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221.
Babay PA Romero Ale EE Itria RF Becquart ET Thiele B Batistoni DA 《Journal of environmental monitoring : JEM》2008,10(4):443-452
In the present work we have developed an analytical methodology for the determination of nonylphenol (NP) and nonylphenol mono- and di-ethoxylates (NP1EO and NP2EO) in water samples. The applicability of this methodology was proved by means of the analysis of environmentally relevant aqueous samples from Buenos Aires. This constitutes a starting point for a rigorous assessment of the incidence of NPnEO surfactants in Argentina, as only very few, qualitative or semi-quantitative data on the occurrence of these compounds in local systems were available up to this time. Enrichment of the analytes was carried out by solid-phase extraction on a C-18 sorbent, followed by elution with ethyl acetate. Normal-phase high performance liquid chromatography on an amino-silica column and fluorescence detection at excitation-emission wavelengths of 230-300 nm were employed for separation and quantification of the analytes. Confirmation of peak assignment in selected real samples was performed by off-line coupling HPLC with GC-MS analysis. A non-polar GC capillary column was used, and a characteristic peak pattern was obtained for the alkyl chain isomers of each ethoxylated homologue and NP. GC-MS analyses yielded in all cases purity levels higher than 80% for the HPLC collected fractions. The elevated concentrations found for the estrogenic metabolites of NPnEO are in accordance with an unrestricted use of this class of non-ionic surfactants in the country. 相似文献
222.
The comparison of heavy metal accumulation ratios of some fish species in Enne Dame Lake (Kütahya/Turkey) 总被引:1,自引:0,他引:1
Uysal K Köse E Bülbül M Dönmez M Erdogan Y Koyun M Omeroglu C Ozmal F 《Environmental monitoring and assessment》2009,157(1-4):355-362
The metal accumulation levels for muscle, skin, gill, liver and intestine tissues of some Cyprinidae species (Carassius carassius, Condrostoma nasus, Leuciscus cephalus and Alburnus alburnus) in Enne Dame Lake (Kütahya/Turkey), which is mostly fed by hot spring waters, were investigated. Analyses were performed for copper (Cu), zinc (Zn), manganese (Mn), iron (Fe), cobalt (Co), magnesium (Mg), nickel (Ni), chrome (Cr) and boron (B) using inductively coupled plasma-optic emission spectroscopy (ICP-OES), and cadmium (Cd) using atomic absorption spectrophotometer (AAS) utilizing microwave digestion techniques. The concentrations of the heavy metals found in the fish varied in the follow ing ranges: Cu: < DL-7.04, Zn: 6.96-357.25, Mn: < DL-20.70, Ni: < DL-6.21, Fe: 9.62-2500.33, Cr: < DL-1.74, Co: < DL-0.54, Cd: 0.01-0.27 and Mg: 197.44-904.90 mg/kg wet weight. While B had the second highest concentration in the water of the lake, it was not encountered in any tissue of the investigated species. In all tissues and the species, While the bioaccumulation factors (BAFs) of Mn, Zn, Fe and Cu were remarkably high, the BAFs of Mg, Cr, Co, and B were also fairly low or none. Although the heavy metal accumulation levels for the muscle were generally lower than other tissues, there were some exceptions. Cd level in the muscle of C. carassius was higher than the permissible limit stated by Turkish legislation, FAO and WHO. The mean metal amounts for all the investigated tissues and species are statistically compared and discussed in this study. 相似文献
223.
Zafer Ziya Öztürk Cihat Tasaltin Güleda Önkal Engin Ayşe Gül Gürek Devrim Atilla Vefa Ahsen Mahir İnce 《Environmental monitoring and assessment》2009,151(1-4):369-375
Sewage treatment works are one of the major sources that cause atmospheric odour pollution. The increase in the number of complaints about odour nuisance is due to the increase in environmental concerns. Unfortunately, the legislation on odour nuisance from sewage treatment works is very limited. In order to determine suitable thresholds on which to base legal standards, reliable and efficient odour measurement methods need to be defined. A chemical sensor array was developed for the purpose of measuring wastewater odour. This paper describes the development of the chemical sensor system which is specifically tuned to odours of wastewater origin and which can give an electronic measure of the wastewater odours. Odour emissions from a wastewater treatment facility were detected by using a quartz crystal microbalance (QCM) sensor array. The array consists of nine sensor elements, which were coated with different materials. In this paper, the usage of these novel instruments in the water industry was shown. 相似文献
224.
