Synthesis and characterisation of potassium polytitanate for photocatalytic degradation of crystal violet

Potassium titanate nanostructures were synthesised by hydrothermal treatment of TiO2 （P25） in KOH and H2O2. As-produced powders were characterised by scanning electron microscopy, energy-dispersive X-ray spectroscopy, transmission electron microscopy, X-ray diffraction, and nitrogen adsorption-desorption methods. Longitudinally-oriented-wire-like structures with a length up to several micrometres and diameters ranging from 10 to 30 nm were obtained. Larger size fibrous nanowires resulting from the hydrotherrnal treatment showed high affinity in adsorbing crystal violet （CV）, which was mainly due to their high surface area. The photocatalytic bleaching of CV solution revealed that the wires are photoactive under ultraviolet light irradiation. Macroporous nanowires are considered as effective adsorbents of CV, capable of photocatalvtic degradation, and they can be easily separated from the solution by settling.     

Environmental monitoring of offshore drilling for petroleum exploration (MAPEM Project): shallow waters

This paper deals with the characteristics and composition of municipal solid waste (MSW) generated in Sangamner city. The composition of solid waste was studied by segregating it into different component, i.e., kitchen waste, paper, earth and fine material, slaughter house waste, leaves, metals, etc. These components were categorised into organic waste and inorganic waste. It was observed that Sangamner city produces around 61% organic waste, and the rest is inorganic waste. The characteristics of organic solid waste, i.e., pH, electrical conductivity, moisture content, organic carbon, nitrogen, phosphorus and potassium were evaluated. The analysis of organic content of MSW indicates that it is good source of nutrients for the agriculture sector whereas inorganic material can be used for landfill.     

Influence of sewage sludge,as a substrate,in the plasticity of functional characteristics of plants

This work aimed to evaluate the effect of sewage sludge application as fertilizer on the plasticity of functional characteristics of species commonly found in the Caatinga. The research was developed in the nursery of the Federal Institute of Education, Science and Technology of Ceará (IFCE), Quixadá campus, located in northeastern Brazil. Three treatments were applied: raw sludge, sanitized sludge, and no manipulation. In each treatment, five species were planted, each with five individuals, totaling 75 individuals, which were tagged, and 4 months after germination, they were destroyed to obtain dry matter content (TMSF) from leaf, stem (TMSC), fine root (TMSRF), and thick root (TMSRG); leaf area; height and diameter of the seedling; and length above and below the ground. The sanitized sludge was responsible for giving higher values for leaf area, height of the seedlings, and diameter and length of stem and root. However, the dry matter content of the fine roots was higher in the treatment without manipulation. At the community level, as TMSRG increased, TMSC also increased, the same occurred between TMSRG and TMSRF, TMSC and TMSRF, and stem length and leaf area. In the treatment without manipulation, there was a positive correlation between leaf area, height and plant diameter, and negative correlation between root length and plant diameter. Thus, it can be concluded that the use of sanitized sludge is a good tool to increase the availability of soil resources, conferring to individuals’ greater dry matter content, greater leaf area, and higher height and diameter above the ground.     

Methane production from anaerobic digestion of date palm leaflet waste in Morocco

Journal of Material Cycles and Waste Management - The recovery of date palm leaflet waste (DPLW), generated by palms through anaerobic digestion (AD) technology, attracts more attention...     

Synergy or substitution? The interactive effects of insiders' fairness and support and organizational socialization tactics on newcomer role clarity and social integration

Drawing on fairness heuristics theory (Lind, 2001) and cue consistency theory (Maheswaran & Chaiken, 1991; Slovic, 1966), we test a moderated mediation model that examines whether the institutionalization of organizational socialization tactics enhances or constrains the beneficial effects of supervisory and coworker‐referenced justice and support on newcomer role clarity and social integration. The findings of a three‐wave study of 219 French newcomers show that although institutionalized tactics strengthen the positive indirect effects of supervisory interpersonal and informational justice on role clarity, via perceived supervisor support, it also acts as a substitute that weakens the positive indirect effect of coworker‐referenced interpersonal justice on social integration, via perceived coworker support. Implications of the findings for socialization research and practice are discussed.     

Norovirus Detection at Oualidia Lagoon,a Moroccan Shellfish Harvesting Area,by Reverse Transcription PCR Analysis

Norovirus (NoV) is the leading cause of acute viral gastroenteritis outbreaks in the world. These outbreaks are frequently associated with bivalve shellfish consumption, particularly because these products are often eaten raw or only slightly cooked. In Morocco, regulations concerning the acceptable levels of enteric bacteria indicator organisms in these products have been put in place. However, these regulations do not take into account the risk of viral contamination, and many gastroenteritis outbreaks have been linked to the ingestion of bivalve shellfish from areas that comply with the current food safety criteria. The aim of this study was to investigate NoV presence in shellfish samples (n = 104) collected at four sites owcff Oualidia lagoon (Moroccan Atlantic coast) from November 2015 to February 2017. Samples were analysed using real-time RT-PCR in accordance with the ISO 15216-2 method. NoVs of the genogroup II were detected in 7% of samples that were all collected during the winter months. Moreover, 71% of NoV-positive samples were harvested at sites upstream of the lagoon. These results highlight the need of regularly monitoring viral contamination in bivalve shellfish to limit the risk of viral gastroenteritis outbreaks.

