Research and application of method of oxygen isotope of inorganic phosphate in Beijing agricultural soils

Phosphorus (P) in agricultural ecosystems is an essential and limited element for plants and microorganisms. However, environmental problems caused by P accumulation as well as by P loss have become more and more serious. Oxygen isotopes of phosphate can trace the sources, migration, and transformation of P in agricultural soils. In order to use the isotopes of phosphate oxygen, appropriate extraction and purification methods for inorganic phosphate from soils are necessary. Here, we combined two different methods to analyze the oxygen isotopic composition of inorganic phosphate (δ¹⁸O_P) from chemical fertilizers and different fractions (Milli-Q water, 0.5 mol L^?1 NaHCO₃ (pH = 8.5), 0.1 mol L^?1 NaOH and 1 mol L^?1 HCl) of agricultural soils from the Beijing area. The δ¹⁸O_P results of the water extracts and NaHCO₃ extracts in most samples were close to the calculated equilibrium value. These phenomena can be explained by rapid P cycling in soils and the influence of chemical fertilizers. The δ¹⁸O_P value of the water extracts and NaHCO₃ extracts in some soil samples below the equilibrium value may be caused by the hydrolysis of organic P fractions mediated by extracellular enzymes. The δ¹⁸O_P values of the NaOH extracts were above the calculated equilibrium value reflecting the balance state between microbial uptake of phosphate and the release of intracellular phosphate back to the soil. The HCl extracts with the lowest δ¹⁸O_P values and highest phosphate concentrations indicated that the HCl fraction was affected by microbial activity. Hence, these δ¹⁸O_p values likely reflected the oxygen isotopic values of the parent materials. The results suggested that phosphate oxygen isotope analyses could be an effective tool in order to trace phosphate sources, transformation processes, and its utilization by microorganisms in agricultural soils.     

Influence of filtration velocity on DON variation in BAF for micropolluted surface water treatment

Biological aerated filters (BAFs) are widely used for the treatment of micropolluted surface water. However, the biological process produces dissolved organic nitrogen (DON), which, as precursors of nitrogenous disinfection by-products, pose potential threats to drinking water safety. Therefore, to control DON in BAF effluent, it is necessary to study the influence of BAF operation parameters on DON production. In this study, the influence of filtration velocity in a BAF on DON production was investigated. Under different filtration velocity (0.5, 2, and 4 m/h) conditions, profiles of DON concentrations along the media layer were measured. The profile at a filtration velocity of 0.5 m/h showed a decreasing trend, and the ones under filtration velocities of 2 and 4 m/h fluctuated in a small range (from 0.1 to 0.4 mg/L). Moreover, the relatively high filtration velocities of 2 and 4 m/h resulted in a lower level of DON concentration. Additionally, 3D excitation-emission matrix fluorescence spectroscopy was used to characterize DON. It is found that the patterns of DON at a relatively high filtration velocity condition (4 m/h) were obviously different from the ones under low filtration velocity conditions (0.5 and 2 m/h).     

Benchmarking Optical/Thermal Satellite Imagery for Estimating Evapotranspiration and Soil Moisture in Decision Support Tools

Generally, one expects evapotranspiration (ET) maps derived from optical/thermal Landsat and MODIS satellite imagery to improve decision support tools and lead to superior decisions regarding water resources management. However, there is lack of supportive evidence to accept or reject this expectation. We “benchmark” three existing hydrologic decision support tools with the following benchmarks: annual ET for the ET Toolbox developed by the United States Bureau of Reclamation, predicted rainfall‐runoff hydrographs for the Gridded Surface/Subsurface Hydrologic Analysis model developed by the U.S. Army Corps of Engineers, and the average annual groundwater recharge for the Distributed Parameter Watershed Model used by Daniel B. Stephens & Associates. The conclusion of this benchmark study is that the use of NASA/USGS optical/thermal satellite imagery can considerably improve hydrologic decision support tools compared to their traditional implementations. The benefits of improved decision making, resulting from more accurate results of hydrologic support systems using optical/thermal satellite imagery, should substantially exceed the costs for acquiring such imagery and implementing the remote sensing algorithms. In fact, the value of reduced error in estimating average annual groundwater recharge in the San Gabriel Mountains, California alone, in terms of value of water, may be as large as $1 billion, more than sufficient to pay for one new Landsat satellite.     