Badreddine Barhoumi Karyn LeMenach Marie-Hélène Devier Walid Ben Ameur Henry Etcheber Hélène Budzinski Jérôme Cachot Mohamed Ridha Driss 《Environmental monitoring and assessment》2014,186(5):2653-2669
To assess the status of polycyclic aromatic hydrocarbon (PAH) contamination in sediments from the Bizerte Lagoon (northern Tunisia), 18 surface sediment samples were collected in March 2011 and analyzed for 14 US Environmental Protection Agency priority PAHs by high-performance liquid chromatography. The total concentrations of the 14 PAHs (ΣPAHs) ranged from 16.9 to 394.1 ng g?1 dry weight (dw) with a mean concentration of 85.5 ng g?1 dw. Compared with other lagoons, coasts, and bays in the world, the concentrations of PAHs in surface sediments of the Bizerte Lagoon are low to moderate. The PAHs’ composition pattern was dominated by the presence of four-ring PAHs (45.8 %) followed by five-ring (26.8 %) and three-ring PAHs (12.7 %). The PAH source analysis suggested that the main origin of PAHs in the sediments of the lagoon was mainly from pyrolytic sources. According to the numerical effect-based sediment quality guidelines of the USA, the levels of PAHs in the Bizerte Lagoon should not exert adverse biological effects. The total benzo[a]pyrene toxicity equivalent values calculated for the samples varied from 3.1 to 53.7 ng g?1 dw with an average of 10.6 ng g?1 dw. 相似文献
225.
Yvan Capowiez Nils Dittbrenner Magali Rault Mickaël Hedde 《Environmental pollution (Barking, Essex : 1987)》2010,158(2):388-393
There is currently a lack of ecotoxicity tests adapted to earthworm species of higher ecological relevance and whose endpoints could be directly related to their ecological role in the soil. We propose a new and relatively simple ecotoxicity test based on the estimation of cast production (CP) by Lumbricus terrestris under laboratory conditions. CP was found to be linearly correlated to earthworm biomass and to be greatly influenced by soil water content. Azinphos-methyl had no effect on CP at all the concentrations tested. Significant decreases were observed at the normal application rate for other pesticides with (imidacloprid, carbaryl, methomyl) or without (ethyl-parathion and chlorpyrifos-ethyl) a clear concentration-effect response. For the highest concentration tested, reduction in CP varied between 35 and 67%. CP is straightforward and rapidly measured and ecologically meaningful. We thus believe it to be of great use as an endpoint in ecotoxicity testing. 相似文献
226.
Ground-living spiders were studied using modified pitfall traps during several years in four characteristic habitats in Giant Mountains (Krkono?e Mts.), the High Sudetes, Czech Republic: alpine tundra, subalpine mire, tall-herb stand at the bottom of a glacial corrie, and decaying mountain spruce forest. Ecological and zoogeographical aspects of spider communities were analysed. The spider communities of alpine tundra, subalpine mire, and glacial corrie exhibited long-term stability, whereas the community of decaying mountain forest changed during observations. Small linyphiid spiders, dominating in mature forest, were gradually replaced by larger Iycosid and gnaphosid species. Zoogeographic characterization of mountain habitats was made based on species exhibiting disjunctive area. In contrast to plants, for spiders of boreal origin alpine tundra is the most important habitat for survival, followed by screes, mires, spruce forests, and corries. 相似文献
227.
