Evaluation of SWAT sub-daily runoff estimation at small agricultural watershed in Korea

A study was undertaken for the prediction of runoff flow from 0.8 ha field-sized agricultural watershed in South Korea using Soil and Water Assessment Tool (SWAT) sub-daily. The SWAT model with sub-daily configuration predicted flow from the watershed within the range of acceptable accuracy. The SWAT sub-daily simulations were carried out for a total of 18 rainfall events, 9 each for calibration and validation. Overall trend and extent of matching simulated flow for the rainfall events in 2007-2008 with measured data during the calibration process were coefficient of determination (R²) value of 0.88 and Nash and Sutcliffe Efficiency (E_NS) value of 0.88. For validation, R² and E_NS values were 0.9 and 0.84, respectively. Whereas R² and E_NS values for simulation results using daily rainfall data were 0.79 and -0.01, respectively, that were observed to be out of acceptable limits for the model simulation. The importance of higher time resolution (hourly) precipitation records for flow simulation were evaluated by comparing R² and E_NS with 15 min, 2 h, 6 h and 12 h precipitation data, which resulted in lower statistics with increases in time resolution of precipitation data. The SWAT sub-daily sensitivity analysis was performed with the consideration of hydraulic parameter and was found as in the rank order of CN2 (curve number), ESCO (soil evaporation compensation factor), GW_DELAY (ground water delay time), ALPHA_BF ( base flow alpha factor), GWQMN ( a threshold minimum depth of water in the shallow aquifer required for return flow to occur) , REVAPMN (minimum depth of water in shallow aquifer for re-evaporation to occur) , LAT_TIME (lateral flow travel time) respectively. These sensitive parameters were evaluated at 10% higher and lower values of the parameters, corresponding to 70.5% higher and 23.2% lower in simulated flow out from the SWAT model. From the results obtained in this study, hourly precipitation record for SWAT sub-daily with Green-Ampt infiltration method was proven to be efficient for runoff estimation at field sized watershed with higher accuracies that could be efficiently used to develop site-specific Best Management Practices (BMPs) considering rainfall intensity, rather than simply using daily rainfall data.     

Formation of dimethyldithioarsinic acid in a simulated landfill leachate in relation to hydrosulfide concentration

Dimethyldithioarsinic acid (DMDTA^V), present in such intense sources as municipal landfill leachate, has drawn a great deal of attention due to its abundant occurrence and different aspect of toxicity. The hydrosulfide (HS⁻) concentration in leachate was studied as a major variable affecting the formation of DMDTA^V. To this end, the HPLC–ICPMS system equipped with the reversed-phase C18 column was used to determine DMDTA^V. Simulated landfill leachates (SLLs) were prepared to cover a mature landfill condition with the addition of sodium sulfate and sulfide at varying concentrations in the presence of dimethylarsinic acid (DMA^V). The concentration of sodium sulfide added in the SLLs generally exhibited a strong positive correlation with the concentration of DMDTA^V. As such, the formation of DMDTA^V in the SLLs is demonstrated to be controlled by the interactive relationship between DMA^V and the HS⁻.

     

Controlling the Behaviors of Biodegradable/Bioabsorbable Polymers with Cyclodextrins

The cyclic six, seven, and eight-membered oligosaccharides -, -, and -cyclodextrins (CDs) can serve as hosts for a variety of polymer guests to form crystalline inclusion compounds (ICs), wherein the guest polymers are included in the continuous narrow channels (0.5–1.0 nm in diameter) formed by the host CD stacks. Polymers included as guests in CD-ICs are highly extended and segregated from neighboring chains by the walls of the host CD bracelets. As a consequence, when polymer-CD-ICs are treated with solvents for CDs that are non-solvents for the included polymers or with amylase enzymes, the CDs are removed and the guest polymers are coalesced into bulk samples whose structures, morphologies, and even chain conformations are different from those achieved by consolidation from their randomly coiling, entangled solutions and melts. Often these CD-IC coalesced and consequently reorganized polymer samples exhibit properties that are distinct from their normally processed bulk samples. Here we describe the CD-IC processing of several biodegradable/bioabsorbable homopolymers, copolymers, and blends made from poly (L-lactic acid), poly (-caprolactone), and poly (-hydroxybutyrate)s, with special emphasis placed on their improved and controllable properties. For example, the phase segregation and consequent crystallinities of their normally incompatible homopolymer blends and their block copolymers may be controlled and thus improved. In addition, co-inclusion of small molecule guests, such as drugs or anti-bacterials, in their common CD-ICs, and subsequent coalescence, yields well-mixed blends of these biodegradable/bioabsorbable polymers and the small molecule co-guests, which may lead, for example, to the improved delivery of drugs.     