Emerging Tools for Continuous Nutrient Monitoring Networks: Sensors Advancing Science and Water Resources Protection

Sensors and enabling technologies are becoming increasingly important tools for water quality monitoring and associated water resource management decisions. In particular, nutrient sensors are of interest because of the well‐known adverse effects of nutrient enrichment on coastal hypoxia, harmful algal blooms, and impacts to human health. Accurate and timely information on nutrient concentrations and loads is integral to strategies designed to minimize risk to humans and manage the underlying drivers of water quality impairment. Using nitrate sensors as the primary example, we highlight the types of applications in freshwater and coastal environments that are likely to benefit from continuous, real‐time nutrient data. The concurrent emergence of new tools to integrate, manage, and share large datasets is critical to the successful use of nutrient sensors and has made it possible for the field of continuous monitoring to rapidly move forward. We highlight several near‐term opportunities for federal agencies, as well as the broader scientific and management community, that will help accelerate sensor development, build and leverage sites within a national network, and develop open data standards and data management protocols that are key to realizing the benefits of a large‐scale, integrated monitoring network. Investing in these opportunities will provide new information to guide management and policies designed to protect and restore our nation's water resources.     

Robustness of Meteorological Droughts in Dynamically Downscaled Climate Simulations

We examine the robustness of a suite of regional climate models (RCMs) in simulating meteorological droughts and associated metrics in present‐day climate (1971‐2003) over the conterminous United States (U.S.). The RCMs that are part of North American Regional Climate Change Assessment Program (NARCCAP) simulations are compared with multiple observations over the climatologically homogeneous regions of the U.S. The seasonal precipitation, climatology, drought attributes, and trends have been assessed. The reanalysis‐based multi‐model median RCM reasonably simulates observed statistical attributes of drought and the regional detail due to topographic forcing. However, models fail to simulate significant drying trend over the Southwest and West. Further, reanalysis‐based NARCCAP runs underestimate the observed drought frequency overall, with the exception of the Southwest; whereas they underestimate persistence in the drought‐affected areas over the Southwest and West‐North Central regions. However, global climate model‐driven NARCCAP ensembles tend to overestimate regional drought frequencies. Models exhibit considerable uncertainties while reproducing meteorological drought statistics, as evidenced by a general lack of agreement in the Hurst exponent, which in turn controls drought persistence. Water resources managers need to be aware of the limitations of current climate models, while regional climate modelers may want to fine‐tune their parameters to address impact‐relevant metrics.     

Glyphosate input modifies microbial community structure in clear and turbid freshwater systems

Since it was commercially introduced in 1974, glyphosate has been one of the most commonly used herbicides in agriculture worldwide, and there is growing concern about its adverse effects on the environment. Assuming that glyphosate may increase the organic turbidity of water bodies, we evaluated the effect of a single application of 2.4?±?0.1 mg l^?1 of glyphosate (technical grade) on freshwater bacterioplankton and phytoplankton (pico, micro, and nanophytoplankton) and on the physical and chemical properties of the water. We used outdoor experimental mesocosms under clear and oligotrophic (phytoplanktonic chlorophyll a?=?2.04 μg l^?1; turbidity?=?2.0 NTU) and organic turbid and eutrophic (phytoplanktonic chlorophyll a?=?50.3 μg l^?1; turbidity?=?16.0 NTU) scenarios. Samplings were conducted at the beginning of the experiment and at 1, 8, 19, and 33 days after glyphosate addition. For both typologies, the herbicide affected the abiotic water properties (with a marked increase in total phosphorus), but it did not affect the structure of micro and nanophytoplankton. In clear waters, glyphosate treatment induced a trend toward higher bacteria and picoeukaryotes abundances, while there was a 2 to 2.5-fold increase in picocyanobacteria number. In turbid waters, without picoeukaryotes at the beginning of the experiment, glyphosate decreased bacteria abundance but increased the number of picocyanobacteria, suggesting a direct favorable effect. Moreover, our results show that the impact of the herbicide was observed in microorganisms from both oligo and eutrophic conditions, indicating that the impact would be independent of the trophic status of the water body.     

