A combined approach of physicochemical and biological methods for the characterization of petroleum hydrocarbon-contaminated soil

Main physicochemical and microbiological parameters of collected petroleum-contaminated soils with different degrees of contamination from DaGang oil field (southeast of Tianjin, northeast China) were comparatively analyzed in order to assess the influence of petroleum contaminants on the physicochemical and microbiological properties of soil. An integration of microcalorimetric technique with urease enzyme analysis was used with the aim to assess a general status of soil metabolism and the potential availability of nitrogen nutrient in soils stressed by petroleum-derived contaminants. The total petroleum hydrocarbon (TPH) content of contaminated soils varied from 752.3 to 29,114 mg kg^?1. Although the studied physicochemical and biological parameters showed variations dependent on TPH content, the correlation matrix showed also highly significant correlation coefficients among parameters, suggesting their utility in describing a complex matrix such as soil even in the presence of a high level of contaminants. The microcalorimetric measures gave evidence of microbial adaptation under highest TPH concentration; this would help in assessing the potential of a polluted soil to promote self-degradation of oil-derived hydrocarbon under natural or assisted remediation. The results highlighted the importance of the application of combined approach in the study of those parameters driving the soil amelioration and bioremediation.     

流域立法视角下生态流量保障的制度供给--以长江流域为例

生态流量保障的重难点在于流域生态流量不足问题的妥善解决。生态流量不足基于产生的原因可分为“自然型”和“人为型”。“人为型”生态流量不足的根源在于《水法》第4条规定的三生用水关系未得到妥善处理,实质上是水资源分配和管理不合理所致。具体表现为水资源保护理念镶嵌在制度表层、生态流量缺乏核心制度保障、流域规划匮乏强效监督机制、流域水资源分配信息公开不足、末端行政考核制度偏重水质管控、生态用水制度顶层设计与地方实施间落差巨大等。流域立法作为立法体系的中间环节,对上位法具有填补协调功能,对地方立法具有引领指导作用。建议在流域立法过程中,通过制度设计解构流域生态流量保障现存的制度困境,主要包括以下几个方面:一是完成流域特有保护理念到实体制度的转型。二是基于流域生态修复、水资源生态红线管控制度的开展以及有效衔接规划环境影响评价制度的需要,建立生态流量管控指标制度体系不可或缺。三是基于流域规划对三生用水的初始分配性,将生态流量供给纳入流域规划体系中,从水资源分配初始阶段保障生态流量,同时强化流域水资源规划制度的监督机制,健全规划制定的程序性规范,明确科学考察和调查评价人员的构成规则、方式及模式。四是依法加深政府信息公开程度保障公众的知情权、参与权及监督权。五是完善行政考核制度体系强化对生态流量供给的考核。     

Phosphorus transformation under the influence of aluminum,organic carbon,and dissolved oxygen at the water-sediment interface: A simulative study

• The three simulation factors caused various changes in both water and sediment. • Responses to simulations differed with the reported natural lakes and wetlands. • Al has dominant effects on sediment P release control among the three factors. • Adding sediment Al can be effective and safe under the simulated conditions. • Polyphosphates were not generated, while added phytate was rather stable. The effects of sediment aluminum (Al), organic carbon (OC), and dissolved oxygen (DO) on phosphorus (P) transformation, at the water-sediment interface of a eutrophic constructed lake, were investigated via a series of simulative experiments. The above three factors had various influences on dissolved P concentration, water pH, water and surface sediment appearance, and P fractions. Additions of Al had the greatest effect on suppressing P release, and the water pH remained alkaline in the water-sediment system under various OC and DO conditions. No dissolution of the added Al was detected. ³¹P-NMR characterization suggested that OC addition did not promote biological P uptake to polyphosphates under oxic conditions. The simulation result on the added phytate indicated the absence of phytate in the original lake sediment. As compared to the reported natural lakes and wetland, the water-sediment system of the constructed lake responded differently to some simulative conditions. Since Al, OC, and DO can be controlled with engineering methods, the results of this study provide insights for the practical site restorations.     

一株耐铬不动杆菌对十二烷基硫酸钠的降解特性

研究醋酸钙不动杆菌H1的降解广谱性时,发现其能在高浓度十二烷基硫酸钠(SDS)环境中生长。经过对菌株H1降解特性研究,结果表明,该菌利用SDS的最适温度为30℃,最适pH为7.0,最适接种量为2%,并适应低渗透压环境。当SDS浓度低于400 mg/L时,菌株H1对SDS的降解率在85%以上,且在SDS浓度为400 mg/L时,达到最大降解率94%。当K2Cr2O7为500 mg/L时,菌株H1对SDS的降解率仍达到50%左右。添加酵母浸出物可促进SDS的降解。     

PCDD/Fs-induced oxidative damage and antioxidant system responses in tobacco cell suspension cultures

