A Three-Dimensional, Integrated Seasonal Separate Advection–Diffusion Model (ISSADM) to Predict Water Quality Patterns in the Chahnimeh Reservoir

Seasonal rivers are the main sources of discharge for many lakes and reservoirs. These rivers can deliver pollutants into these water bodies, especially during large events. The fate and distribution of these pollutants within lakes is difficult to predict. Here, a three-dimensional, finite-volume model for predicting lake water quality is used to account for internal advection and diffusion, including the impacts of the inflowing rivers on the velocity field. We used parsimonious sub-models for the source/sink terms for temperature, dissolved oxygen, ammonia nitrogen, phosphorous, phytoplankton, and zooplankton concentrations and tested the model predictions against field measurements from the Chahnimeh Reservoir in Iran. The modeled water quality parameters were in good agreement with the measured values. Results were notably poorer when the three-dimensionality of the model was removed. This study suggests that properly simulating three-dimensional advection is important to properly predict the distribution of pollutants within some lakes and reservoirs and that this model may be directly applicable to systems similar to Chahnimeh Reservoir.     

Detection of SARS-CoV-2 in the indoor air of intensive care unit (ICU) for severe COVID-19 patients and its surroundings: considering the role of environmental conditions

Environmental Science and Pollution Research - There is ambiguity about the airborne transmission of the SARS-CoV-2. While a distance of 6 feet is considered a safe physical distance, new findings...     

Surfactant-mediated complex formation for determination of traces amounts of zinc, cadmium, and lead with 4-(2-thiazolylazo) resorcinol and chemometric methods

The partial least squares modeling is a powerful multivariate statistical tool applied to the spectrophotometric simultaneous determination of the divalent ions of zinc, cadmium, and lead based on the formation of their complexes with 4-(2-thiazolylazo) resorcinol in surfactant media. The linear concentration range for zinc, cadmium, and lead were 0.10-1.31, 0.148-1.92, and 0.148-3.70 mg L(?-1), respectively. The experimental calibration set was composed of 36 sample solutions using a mixture design for three component mixtures. The absorption spectra were recorded from 380 through 650 nm. The effect of pH on the sensitivity in determination of zinc, cadmium, and lead was studied in order to choose the optimum pH (pH = 8) for determination. The root-mean-square errors of predictions for zinc, cadmium, and lead were 0.0466, 0.0282, and 0.050, respectively. The proposed method was successfully applied for the determination of zinc, cadmium, and lead in water samples.     

Removal of hinosan from underground water using NH4Cl-modified activated carbon from rice husk

Environmental Science and Pollution Research - In the present study, NH4Cl-modified activated carbon was synthesized from rice husk and used as an adsorbent for removal of hinosan from underground...     

A new catalytic oxidation method for sensitive quantification of bromate in flours and bottled water using AgNPs

In this paper, a simple and sensitive spectrophotometric method for the determination of nanomolar level of bromate, based on the catalytic effect of silver nanoparticles on the oxidation of acid red 14 by potassium bromate, is described. The reaction rate was monitored spectrophotometrically by measuring the decrease in absorbance of acid red 14 at 516 nm. The detection limit of the method was 8 ng/mL, and the linear range was between 15 and 130 ng/mL. The effects of acidity, concentration of reactants and reaction time, and external ions were also discussed. The optimum reaction conditions were fixed, and some kinetic parameters determined. The relative standard deviation for the determination of bromate at the concentration of 50 ng/mL was calculated to be 0.996 % (n?=?10). The method has been successfully applied to the determination of bromate in flours and bottled waters.     

Adsorption and photocatalytic properties of porphyrin loaded MIL-101 (Cr) in methylene blue degradation

Environmental Science and Pollution Research - In this study for the very first time, zinc tetraphenylporphyrin (ZnTPP) was loaded into MIL-101 (Zn[TPP]@MIL-101) to perform an adsorptive and...