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CMK-3 and C-FDU-15 samples were synthesized using hard-templating and evaporationinduced self-assembly(EISA) methods,respectively.The pore structures of CMK-3 and CFDU-15 as well as commercial activated carbon were characterized by means of X-ray diffraction,field emission scanning electron microscopy,transmission electron microscopy,and N_2 adsorption–desorption.Adsorption of NO was investigated by means of thermogravimetric analysis,temperature-programmed desorption of NO + O_2,and in situ diffuse reflectance Fourier transform infrared spectroscopy.The results show that the CMK-3 and C-FDU-15 materials possessed ordered and uniform structures.The coadsorption capacity of NO and O_2 decreased in the sequence CMK-3(88.6 mg/g) C-FDU-15(71.7 mg/g) AC(25.3 mg/g).There were two main adsorption species on CMK-3 and CFDU-15:nitrite and nitrate.Nitrite is converted to nitrate easily.However,the adsorption species were more complex on AC,with nitrite being the main species.Moreover,CMK-3 and C-FDU-15 exhibit excellent regeneration efficiency compared with AC.The excellent NO adsorption performance of CMK-3 and C-FDU-15 was associated with their ordered mesoporous structures and high surface areas.The research provides more options for NO adsorption in the future. 相似文献
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洛阳分公司恶臭污染调查及防治 总被引:2,自引:0,他引:2
程俊梅 《石油化工环境保护》2005,28(1):31-33,i002
分析了洛阳分公司恶臭污染源,提出了解决恶臭污染的常用方法及对洛阳分公司恶臭污染源的控制及治理途径。 相似文献
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利用pH值梯度研究建筑砂浆的酸蚀程度 总被引:1,自引:0,他引:1
在两种不同pH值模拟酸雨和3种浸泡时间条件下,据pH值梯度测定了各类保护剂处理建筑砂浆试件的酸化层厚度,从而判定保护剂的保护效果,了解酸蚀程度。并分析了影响酸化层厚度的因素。 相似文献
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Andreas Züttel 《Mitigation and Adaptation Strategies for Global Change》2007,12(3):343-365
Hydrogen storage and transportation or distribution is closely linked together. Hydrogen can be distributed continuously in
pipelines or batch wise by ships, trucks, railway or airplanes. All batch transportation requires a storage system but also
pipelines can be used as pressure storage system. Hydrogen exhibits the highest heating value per weight of all chemical fuels.
Furthermore, hydrogen is regenerative and environment friendly. There are two reasons why hydrogen is not the major fuel of
toady’s energy consumption: First of all, hydrogen is just an energy carrier. And, although it is the most abundant element
in the universe, it has to be produced, since on earth it only occurs in the form of water. This implies that we have to pay
for this energy, which results in a difficult economic task, because since the industrialization we are used to consuming
energy for free. The second difficulty with hydrogen as an energy carrier is the low critical temperature of 33 K, i.e. hydrogen
is a gas at room temperature. For mobile and in many cases also for stationary applications the volumetric and gravimetric
density of hydrogen in a storage system is crucial. Hydrogen can be stored by six different methods and phenomena: high pressure
gas cylinders (up to 800 bar), liquid hydrogen in cryogenic tanks (at 21 K), adsorbed hydrogen on materials with a large specific
surface area (at T < 100 K), absorbed on interstitial sites in a host metal (at ambient pressure and temperature), chemically bond in covalent
and ionic compounds (at ambient pressure), oxidation of reactive metals e.g. Li, Na, Mg, Al, Zn with water. These metals easily
react with water to the corresponding hydroxide and liberate the hydrogen from the water. Finally, the metal hydroxides can
be thermally reduced to the metals in a solar furnace. 相似文献
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