Simultaneous removal of potent cyanotoxins from water using magnetophoretic nanoparticle of polypyrrole: adsorption kinetic and isotherm study

Cyanotoxins, microcystins and cylindrospermopsin, are potent toxins produced by cyanobacteria in potable water supplies. This study investigated the removal of cyanotoxins from aqueous media by magnetophoretic nanoparticle of polypyrrole adsorbent. The adsorption process was pH dependent with maximum adsorption occurring at pH 7 for microcystin-LA, LR, and YR and at pH 9 for microcystin-RR and cylindrospermopsin (CYN). Kinetic studies and adsorption isotherms reflected better fit for pseudo-second-order rate and Langmuir isotherm model, respectively. Thermodynamic calculations showed that the cyanotoxin adsorption process is endothermic and spontaneous in nature. The regenerated adsorbent can be successfully reused without appreciable loss of its original capacity.     

Climate change,multiple stressors and human vulnerability: a systematic review

We systematically reviewed current climate change literature in order to examine how multiple processes that affect human vulnerability have been studied. Of the 125 reviewed articles, 79 % were published after 2009. There are numerous concepts that point out to stressors other than climate change that were used in reviewed studies. These different concepts were used interchangeably, and they illustrate processes that act on different scales. Most widely used concepts included non-climatic (40 % of the articles), multiple stressors (38 %) and other factors (37 %). About 75 % of the studies either acknowledged or carefully analyzed the social and environmental context in which vulnerability is experienced. One-third of the studies recognized climate change-related stressors as the most important, one-third argued that stressors other than climate are more important, and the rest of the studies did not analyze the relative importance of the different processes. Interactions between different stressors were mentioned in 76 % and analyzed explicitly in 28 % of the articles. Our review shows that there are studies that analyze the social context of vulnerability within climate change-related literature and this literature is rapidly expanding. Reviewed studies point out that there are multiple interacting stressors, whose interlinkages need to be carefully analyzed and targeted by policies, which integrate adaptation to climate change and other stressors. In conclusion, we suggest that future studies should include analytical frameworks that reflect dissimilarities between different types of stressors, methodological triangulation to identify key stressors and analysis of interactions between multiple stressors across different scales.     

Decline of woody vegetation in a saline landscape in the Groundnut Basin,Senegal

Several studies have documented that vegetation in the Sahel is highly dynamic and is affected by the prevailing climatic conditions, as well as by human use of the areas. However, little is known about vegetation dynamics in the large saline areas bordering the rivers of West Africa. Combining satellite imagery, the perception of local people and botanical information, this study investigated the vegetation dynamics and the drivers of vegetation changes in Fatick Province, Senegal. Satellite images showed a change in vegetation composition, i.e., a loss of tree cover and an increase in shrub cover, herbaceous cover and tans (highly saline areas with sparse vegetation). Although the trend was the same, the three villages had different vegetation histories. A survey of the woody vegetation showed that shrubs and young trees were dominating with relatively few large trees. Local people perceived a general decline of woody plants from 1993 to 2013. Among 60 species mentioned by local people, 90 % were declining and 10 % increasing. Together the three methods documented a decrease in density and diversity of the woody vegetation, mainly influenced by salinity and land use. The large numbers of young trees indicate a potential for regeneration of some, but not all, tree species. As many tree species appreciated by local people were reported to be declining, local communities have experienced a reduction of their natural resources. Based on villagers’ recommendations for improved vegetation management, we discuss possible contributions including reforestation, desalinization and environmental protection for restoration of the vegetation.     

Conservation of animals traded for medicinal purposes in Brazil: Can products derived from plants or domestic animals replace products of wild animals?

Regional Environmental Change - The use and trade of animals in traditional medicine involves many different species, some of which are threatened with extinction. Thus, evaluating biological and...