全文获取类型
收费全文 | 397篇 |
免费 | 9篇 |
国内免费 | 3篇 |
专业分类
安全科学 | 15篇 |
废物处理 | 14篇 |
环保管理 | 94篇 |
综合类 | 44篇 |
基础理论 | 107篇 |
环境理论 | 1篇 |
污染及防治 | 76篇 |
评价与监测 | 36篇 |
社会与环境 | 14篇 |
灾害及防治 | 8篇 |
出版年
2023年 | 2篇 |
2022年 | 2篇 |
2021年 | 4篇 |
2020年 | 4篇 |
2019年 | 7篇 |
2018年 | 9篇 |
2017年 | 10篇 |
2016年 | 7篇 |
2015年 | 8篇 |
2014年 | 15篇 |
2013年 | 21篇 |
2012年 | 16篇 |
2011年 | 28篇 |
2010年 | 14篇 |
2009年 | 18篇 |
2008年 | 20篇 |
2007年 | 23篇 |
2006年 | 18篇 |
2005年 | 15篇 |
2004年 | 18篇 |
2003年 | 13篇 |
2002年 | 9篇 |
2001年 | 14篇 |
2000年 | 9篇 |
1999年 | 11篇 |
1998年 | 3篇 |
1997年 | 7篇 |
1996年 | 8篇 |
1995年 | 2篇 |
1994年 | 5篇 |
1993年 | 8篇 |
1992年 | 6篇 |
1991年 | 4篇 |
1990年 | 5篇 |
1989年 | 4篇 |
1988年 | 5篇 |
1987年 | 6篇 |
1986年 | 8篇 |
1985年 | 5篇 |
1984年 | 4篇 |
1983年 | 3篇 |
1982年 | 2篇 |
1981年 | 3篇 |
1980年 | 1篇 |
1979年 | 1篇 |
1973年 | 1篇 |
1972年 | 1篇 |
1970年 | 1篇 |
1969年 | 1篇 |
排序方式: 共有409条查询结果,搜索用时 31 毫秒
71.
The influence of pH on the degradation of phenol and chlorophenols by potassium ferrate 总被引:16,自引:0,他引:16
This paper presents information concerning the influence of solution pH on the aqueous reaction between potassium ferrate and phenol and three chlorinated phenols: 4-chlorophenol (CP), 2,4-dichlorophenol (DCP), 2,4,6-trichlorophenol (TCP). The redox potential and aqueous stability of the ferrate ion, and the reactivity of dissociating compounds, are known to be pH dependent. Laboratory tests have been undertaken over a wide range of pH (5.8-11) and reactant concentrations (ferrate:compound molar ratios of 1:1 to 8:1). The reactivity of trichloroethylene was also investigated as a reference compound owing to its non-dissociating nature. The extent of compound degradation by ferrate was found to be highly pH dependent, and the optimal pH (maximum degradation) decreased in the order: phenol/CP, DCP, TCP; at the optimal pH the degree of degradation of these compounds was similar. The results indicate that for the group of phenol and chlorophenols studied, the presence of an increasing number of chlorine substituent atoms corresponds to an increasing reactivity of the undissociated compound, and a decreasing reactivity of the dissociated compound. 相似文献
72.
Observations of 2,4,6-trichlorophenol degradation by ozone 总被引:7,自引:0,他引:7
The aqueous reactivity of 2,4,6-trichlorophenol (TCP) with ozone has been studied at laboratory-scale using a simple gas bubble/liquid contacting system. Degradation rate constants were measured directly and found to be 7.6 and 77.2 M(-1)s(-1) at pH 2 and 7.5, respectively. At pH 7.5, 10 min of ozonation ( identical with 15 mM ozone consumption) achieved a 90% degradation of TCP, which corresponded to the release of approximately 2 mol Cl(-) per mol TCP. The presence of hydrogen peroxide in solution did not significantly increase the TCP degradation but increased the overall dechlorination to 2.7 mol Cl(-) per mol TCP. The presence of humic acid (HA) in solution was found to enhance the degradation rate of TCP at low relative HA concentrations (<0.6 g/g HA:TCP), but to reduce the rate at higher HA concentrations. 相似文献
73.
