Biodegradation of an Epoxy-Based Thermoplastic Polyester, Poly(Hydroxy Ester Ether) in a Laboratory-Scale Compost System

An epoxy-based thermoplastic polyester, poly(hydroxy ester ether), was incubated under aerobic conditions in a laboratory-scale compost system for 168 days to evaluate its potential for biodegradation. Radiolabeled test polymer [uniformly ¹⁴C ring-labeled, poly(hydroxy ester ether)] was incorporated into a mature compost and a sludge-amended compost at a loading of 3 mg test polymer/g compost. ¹⁴C-Cellulose was used as the positive control and a biologically inhibited control reactor was used to assess abiotic degradation of the test polymer. Degradation of the test polymer was assessed by measuring the amount of ¹⁴C-CO₂ from each of the test reactors. In addition, at selected time intervals subsamples of the compost were collected and serially extracted with water, methanol, and dimethylformamide to monitor degradation of the ¹⁴C-test polymer and provide a partial characterization of the degradation intermediates. Extensive degradation of ¹⁴C-poly(hydroxy ester ether) was observed in the test reactors with degradation half-life of the parent polymer (t _1/2) of approximately 32 days. By the end of the study, only 2% of the total ¹⁴C activity in the test reactors was attributed to intact polymer, with most of the measurable ¹⁴C activity converted to either ¹⁴C-CO₂ (26% of total ¹⁴C activity) or nonextractable products (accounting for 60% of the total activity). In contrast to the test reactors, only 3% of the ¹⁴C-poly(hydroxy ester ether) added to the biologically inhibited control reactor was mineralized to ¹⁴C-CO₂. The results obtained from the microbially active and biologically inhibited compost systems indicate that the poly(hydroxy ester ether) polymer was degraded, at least in part, by a biologically mediated process.     

Constituency Bias in a Federal Resource Management Agency: a Confirmatory Analysis

In a 1989 article, Ben Twight and Fremont Lyden compared the attitudes of national forest managers in the United States in 1981 with those of its major constituents to assess the extent to which the U.S. Forest Service was biased: were the beliefs and values of agency employees concerning resource management more representative of one of two major constituent groups, environmentalists and forest utilizers? The research tested Culhane's (Public Lands Politics: Interest Group Influence on the Forest Service and the Bureau of Land Management. Baltimore, Maryland: John Hopkins University Press. 1981) theory that the Forest Service occupies a middle ground in its attitudes relative to those of its environmental and utilization constituencies. They concluded that the agency did not; ideologically, district rangers were quite close to the Forest Service's utilizer constituency and relatively far from its environmentalist constituency. Given recent changes in the attitudes of Forest Services managers, the present study sought to answer the question: what do these changes reveal about the ideological position of the agency in 1981 vis a vis its position in 1990, and what are their implications for continuing concerns over the agency's representation of all interest groups? The response to survey questions of four groups—1990 district rangers and district rangers, environmentalists and forest utilizers in 1981—were combined for statistical comparison. Discriminant analyses were conducted to clarify the differences in the groups. Although the hypothesized bias of the Forest Service toward the traditional utilizer position was confirmed, the results also suggested that managers' values and attitudes had changed over the decade. The major issue underlying this bias—preservation versus utilization of resources—no longer adequately represented the agency's position, which has been fragmented into concerns with multiple issues.     

INFLUENCING WATER LEGISLATWE DEVELOPMENT WHAT TO DO AND WHAT TO AVOID1

ABSTRACT: Whomever would affect water policy development must influence the water legislative process. This paper discusses in the context of the Model State Water Allocation Code the following ten ideas about doing that: (1) seek the right timing for enactment; (2) set modest goals; (3) prepare a well-drafted proposal; (4) recognize diversity by offering legislative choices; (5) consider the impacts of adoption; (6) make alliances; (7) respect executive influence; (8) become involved in legislative interaction; (9) be flexible; and (10) persist. Heeding these ideas, although not guaranteeing enactment, is sure to be educational for participants and useful to legislators.     

Industry and the environment: Chief executive officer attitudes, 1976 and 1986

This research considers the question of changing environmental values within the leadership of firms responsible for the management of pollution as an unwanted byproduct. Information was obtained from a pair of surveys mailed to the chief executive officers (CEOs) of the 50 largest firms listed within the mining and manufacturing directories of Colorado, Montana, Utah, and Wyoming in 1976 and again in 1986. The authors found that industry CEOs were more supportive of environmental concerns in 1986 than 1976, suggesting that ecological values have become institutionalized to some extent. Yet, there is little indication that this attitudinal shift in environmental concern among CEOs has been accompanied by a willingness to spend a larger proportion of the company budget on pollution control or to improve working relationships with federal regulatory officials.     

