Changes in visibility with PM2.5 composition and relative humidity at a background site in the Pearl River Delta region

In fall–winter, 2007–2013, visibility and light scattering coefficients(b sp) were measured along with PM_(2.5)mass concentrations and chemical compositions at a background site in the Pearl River Delta(PRD) region. The daily average visibility increased significantly(p 0.01) at a rate of 1.1 km/year, yet its median stabilized at ~13 km. No haze days occurred when the 24-hr mean PM_(2.5)mass concentration was below 75 μg/m~3. By multiple linear regression on the chemical budget of particle scattering coefficient(b sp), we obtained site-specific mass scattering efficiency(MSE) values of 6.5 ± 0.2, 2.6 ± 0.3, 2.4 ± 0.7 and 7.3 ± 1.2 m2/g,respectively, for organic matter(OM), ammonium sulfate(AS), ammonium nitrate(AN) and sea salt(SS). The reconstructed light extinction coefficient(b ext) based on the Interagency Monitoring of Protected Visual Environments(IMPROVE) algorithm with our site-specific MSE revealed that OM, AS, AN, SS and light-absorbing carbon(LAC) on average contributed 45.9% ± 1.6%,25.6% ± 1.2%, 12.0% ± 0.7%, 11.2% ± 0.9% and 5.4% ± 0.3% to light extinction, respectively.Averaged b ext displayed a significant reduction rate of 14.1/Mm·year(p 0.05); this rate would be 82% higher if it were not counteracted by increasing relative humidity(RH) and hygroscopic growth factor(f(RH)) at rates of 2.5% and 0.16/year-1(p 0.01), respectively, during the fall–winter, 2007–2013. This growth of RH and f(RH) partly offsets the positive effects of lowered AS in improving visibility, and aggravated the negative effects of increasing AN to impair visibility.     

固定式燃气内燃机排放特性与大气环境影响研究

燃气内燃机冷热电联供机组由于其特性在城市楼宇型建筑中得到一定的运用,虽然它发电效率高,在建筑规模较小时,其经济性能也优于燃气轮机发电机组,但是其NOx的排放水平较高,噪声较大,因此有必要对其排放特性及污染控制进行研究和探讨.以某城区燃气内燃机冷热电联供项目为例,采用AERMOD烟羽扩散模式首次模拟了该燃气内燃机NOx等污染物排放对周边建筑物不同楼层的影响.结果表明,对近距离高于排气筒高度一定范围内的楼层,NOx的排放影响较大.     

江苏省太湖流域农村生活污水处理现状及对策研究

基于对江苏省太湖流域农村生活污水处理设施的全面调研,统计分析了江苏省太湖流域农村生活污水处理设施现状,包括建设数量、建设规模、处理工艺、运维模式、经费来源等,探讨了江苏省太湖流域农村生活污水处理设施存在的问题并提出建议。结果表明：目前江苏省太湖流域农村生活污水处理设施以中小规模(<100 t/d)为主,主要采用生物生态耦合处理技术,出水一般执行(GB 18918-2002)《城镇污水处理厂污染物排放标准》中的一级B标准,以属地管理的运维模式为主。应加快制订符合江苏省太湖流域的农村生活污水处理设施建设标准,并形成责任主体明确、监管制度完善、资金投入有保障的长效稳定运行体制。     

盐城湿地建设项目对越冬水鸟生境的累积生态影响评价研究

选择盐城湿地的建设项目为研究对象.选取丹顶鹤、雁鸭类和鸻鹬类作为盐城湿地越冬水鸟的代表性物种,选取生境景观类型、土地占用以及人为干扰作为影响因子,利用ArcGIS分别做出三个影响因子对于越冬水鸟生境影响分布图,采用图形叠置法对各因子生境影响进行叠加.据此,以越冬水鸟适宜生境面积的变化来反映建设项目对于越冬水鸟的累积生态影响.并且提出设立鸟类监测救护站和栖息地补偿等生态措施来减少建设项目的影响.     

