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排序方式: 共有7310条查询结果,搜索用时 328 毫秒
81.
Yang Zhang Tianyi Zhao Yu Yan Bian Zhou Xuezhen Zhong Xiaoyu Hu Lijia Zhang Peng Huo Kang Xiao Yuanxun Zhang 《环境科学学报(英文版)》2023,35(2):835-845
Ambient particulate matter (PM) can cause adverse health effects via their ability to produce Reactive Oxygen Species (ROS). Water-Soluble Organic Compounds (WSOCs), a complex mixture of organic compounds which usually coexist with Transition Metals (TMs) in PM, have been found to contribute to ROS formation. However, the interaction between WSOCs and TMs and its effect on ROS generation are still unknown. In this study, we examined the ROS concentrations of V, Zn, Suwannee River Fulvic Acid (SRFA), Suwannee River Humic Acid (SRHA) and the mixtures of V/Zn and SRFA/SRHA by using a cell-free 2′,7′-Dichlorodihydrofluorescein (DCFH) assay. The results showed that V or Zn synergistically promoted ROS generated by SRFA, but had an antagonistic effect on ROS generated by SRHA. Fluorescence quenching experiments indicated that V and Zn were more prone to form stable complexes with aromatic humic acid-like component (C1) and fulvic acid-like component (C3) in SRFA and SRHA. Results suggested that the underlying mechanism involving the fulvic acid-like component in SRFA more tending to complex with TMs to facilitate ROS generation through π electron transfer. Our work showed that the complexing ability and complexing stability of atmospheric PM organics with metals could significantly affect ROS generation. It is recommended that the research deploying multiple analytical methods to quantify the impact of PM components on public health and environment is needed in the future. 相似文献
82.
活性艳红X-3B微波辅助光催化脱色的研究 总被引:5,自引:0,他引:5
研究了微波辅助光催化氧化(MW/UV/TiO2)处理活性艳红(X 3B)模拟废水。结果表明:400mg/LX 3B在反应150min时的脱色率由UV/TiO2体系的7.07%、MW体系的13.52%提高到了MW/UV/TiO2体系的56.35%。脱色反应速率随初始浓度(CX 3B)的增大而减慢;在强酸性介质中,脱色率更高;光照度(E)越强,越有利于X 3B脱色反应;改变催化剂投加量对X 3B脱色影响不大;H2O2浓度增加,X 3B脱色率升高;在以上条件下,X 3B的脱色反应均符合一级反应动力学方程,脱色反应中同时存在自由基反应与直接光解反应。 相似文献
83.
CharacteristicsofphosphoruschemistryanditsgeographicaldistributionintheHaiheRivervalley,NorthChinaJiangGaoming;HuangYinxiao;L... 相似文献
84.
YellowRiverValleyfloodanddroughtdisaster:spatial-temporaldistributionpredictionandearly-warningGaoLin,ShaWanying,LiuHuaiquan,... 相似文献
85.
86.
中国米质气候资源的地域分布 总被引:7,自引:1,他引:7
稻米品质受着气候条件的明显影响。在我国不同地域,米质气候资源各不相同,对米质的影响也各具特色,总的趋势是,北方优于南方;西部优于东部;晚茬口水稻优于旱茬口;在地形复杂地区,米质气候资源还具有垂直地带性结构。我国丰富的米质气候资源为各种类型优质米的生产创造出优越的环境条件。 相似文献
87.
In this paper the grid data of total ozone mapping spectrograph (TOMS) installed on Nimbus-7 satellite (1978 to 1994) was used and the spatial and temporal distribution of total ozone over China was analyzed. The research indicates that the Qinghai-Tibet Plateau destroyed the latitudinal distribution of total ozone of China and the low value closed center emerged over Qinghai-Tibet Plateau. Long time change trends of seasonal total ozone of Qinghai-Tibet plateau are provided. It shows that the most obvious decrease of total ozone occurs in winter (Jan.), then in summer (Jul.), the relevant slow change occurs in autumn (Oct.) and spring (Apr.). 相似文献
88.
NitrogenremovalinsequencingbatchreactorWangFuzhen;PengYongzhen;YuErjie;LiBaikun(HarbinArchitecturalandCivilEngineeringInstitu... 相似文献
89.
开发非粘土砖墙体建材应重视它们的隔声、抗震、放射性及隔热等性能是否符合技术标准,避免产生新的社会和环境问题。同时应严格技术考核,政府的倾斜政策也应合理、适度。 相似文献
90.
Muhammad Akram Xing Xu Baoyu Gao Qinyan Yue Shang Yanan Rizwan Khan Muhammad Ali Inam 《环境科学学报(英文版)》2020,32(5):189-198
This study aimed to fabricate new and effective material for the efficiency of phosphate adsorption. Two types of adsorbent materials, the zirconium hydroxides embedded in pomegranate peel (Zr/Peel) and zirconium-lanthanum hydroxides embedded in pomegranate peel (Zr–La/Peel) were developed. Scanning electronic microscopy (SEM), x-ray photoelectron spectroscopy (XPS) and x-ray diffraction (XRD) were evaluated to give insight into the physicochemical properties of these adsorbents. Zr–La/Peel exceeded the adsorption efficiency of Zr/Peel adsorbents in batch adsorption experiments at the same pH level. The peel as a host can strive to have a strong “shielding effect” to increase the steadiness of the entrenched Zr and La elements. La and Zr are hydroxide metals that emit many hydrogen ions during the hydrolysis reaction, which contribute to protonation and electrostatic attraction. The highest adsorption capacity of La–Zr/Peel for phosphate was calculated to be 40.21 mg/g, and pseudo second-order equation is very well fitted for kinetic adsorption. Phosphate adsorption efficiency was reduced by an increase of pH. With the background of coexisting Cl?, little effect on adsorption efficiency was observed, while adsorption capacities were reduced by almost 20–30% with the coexistence of , and humic acid (HA). 相似文献