Making decisions about environmental management when conventional economic analysis cannot be used

A process is described for making comparative valuations of a wide range of environmental management activities when the combined social, economic, managerial, and political benefits of some (but not all) of these activities cannot be adequately described in economic terms and when budgetary constraints do not permit funding of all activities under consideration. The process accounts for subjective judgment and contains a formal rigorous decision strategy that takes the place of intuition when quantitative and qualitative values of environmental activities need to be evaluated.     

Assessing who gains and who loses from natural resource policy: Distributional information and the public participation process

Recent legislation mandates an increased role for public participation in natural resource policy making. This paper presents an operational way to provide those impacted with relevant information and to enable public officials to assess public reaction to proposed policies. The methodology transforms results obtained from a multisector model of income formation and distribution into positive economic measures of distributional impacts. The usefulness of the methodology is illustrated in the context of a policy to increase coal surface mining on public lands.     

400 YEARS OF CENTRAL CALIFORNIA PRECIPITATION VARIABILITY RECONSTRUCTED FROM TREE-RINGS1

ABSTRACT: Coastal central California is a region that has never been the subject of tree-ring studies. New tree-ring chronologies developed from cores of big cone spruce (Pseudotusuga macrocarpa (Torr.) Mayr.) growing in the Transverse Ranges of central Santa Barbara county were used to reconstruct precipitation fluctuations for this region. To verify the new reconstructions, calibration with recorded rainfall using cross-validation, comparison with other reconstructions, and documentary evidence from historical sources were utilized. The precipitation reconstructions show that there have not been fluctuations in mean precipitation on time scales longer than 30 years, but there have been major fluctuations in precipitation variability including changes in the frequency of extremes and rare events that have not occurred in the modern record.     

Design elements of monitoring programs: The necessary ingredients for success

Natural resource managers must know the condition of resources entrusted to their steward-ship so that they can maintain unimpaired resources and know when to restore impaired ecosystems. Resource monitoring programs should be designed to provide indications of ecosystem health, define limits of normal variation, identify abnormal conditions, and suggest potential agents of abnormal changes. Development of a conceptual model that identifies all ecosystem components and their relationships is the first step in the design of such a diagnostic monitoring program. Design studies, with field testing on each selected system component, are required to determine the parameters to be measured and to establish monitoring protocols. The best approach to diagnostic monitoring appears to be based on the population dynamics of selected species relative to physical and chemical environmental factors. Both management and monitoring of natural ecosystems need to be recognized as experimental endeavors, and thus approached in an iterative fashion with the scientific method to reduce uncertainty and cost.     

Updating federal standards for toxicants: n-Hexane as the model

Regulatory agencies commonly set standards for a myriad of chemical and physical hazards, with a special focus on carcinogens. This focus can obscure the need to update previously set standards for non-carcinogenic hazards in response to new scientific data. This paper considers n-hexane as a representative chemical hazard: the occupational standard of 500 ppm over an 8 hr time weighted average for a 40 hr week as set in 1948. In the last 12 yr, n-hexane has been shown to cause adverse effects on the peripheral and central nervous systems, the eye, and the respiratory tract. Yet, these new data have not, as yet, been incorporated into a revised standard for n-hexane. The lack of scientific data on the carcinogenicity of n-hexane may be an underlying reason explaining the failure of regulatory agencies to revise their standards. Perhaps, the most troubling problem to regulatory agencies is the sheer magnitude of the chemical regulatory burden. Research should proceed on developing meaningful categories or groupings both for the initial setting of standards and for revising existing standards.     

Effective application of monitoring information: the case of San Francisco Bay

The San Francisco Estuary Regional Monitoring Program (RMP) for Trace Substances is an innovative partnership among a regulatory agency, more than 70 regulated entities, and an independent scientific organization. The institutional arrangement behind the RMP has made the regulatory system increasingly responsive to emerging management needs, particularly with regard to the development of total maximum daily loads and ecosystem impairment assessment. Through multi-agency partnerships within and outside the RMP institutional structure, major information gaps for several pollutants of concern have been narrowed, resulting in a successful consensus-based regulatory approach to managing copper and nickel mass inputs into the Estuary. Short-term research efforts, based upon monitoring results, helped identify the most cost-effective control and remediation options for various bioaccumulative substances. Additionally, adaptive changes to the monitoring program documented the existence of widespread aquatic toxicity in the Estuary that is apparently due to pesticide runoff from agricultural and urban areas. One of the most important contributions of this collaborative monitoring program is the deliberate and systematic adjustment of management and research questions that serve to influence and add relevance to the overall research agenda related to San Francisco Estuary ecosystem assessment.