to have been affected only by fenamidone residues. Growth zone inhibition test showed only an in vitro activity of pyraclostrobin over Kloeckera spp., C. stellata, and M. pulcherrima. Microvinification experiments produced wines with no differences concerning S. cerevisiae population as well as production of ethanol and residual sugars. Experiments showed that at the end of the fermentation process pesticides were adsorbed by the lees and grape skins, and no pesticides residue was detectable in wine. 相似文献
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Ferretti M Calderisi M Bussotti F 《Environmental pollution (Barking, Essex : 1987)》2007,145(3):644-651
The relationships between crown defoliation of beech, visible foliar symptoms on native vegetation and ozone exposure were investigated on permanent monitoring sites in South-Western Europe in the years 2000-2002. Relationships between defoliation of beech and O3 (seasonal mean, 2-week maximum, AOT40) were investigated by means of multiple regression models (11 plots, 1-3 years of data each) and a model based on temporal autocorrelation of defoliation data (14 plots, 1-3 years of data each). Different multiple regression techniques were used. The four models generated (R2=0.71-0.85, explained variance in cross-validation 61-78%) identified several significant predictors of defoliation, with AOT40 (p=0.008) and foliar content of phosphorous (p=0.0002-0.0004) being common to all models. The autocorrelation model (R2=0.55; p<0.0001) was used to calculate expected defoliation on the basis of the previous year's defoliation, and model predictions were used as an estimate of expected defoliation under constant site and environmental condition. Residuals (predicted-measured) plotted against current AOT40 shows that a possible effect of ozone occurs only at very high AOT40 (>35,000 ppbh). O3-like visible foliar symptoms were recorded on 65 species at 47% of the common monitoring sites in 2001 and 38% in 2002. No relationship was found between O3 exposure, frequency of symptomatic sites and frequency of species with symptoms (R2=0.11; p>0.05). A number of questions related to the ecological and methodological basis of the survey were identified. Inherent sampling and non-sampling errors and multicollinearity of the data suggest great caution when examining results obtained from mensurational, correlative studies. 相似文献
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Torresan Filippo Piccinini Leonardo Cacace Mauro Pola Marco Zampieri Dario Fabbri Paolo 《Environmental geochemistry and health》2022,44(7):2135-2162
Environmental Geochemistry and Health - Renewable natural resources are strategic for reducing greenhouse gas emissions and the human footprint. The renewability of these resources is a crucial... 相似文献