The degradation of endocrine disruptor di-n-butyl phthalate by UV irradiation: a photolysis and product study 总被引:5,自引:0,他引:5
The direct photolysis of an important endocrine disruptor compound, di-n-butyl phthalate (DBP), has been investigated under monochromatic UV irradiation at 254 nm over a wide pH range (3-11). The investigation was carried out under idealized conditions and has considered both reaction kinetics and the degradation mechanism. It was found that more than 90% of DBP can be degraded within an hour of irradiation in water. A simple model has been developed and used to predict the initial DBP photolysis rate constant at different pH values and initial DBP concentrations. The major decomposition mechanism of DBP is believed to involve the hydrolytic photolysis of the carbon in the alpha and/or beta-position of the ester chain with the production of aromatic carboxylic derivatives. Additionally, multi-degradation pathways are proposed for acid-catalyzed hydrolytic photolysis (pH 3-5), which was found to be useful in explaining the photo-degradation of DBP under acidic conditions. The use of 254 nm UV to photo-degrade DBP was found to be a relatively fast and clean process, especially in neutral to basic conditions. 相似文献
74.
Climate change effects on river flow to the Baltic Sea 总被引:1,自引:0,他引:1
River flow to the Baltic Sea originates under a range of different climate regimes in a drainage basin covering some 1,600,000 km2. Changes to the climate in the Baltic Basin will not only affect the total amount of freshwater flowing into the sea, but also the distribution of the origin of these flows. Using hydrological modeling, the effects of future climate change on river runoff to the Baltic Sea have been analyzed. Four different climate change scenarios from the Swedish Regional Climate Modelling Programme (SWECLIM) were used. The resulting change to total mean annual river flow to the Baltic Sea ranges from -2% to +15% of present-day flow according to the different climate scenarios. The magnitude of changes within different subregions of the basin varies considerably, with the most severe mean annual changes ranging from -30% to +40%. However, common to all of the scenarios evaluated is a general trend of reduced river flow from the south of the Baltic Basin together with increased river flow from the north. 相似文献
75.
The bioavailability and environmental fate of extremely hydrophobic environmental contaminants such as chlorinated dioxins is linked to their solubility characteristics in water. Solubilities of three chlorinated dioxins, viz., 1,2,3,7-T4CDD, 1,2,3,4,7-P5CDD, and 1,2,3,4,7,8-H6CDD, were determined in pure water using a glass bead generator column technique, and their enhanced solubilities in the presence of several dissolved humic fractions quantified at 20, 30 and 40°C. The strengths of these interactions between chlorodioxins and the dissolved humic substances, viz., a fulvic acid, a humic acid, and Aldrich humic acid, were examined using simple thermodynamic calculations. A new partition/association coefficient, Koc (mobile) is defined. 相似文献
76.
Sarah J. Cowell Walter Wehrmeyer Peter W. Argust J. Graham S. Robertson 《Resources Policy》1999,25(4):421
This paper reflects on how sustainability is being interpreted both theoretically and in practice for the primary extraction industries. Two contrasting perspectives can be adopted: one states that continued extraction of non-renewable resources is a necessary part of sustainable development, whilst the other states that extraction of these resources must be greatly reduced or even eliminated. It is shown that these different approaches can be traced back to underlying, often unarticulated, assumptions about the acceptability of trade-offs between different societal goals; attitudes towards uncertainties in scientific analysis and the reliability of management systems; and the perceived appropriateness of system boundaries at different conceptual scales. These assumptions are founded in the self-perception of organisations and individuals about their roles in society, and the cultural context within which these organisations and individuals define their raison d'être. 相似文献
77.
