Radiation Effects on Blends of Poly(ε-Caprolactone) and Diatomites

Poly(-caprolactone) (PCL) was blended with diatomaceous earth (diatomite) and irradiated with -rays to introduce cross-linking between PCL molecules or both components. The unwashed diatomite containing a little of a volatile component showed high efficiency of introduction of cross-linking, whereas that with no volatile component showed low efficiency of introduction of cross-linking. Elongational viscosity, melt viscosity, and modulus of PCL/diatomite blend irradiated at various doses were significantly improved. Enzymatic degradation of the PCL/diatomite blend became faster than that of the PCL, though that of the blend irradiated became slower.     

Recovery of gold by chicken egg shell membrane-conjugated chitosan beads

We have successfully prepared a bead-type adsorbent from two materials with different adsorption characteristics. Heavy metals were removed by greatly swollen egg shell membrane-conjugated chitosan beads. The egg shell membrane accumulated and removed precious metal ions from a dilute aqueous solution with a high affinity in a short contact time. Experiments suggested that chitosan beads could take up gold ions with great capacity and selectivity by conjugation with egg shell membrane. Under certain conditions, the selective removal of gold and copper in a mixture of gold and copper ions by egg shell membrane-conjugated chitosan beads was 100% and 2%, respectively. Egg shell membrane-conjugated chitosan beads can be seen as a promising material to recover gold in wastewater from various industries, such as electroplating.     

渚滑川河口拦门沙演变特性

河口拦门沙的存在可导致径流流出不畅，并能引起一系列的河口生态及环境问题。特别是弯曲型河口，在波浪流、河川径流及弯道副流的共同作用下，拦门沙的形成及演变将更为复杂。通过对日本渚滑川河口多次实地调查资料的分析，揭示了渚滑川河口拦门沙的演变特性。结果表明：渚滑川河口修筑防波堤后，在东北方向的海洋入射波作用下，拦门沙由河口右岸发育并向左岸逐渐延伸扩展，其河水流动也相应由右岸偏向左岸一侧；不论河口有无拦门沙，3次洪水在右岸的最大冲深均稳定在-6m高程，且河床横剖面的形状基本不变，即汛期时该河口河床形状已达平衡状态。     

Immobilization of tritiated water by hydrothermal hot-pressing

Tritium is generally disposed of as an oxide form, and immobilization of tritium oxide with Portland cement is the most popular disposal method. However, the cement solidified body is rather leachable for tritium and is poor in some physical properties. A silicate powder, such as borosilicate glass powder, forms a synthetic rock by the hydrothermal hot-pressing (HHP) technique, making it a technique for immobilization of tritium oxide. Tritium oxide with borosilicate glass powder was solidified by the HHP technique. Leachability of tritium from the produced solidified bodies and the behavior of fixed tritium oxide during the heating were studied and discussed. The amount of tritium oxide fixed by the present procedure was almost the same as that fixed by the ordinary cement solidifying procedure. The diffusivity of tritium from the body by this procedure was much lower than that from the cement body and the compressive strength of the body was higher than that of the cement body.