江苏太湖流域畜禽养殖及农业氮磷污染防治示范区构建技术研究

畜禽养殖废弃物及农业氮磷流失造成的环境面源污染已经成为太湖流域湖泊和水体污染的主要来源之一.通过现场勘查、文献查阅、实地调研等方法,对以太仓为代表的江苏太湖流域畜禽养殖及农业氮磷流失造成的农村生态环境污染问题进行了分析,研究提出了污染防治示范区构建的指导思想、基本原则、技术路径、技术及模式创新点,用五大发展新理念指导污染防治示范区构建,创新畜禽养殖废弃物及农业氮磷污染防治的产业化模式、区域分散畜禽粪便收集服务的社会化体系、覆盖农业氮磷污染防治全程的可控化技术体系.     

The mutagenic potentials of tap water samples in Shanghai

The tap water samples were collected from the users' ends in several areas of Shanghai, which is located in Taihu Lake basin, Eastern China. Source water samples were also collected from two municipal source water facilities at the same time. Samples were assayed by three different short-term mutagenicity test systems: Salmonella/microsome assay (Ames test), the Arabinose resistance test (Ara test) and the SOS/umu test. The data showed that two source water samples did not display direct mutagenic potentials. Two tap water samples from city north, which were directly from Yangtze River, were also not mutagenic. Water samples from city south and middle which used source water originating from Taihu Lake were proved to be contaminated with mutagenic potentials by three different assay techniques. The boiled water displayed an even stronger mutagenic potential compared to its original tap water. The molecular mechanism of mutagenicity was associated with a reading frame-shifting potential. GC-MS analysis of tap water extracts from city middle and corresponding source water was compared. Qualitatively similar spectra were observed except for the peaks of three chlorinated aromatic hydrocarbon compounds, which existed only in the tap water. Since the water source has been polluted, raw water was heavily chlorinated in order to sterilize. More toxic compounds, including mutagens, might form during the multi-chlorination. Caution about the possibility of elevated cancer risks in the population that consumes heavily chlorinated water should be kept in mind. A cohort study in the residents of Shanghai is required.     

Degradation of 4-CP in an internal electrolysis system

The characteristic and mechanism of parachlorophenol (4-CP) degradation in an internal electrolysis system were investigated. The degradation rate of 4-CP was higher in acid solution than that of in neutral or alkaline solution. Addition of activated carbon could make 4-CP easier be degraded by the surface contact catalysis. The dissolved oxygen in solution could take part in the electrode reaction and intensify the degradation of 4-CP. By the analysis of intermediates of degradation of 4-CP, it could be conferred that 4-CP was broken through the bond beside hydroxy firstly, then the bond beside chloride was broken and the chloride was dechlorinated simultaneously. Most intermediate products were glycerine, ethane diacid and acetic acid, while very few 1, 4-butanedial and alcohols were found.     

燃烧假人实验室闪火生成系统设计

对国内外燃烧假人实验室相关标准及闪火生成系统进行介绍,结合应用实际提出闪火的设计要求是热流量84kW/m2,持续时间为5s。最后从管道压力调节、燃烧器设计、嵌入式控制系统开发等三个方面介绍了实验室火闪火生成系统的设计实现。     

童装机械安全性检验与设计

本文分析了由于童装安全性不合格而被召回的案例,针对美国和欧盟的有关童装机械安全性标准,细化解析了标准中有关安全性设计的要求,以期为服装设计和生产提供参考。     

简易干法烟气脱硫技术的试验研究

为了开发研究低投资,低成本的脱硫方法,在研制高活性多孔脱硫剂的过程中,研究了各种因素的影响,并对脱硫剂进行物化特性的表征。脱硫剂比表面积可达４１ｍ＾２／ｇ,粒径分布：０－１μｍ占２４．１％．－１０－２０μｍ占２０．１％;２０－４０μｍ占２９．０％,４０μｍ－６０μｍ占１０．３％。实验室小试,用固定床反应器模拟研究干法烟气脱硫反应过程,烟气相对湿度,脱硫剂比表面积,反应温度等为影响脱硫剂与ＯＳ２反应