     

Natural radioactivity measurements in building materials in Southern Lebanon

Using gamma-spectroscopy and CR-39 detector, concentration C of naturally occurring radioactive nuclides (226)Ra, (222)Rn, (214)Bi, (228)Ac, (212)Pb, (212)Bi and (40)K, has been measured in sand, cement, gravel, gypsum, and paint, which are used as building materials in Lebanon. Sand samples were collected from 10 different sandbank locations in the southern part of the country. Gravel samples of different types and forms were collected from several quarries. White and gray cement fabricated by Shaka Co. were obtained. gamma-spectroscopy measurements in sand gave Ra concentration ranging from 4.2+/-0.4 to 60.8+/-2.2 Bq kg(-1) and Ra concentration equivalents from 8.8+/-1.0 to 74.3+/-9.2 Bq kg(-1). The highest Ra concentration was in gray and white cement having the values 73.2+/-3.0 and 76.3+/-3.0 Bq kg(-1), respectively. Gravel results showed Ra concentration between 20.2+/-1.0 and 31.7+/-1.4 Bq kg(-1) with an average of 27.5+/-1.3 Bq kg(-1). Radon concentration in paint was determined by CR-39 detector. In sand, the average (222)Rn concentration ranged between 291+/-69 and 1774+/-339 Bq m(-3) among the sandbanks with a total average value of 704+/-139 Bq m(-3). For gravel, the range was found to be from 52+/-9 to 3077+/-370 Bq m(-3) with an average value of 608+/-85 Bq m(-3). Aerial and mass exhalation rates of (222)Rn were also calculated and found to be between 44+/-7 and 2226+/-267 mBq m(-2)h(-1), and between 0.40+/-0.07 and 20.0+/-0.3 mBq kg(-1)h(-1), respectively.     

Risk assessment of chromium and arsenic in date palm leaves used as livestock feed

Appreciable levels of total chromium (Cr) and arsenic (As) were found (by emission spectroscopy) in date palm leaves, which form a significant ingredient in livestock feed. The levels in the fruit were considered safe for human consumption. Our work involved evaluation of the distribution of these elements in the leaves during the developmental stages of the fruiting season. Thirty-six leaf specimens of the Fard cultivar were collected 9, 15 and 20 weeks, respectively, after pollination and subjected to a standard digestion procedure. Sample masses of typically 1 g (dry weight) were prepared in 25 ml dilute acid solution and investigated for trace levels of Cr and As by ICP-AES. Eleven soil samples collected at random during the growth stages were subjected to a similar digestion procedure and analysis. According to the literature, the permissible mean levels of Cr and As in plants are 200 and 80 ng/g (dry weight), respectively. We used these values as our guideline to assess the "risk" levels in our samples of interest. In the case of Cr, about 45% of the specimens possessed levels between 250 and 700 ng/g, while a significant number produced levels between 1000 and 5000 ng/g. With regard to As, about 70% of the samples were above the documented permissible mean value. As a result of the unusually high Cr concentrations in some cases, the feasibility of Cr "accumulation" in the leaves was examined. Insects and other organisms subsist on the leaves and an added concern was the accumulation of these elements in the food chain. The study formed an interesting contribution to environmental research, and the impact of our assessment on the environment is discussed.     

Effects of Rainfall and Ground‐Water Pumping on Streamflow in Mākaha,O’ahu,Hawai’i1

Abstract: Land‐use/land‐cover changes in Mākaha valley have included the development of agriculture, residential dwellings, golf courses, potable water supply facilities, and the introduction of alien species. The impact of these changes on surface water and ground water resources in the valley is of concern. In this study, streamflow, rainfall, and ground‐water pumping data for the upper part of the Mākaha valley watershed were evaluated to identify corresponding trends and relationships. The results of this study indicate that streamflow declined during the ground‐water pumping period. Mean and median annual streamflow have declined by 42% (135 mm) and 56% (175 mm), respectively, and the mean number of dry stream days per year has increased from 8 to 125. Rainfall across the study area appears to have also declined though it is not clear whether the reduction in rainfall is responsible for all or part of the observed streamflow decline. Mean annual rainfall at one location in the study area declined by 14% (179 mm) and increased by 2% (48 mm) at a second location. Further study is needed to assess the effect of ground‐water pumping and to characterize the hydrologic cycle with respect to rainfall, infiltration, ground‐water recharge and flow in the study area, and stream base flow and storm flow.