Polychlorinated dibenzo-p-dioxins and polychlorinated dibenzofurans (PCDD/Fs) are ubiquitous contaminants and can be considerably accumulated by natural plants. In order to elucidate the biochemical and physiological responses of plant to PCDD/Fs, tobacco Bright Yellow-2 (BY-2) cells were selected as model plant and treated with time- and concentration-dependent PCDD/Fs. The toxic effect and oxidative stress caused by PCDD/Fs were evident, which could be indicted by the reduction in fresh mass, the increase in malondialdehyde (MDA) content, and the damage of tobacco cell ultrastructure. PCDD/Fs tolerance was correlated with changes in antioxidant system and hormones of tobacco cells. Superoxide dismutase (SOD) and peroxidase (POD) exhibited peak enzyme activities at the PCDD/Fs concentration of 1000 ng WHO₉₈-TEQ g⁻¹ fresh weight. Glutathione reductase (GR) enzyme activity increased monotonically at high level PCDD/Fs, but the activity of catalase (CAT) was only slightly affected at all treatment. Meanwhile, the exposure to PCDD/Fs resulted in the changes of hormones content. With the increase of exposure concentration of PCDD/Fs, the levels of indole-3-acetic acid (IAA) and abscisic acid (ABA) increased, whereas the concentration of jasmonates (JAs) decreased. The above results suggest that tobacco cells had the ability to cope with the oxidative stress induced by low concentration of PCDD/Fs through increasing the activities of antioxidant enzymes and alternating plant hormones levels. However, oxidative stress and toxicity would burst out when plant cells were exposed to the high levels of PCDD/Fs.     

硅藻土强化混凝处理线路板含络合铜废水

采用硅藻土对聚合硫酸铁（PFS）、聚合氯化铝（PAC）的混凝能力进行强化,并用于线路板含络合铜废水中铜的去除。考察了硅藻土加入量、混凝剂加入量、pH、快速搅拌速率和沉淀时间等因素对除铜效果的影响,并与目前常用的硫化钠破络方法进行了对比。实验结果表明：硅藻土强化混凝的除铜效果明显好于单独投加PAC或PFS;PFS-硅藻土除铜效果好于PAC-硅藻土;在pH为8.0~9.0、硅藻土加入量为120 mg/L、PFS加入量为60 mg/L、快速搅拌速率为250 r/min的条件下,沉淀40 min后可使出水铜质量浓度低于0.30 mg/L,比传统破络工艺出水水质更稳定,成本更低。     

基于GIS与SketchUp的矿井三维可视化方法研究

为更加实时、直观地体现矿井信息及三维地学信息,本文运用ArcGIS软件与SketchUp Pro软件,分别建立矿井三维地层模型,地表景观模型与工程巷道模型,最终在.NET与ArcEngine编程环境中实现原型系统集成并进行二次开发。经实践证明,本技术方案所实现的矿井模型三维可视化效果形象直观、沉浸感强,成果切实可靠。这对煤矿开采设计水平的提高及其应急管理决策支持软件的研发有一定的借鉴意义。     

岷江中下游生态景观格局变化

以生态景观理论为基础,地理信息与遥感技术为支撑,对三期遥感影像数据,1990年和2002年TM数据、2014年ETM+数据进行土地覆被变化监测,景观格局指数定量分析,面积转移矩阵统计,对9种社会与自然驱动力因素降维转化,分析景观格局变化主要驱动力因素,研究结果表明:(1)研究区内景观类型面积排序:林地草地农田水域居民地裸地。1990—2014年期间林地所占比例由78.03%下降到68.97%,农田比例由6.85%上升到10.91%。居民地所占比例升高了4.1%。(2)农田发生变化的区域主要分布在岷江、大渡河两侧以及西南山地附近。林地减少的区域主要在岷江、青衣江、大渡河交汇的西北部。1990—2002年,林地分别向草地和农田转化了14061.0 hm~2和13891.0 hm~2;此外,水域向裸地转化了214.3 hm~2。2002—2014年,林地向草地、农田、居民地分别转化了3932.0 hm~2、3240.0 hm~2、801.0 hm~2;同时草地景观向农田、居民地进行了转化,分别为10164.0 hm~2、826.0 hm~2。(3)PC1和PC2主成分载荷超过0.8的变量中,导致区域景观发生变化的主要驱动力因子是农业耕作面积扩大和城市化进程。     

居民对室内空气质量安全认知程度的调查研究

为了解山西省城市居民对室内空气质量安全的认知情况和室内空气质量现状,在山西省太原、大同、晋城和吕梁随机选取786户居民进行问卷调查,并对有检测意愿的86户居民进行室内甲醛含量检测.结果表明,山西省居民室内空气质量安全认知得分15.37,得分率为51%;山西省居民平均室内甲醛浓度(0.197 mg/m3)超过国家标准(0.1 mg/m3);四市中太原市的情况最好.山西省居民在室内空气质量安全方面的认知水平和室内空气质量都不高,为保障山西省居民健康,应对山西省城市居民进行室内空气质量安全知识的普及.     

张家口市农业源污染现状及农业减排分析

随着农村经济的快速发展,农业污染问题日趋严重。张家口市农业的污染源主要是畜禽养殖业,根据其污染特点,提出适合张家口市规模化养殖和专业户养殖的以沼气为纽带的生态养殖场模式和户用沼气池生态庭院模式,这两种模式基本都能达到畜禽养殖业的"零排放"。此外,加强政府管理力度、积极发挥政府引导作用,也是农业减排的重要措施之一。