APPLICATION OF THE GENETIC ALGORITHM FOR OPTIMIZING OPERATION RULES OF THE LiYuTan RESERVOIR IN TAIWAN1

ABSTRACT: A procedure to apply genetic algorithm to optimize operation rules is proposed and applied to the LiYuTan Reservoir in Taiwan. The designed operation rules are operation zones with discount rates of water supply. The first step of the procedure is to predefine the shape of boundary curves of operation zones according to reservoir storage routing. Then, relatively fewer variables are used to describe the curves, and a last genetic algorithm (GA) is applied to optimize the curves. The procedure is applied to the newly built LiYuTan Reservoir for increasing domestic water demands. Shortage index is used to evaluate the performance of operation zones. A year is divided into 36 operational periods, with each month containing three operational periods. The shortage indexes calculated in operational periods are 9.81, 8.27, and 7.13, respectively, for the reservoir without operation rules, applying operation zones optimized by GA with encoding 36 storage levels for each curve, and adopting operation zones optimized by GA with encoding the curves with predefined shape. The average deficits for the three cases are 77.2, 43.6, and 33.3 (10⁴ m³/day), respectively. The results indicate that operation zones optimized by the proposed procedure have smaller shortage indexes and lower average deficits. In addition, the optimized operation zones have less variation and thus are more practical for operation. Conclusively, the proposed procedure utilizing GA to optimize operation zones with predefined shape can provide better and realistic outcomes through limited iterations.     

Effect of Poly(l-Lactide) and Poly(Butylene Succinate) on the Growth of Red Pepper and Tomato

Seeds of red pepper and tomato were sowed and cultivated in a soil blended with powdery poly(l-lactide) (PLLA), and poly(butylene succinate) (PBS). PBS depressed the growth of the two plants significantly even at a concentration as low as 5%, whereas PLLA up to 35% affected negligibly or even boosted the growth of the two plants. pH and number of microbial cells in the soil after 80 days of cultivation were almost the same independently whether the soil was blended with the two polymers or not. In contrast, the molecular weight of PBS decreased much faster than that of PLLA. Because succinic acid and 1,4-butane diol, from which PBS was synthesized, exhibited toxicity to both plant and animal cells to retard the germination rate of young radish seeds and to deform the morphology of HeLa cells significantly [1], the monomers and the oligomers produced from the PBS degradation should have a detrimental influence on the growth of the two plants.     

Photocatalytic decomposition of mobile-source related pollutants using a continuous-flow reactor

This study evaluated the application of a continuous-flow photocatalytic reactor for the control of two mobile-derived pollutants, methyl-tertiary butyl ether (MTBE) and naphthalene, present at in-vehicle levels. Variables tested for this study included the hydraulic diameter (HD), stream flow rate (SFR), relative humidity (RH), and feeding type (FT). The fixed parameters included contaminant concentration, ultraviolet light source, and the weight of TiO2. In all experimental conditions the adsorption proce...     

Solubilization of water-insoluble beta-glucan isolated from Ganoderma lucidum

The fungal beta-D-glucan is a biological response modifier (BRM), but a major obstacle to the clinical utilization of beta-glucan BRMs is thei relative lack of solubility in aqueous media. Water insoluble fungal glucans extracted by alkali from the mycelia of Ganoderma lucidum were sulfated to yield their corresponding water-soluble derivatives. Insoluble glucan is dissolved in methyl sulfoxide and urea, and is partially sulfated with sulfuric acid. The sulfated glucan (SGL) yield prepared from insoluble glucan (IGL) was 85%, the sulfation degree of SGL was about 14.9%, and the solubility of SGL was above 95% in water. The monosugar SGL content was 34.9% alpha-glucose and 35.9% beta-glucose. The mean molecular weight (MW) of SGL was shown as a single peak on Sepharose CL-4B column chromatography, and their MW was approximately 9.3 kDa. The 13C NMR spectrum analysis shows that SGL has a high similarity with the beta-(1-->3)-linked triple-helical control.     

Survey of coastal inland pollution sources and their influence on seawater quality in Doam bay,Korea

Inland pollution sources of Doam bay were investigated from August to October in 2013. A total of 210 sources including rivers, streams, domestic, agricultural and industrial discharge points were identified along the coast, including 32 sources that had outflow. Agricultural sources were the largest inland pollution sources (139, 66.2%). Fecal coliform concentrations were measured. These data were combined with water discharge data to determine daily loads of pollutants discharged from each source into the bay. Fecal coliform concentrations were the highest in domestic discharges. However, they only had slight influence because their discharge volume was small. The most significant pollution source was Tamjin River (St.85) due to large amount of discharge volume. The influence of St.85 reached almost half of Doam bay. Fecal coliform levels of streams increased after rainfall, but decreased overtime. Domestic pollution sources were not affected upon rain event.