Enhanced adsorptive removal of naphthalene intermediates from aqueous solution by introducing reed straw into sewage sludge-based activated carbon

The disposal of sewage sludge (SS) and reed straw (RS) has becoming a critical issue due to their rapid production. In this study, the SS-based activated carbon (SSC) was produced by introducing the RS as a component material. Properties including BET surface area, pore volume, surface chemical groups, and morphologies were characterized. The adsorption of 1-diazo-2-naphthol-4-sulfonic acid (1,2,4-Acid) and 2-Naphthol (2-Nap), which differs in their physicochemical properties, on as-prepared carbons were investigated. The overall adsorption was found to be jointly controlled by external mass transfer and intraparticle diffusion, and the optimal pH was found to be 5 due to their electrostatic attraction. Further study revealed that the SS- and RS-based carbons (SC and RSC, respectively) exhibited different adsorption behavior toward 1,2,4-Acid and 2-Nap. The calculated adsorption capacity from Langmuir–Freundlich model of SC and RSC for the two intermediates was 141.0, 84.6 mg g^-1 and 48.2, 110.2 mg g^-1, respectively, whereas their hybrid product (SSC) showed comparable capacity for 1,2,4-Acid (117.8 mg g^-1), as well as higher capacity for 2-Nap (157.5 mg g^-1). It was found that the presence of meso- or macropores facilitates the precipitation of mineral phases of inorganic substances during carbonization, attracting the molecules with polar functional groups, while the introduction of C-rich RS to SS enhances the adsorption of hydrophobic molecules.     

An improved biofilter to control the dissolved organic nitrogen concentration during drinking water treatment

Environmental Science and Pollution Research - Dissolved organic nitrogen (DON) is a key precursor of numerous disinfection by-products (DBPs), especially nitrogenous DBPs (N-DBPs) formed during...     

Nitrogen use efficiencies in Chinese agricultural systems and implications for food security and environmental protection

Regional Environmental Change - Nitrogen (N) use efficiency (NUE) is an important indicator to evaluate the performance of N use in agricultural systems. Understanding changes in NUE is crucial to...     

基于N-GAS模型的某沙发厂火灾烟气中HCN分布及烟气毒性分析

引入湍流涡耗散概念(EDC)模型,以昆明市某沙发工厂火灾,获得了含有HCN的火灾烟气浓度的时空分布,采用N-GAS模型来评价火灾烟气综合毒性并讨论HCN对于多组分烟气耦合毒性的影响。为了讨论HCN对火灾烟气毒性的影响,本文进行了A、B两组模拟计算,A组烟气组分不包含HCN,B组烟气组分包含HCN。将A、B两组的模拟结果进行对比,验证了引入EDC模型、讨论HCN对多组分火灾烟气毒性的影响具有可行性。基于N-GAS模型的计算结果,说明了HCN气体对于多组分烟气的耦合毒性的影响不可忽略,有时甚至起着至关重要的作用。     

聚乙烯醇缩-5-甲酰基-2,4-二羟基苯偶氮安替比林液-固萃取和光度测定镍的研究

本文报道了2,4-二羟基-5-安替比林偶氮苯甲醛(DAP)及DAP与聚乙烯醇(PVA)的缩合产物(PV·DAP)的合成.并利用PV·DAP做萃取剂,析相萃取和光度测定了铝合金和环境水样中的镍.实验结果还表明,高分子显色剂与相应的小分子试剂相比,在液-固萃取方面表现为易获得高萃取率且不受萃合物电性的影响,在光度测定方面则表现出较高的灵敏度和稳定性.从而说明试剂的高分子化可改善其性能.     

文丘里水膜除尘器后烟气带水的原因及控制对策

通过对一些文丘里水膜除尘器运行情况的实际调查,分析了烟气带水和风机挂灰振动的可能原因,针对不同情况提出了控制烟气带水危害的可行措施。     

滤筒式除尘器的改进及在白云石生产中的应用

介绍了利用改进滤筒、增加导流装置等一系列技术措施,提高滤筒式除尘器性能,使之应用于轻烧白云石除尘系统。实践表明,设备运行稳定,效果良好。     

糖蜜废水生化法处理的现状和最新进展

本文综述了国内外糖蜜废水的生化法处理的现状和最新进展     

浙江省进口废物环境管理现状及对策研究

随着经济社会的快速发展、资源及原材料需求量的不断增加,可用于再生利用的废物进口量近年来大幅度增长,浙江省作为进出口条件相对便利的沿海省份,上述废弃物资的加工利用已逐步形成相当规模的产业市场,但随之带来的环境污染和各类"洋垃圾"事件也成为社会各界和媒体追逐的热点问题.详述了目前浙江省限制类进口废物环境管理的现状情况,根据存在的主要问题,提出了相应的对策建议,为浙江省进口废物环境监管提供指导依据,同时也对全国进口废物管理政策的制定提供技术支撑.     

基于生态水泥的再生混凝土中重金属浸出动力学研究

使用生态水泥、再生骨料制备再生混凝土.分别通过快速浸出实验和长期连续浸出实验对混凝土中的重金属进行浸取,并采用原子吸收光谱法检测浸出溶液中的重金属含量,对比研究再生混凝土与普通混凝土重金属浸出性能差异.研究发现,快速浸出实验条件下,再生混凝土浸出液各重金属浸出浓度高于普通混凝土浸出浓度,但仍低于《危险废物鉴别标准浸出毒性鉴别》(GB5085.3-2007)标准规定的限值.快速浸出实验条件下重金属浸出量与重金属总量相关性不显著,说明快速实验方法有局限性.长期连续浸出实验结果表明,再生混凝土各重金属元素的扩散系数高于普通混凝土(除Zn外),这是由再生混凝土独特的显微结构引起的.