F. A. Hockley C. A. M. E. Wilson N. Graham J. Cable 《Behavioral ecology and sociobiology》2014,68(9):1513-1520
Group living in fish can provide benefits of protection from predators and some parasites, more efficient foraging for food, increased mating opportunities and enhanced energetic benefit when swimming. For riverine species, shoaling behaviour can be influenced by various environmental stressors, yet little is known how flow rate might influence the shoaling of diseased fish shoals. In view of the increasingly unpredictable flow rates in streams and rivers, this study aimed to assess the combined effect of flow condition and parasitism on the shoaling behaviour of a model fish species. Shoal size, shoal cohesion and time spent shoaling of female guppies Poecilia reticulata were compared when infected with the directly transmitted ectoparasite Gyrodactylus turnbulli under flow and static conditions. Flow condition was an important factor in influencing shoaling behaviour of guppies with the fish forming larger shoals in the absence of flow. When a shoal member was infected with G. turnbulli, shoal cohesion was reduced, but the magnitude of this effect was dependent on flow condition. In both flow and static conditions, bigger fish formed larger shoals than smaller counterparts. Future changes to stream hydrology with more frequent flooding and drought events will affect the shoaling tendency of fish. During high-flow events, diseased fish may not be able to keep up with shoal mates and therefore have a higher risk of predation. Additionally, these findings may be important for aquaria and farmed species where an increase in flow rate may reduce aggregation in fish. 相似文献
78.
Dana Swift Joe Rothermel Lance Peterson Brennon Orr Gordon H. Bures Jennifer Weidhaas 《补救:环境净化治理成本、技术与工艺杂志》2012,22(2):49-67
A field pilot test in which hydraulic fracturing was used to emplace granular remediation amendment (a mixture of zero‐valent iron [ZVI] and organic carbon) into fine‐grained sandstone to remediate dissolved trichloroethene (TCE)‐contaminated groundwater was performed at a former intercontinental ballistic missile site in Colorado. Hydraulic fracturing was used to enhance the permeability of the aquifer with concurrent emplacement of amendment that facilitates TCE degradation. Geophysical monitoring and inverse modeling show that the network of amendment‐filled fractures extends throughout the aquifer volume targeted in the pilot test zone. Two years of subsequent groundwater monitoring demonstrate that amendment addition resulted in development of geochemical conditions favorable to both abiotic and biological TCE degradation, that TCE concentrations were substantially reduced (i.e., greater than 90 percent reduction in TCE mass), and that the primary degradation processes are likely abiotic. The pilot‐test data aided in re‐evaluating the conceptual site model and in designing the full‐scale remedy to address a larger portion of the TCE‐contaminated groundwater plume. © 2012 Wiley Periodicals, Inc. 相似文献
79.
Paula Méndez-Fernandez Graham J. Pierce Paco Bustamante Tiphaine Chouvelon Marisa Ferreira Angel F. González Alfredo López Fiona L. Read M. Begoña Santos Jérôme Spitz José V. Vingada Florence Caurant 《Marine Biology》2013,160(11):2825-2840
This study aims to assess niche segregation among the five main toothed whales that frequent the NW Iberian Peninsula waters: the common dolphin, the harbour porpoise, the bottlenose dolphin, the striped dolphin and the long-finned pilot whale. We used cadmium (Cd) and stable isotope ratios (δ13C and δ15N) as ecological tracers to assess degree of segregation in diet/trophic level and in foraging habitat, over various time-scales. δ13C values highlighted different habitats, while Cd concentrations highlighted feeding differences between oceanic and neritic species. Moreover, δ15N values suggest different trophic levels of prey targeted within oceanic and neritic species. Hence, results revealed long-term ecological segregation among five toothed whales that coexist in the NWIP and demonstrated the ability of ecological tracers to discriminate ecological niches among closely related species. 相似文献
80.