Daniel Gorman Touria Bajjouk Jacques Populus Mickaël Vasquez Axel Ehrhold 《Marine Biology》2013,160(2):309-325
We address the global deficit of data describing kelp forest distribution, relative covers and biomass by testing the ability of species distribution models to predict these attributes at locations where data are currently limited. We integrated biological ground truth data with high-resolution environmental datasets to develop generalized additive models that accurately predict the structure of Laminaria forests within the Bay of Morlaix (48°42′42″N, 3°55′40″W). Forest distribution and proportional covers were predicted using water depth, light availability, wave exposure and sediment dynamics. The biomass of individual kelp species was modeled by supplementing these same variables with measures of seafloor slope and benthic position. Biomass predictions for Laminaria digitata and Laminaria hyperborea contrast the physiological tolerances of these species to light and wave exposure gradients. As a direct management output, we produced high-resolution maps (25 m2 grids) that closely match independent field data and provide vital information for marine spatial planning. 相似文献
228.
Combining field and laboratory work, this study investigated the reproductive cycle, aggregative behavior, spawning periodicity,
development and early growth of the sea star Henricia lisa living at bathyal depths off eastern Canada. Marked differences were found between individuals from ~1,300 and ~600 m deep.
The former had a male biased sex ratio and an aperiodic reproductive cycle, whereas the latter displayed an equal sex ratio
and a biannual breeding pattern. Furthermore, the maximum size was larger and female fecundity roughly five times higher in
shallower compared to deeper populations. In the tanks, aggregative behavior was recorded twice a year during the summer and
winter breeding periods. The onset of aggregations and spawning coincided with a temperature of 3–4°C. Males spawned first
and females typically responded inside 30–60 min. Between 12 and 20 eggs were retained to be brooded under the arched arms
of the female, whereas the remainder were broadcasted and developed without parental care. The fertilized eggs underwent a
first cleavage after 12 h, reached the brachiolaria stage in 1 month, became juveniles within 3–4 months and reached ~ 4 mm
in diameter after 14–17 months of growth. The embryos and juveniles developed at the same rate whether brooded or not, and
development of winter cohorts was typically slower due to lower prevailing temperatures. This study of H. lisa provides the first evidence of lecithotrophy in a seasonally breeding deep-sea echinoderm and of brooding in a deep-sea asteroid. 相似文献
229.
This study examines the composition and activity of the planktonic community during the polar night in the high Arctic Kongsfjord,
Svalbard. Our results are the first published evidence of bioluminescence among zooplankton during the Arctic polar night.
The observations were collected by a bathyphotometer detecting bioluminescence, integrated into an autonomous underwater vehicle,
to determine the concentration and intensity of bioluminescent flashes as a function of time of day and depth. To further
understand community dynamics and composition, plankton nets were used to collect organisms passing through the bathyphotometer
along with traditional vertical net tows. Additionally, using a moored bathyphotometer closed to the sampling site, the bioluminescence
potential itself was shown not to have a diurnal or circadian rhythm. Rather, our results provide evidence for a diel vertical
migration of bioluminescent zooplankton that does not correspond to any externally detectable changes in illumination. 相似文献
230.
Pascal D. Leroy Ahmed Sabri Fran?ois J. Verheggen Fr��d��ric Francis Philippe Thonart Eric Haubruge 《Chemoecology》2011,21(3):113-122
In natural environment, semiochemicals are involved in many interactions between the different trophic levels involving insects,
plants and hosts for parasitoids or prey for predators. These volatile compounds act as messengers within or between insect
species, inducing particular behaviours, such as the localisation of a source of food, the orientation to an adequate oviposition
site, the selection of a suitable breeding site and the localisation of hosts or prey. In this sense, bacteria have been shown
to play an important role in the production of volatile compounds which ones act as semiochemicals. This review, focusing
on the semiochemically mediated interactions between bacteria and insects, highlights that bacterial semiochemicals act as
important messengers for insects. Indeed, in most of the studies reported here, insects respond to specific volatiles emitted
by specific bacteria hosted by the insect itself (gut, mouthparts, etc.) or present in the natural environment where the insect
evolves. Particularly, bacteria from the families Enterobacteriaceae, Pseudomonaceae and Bacillaceae are involved in many
interactions with insects. Because semiochemicals naturally produced by bacteria could be a very interesting option for pest
management, advances in this field are discussed in the context of biological control against insect pests. 相似文献