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161.
An empirical approach for the decomposition and reconstruction of long-term flowering records of eight eucalypt species is presented. Results from singular spectrum analysis (SSA) allow for characterisation of the dynamic and complex flowering patterns in response to temperature and rainfall throughout the year. SSA identified trend, annual, biennial and other sub-components of flowering. The ability to discriminate flowering and climate relationships is demonstrated based on SSA (cross-)correlation analysis. SSA also identified the cyclical influence of temperature and rainfall on peak flowering. For each species, there is, on average, 6 months of the annual cycle when temperature positively influences flowering and 6 months when the influence of temperature is negative. For all species, rainfall exerts a negative influence when temperature is positive. Investigation of short-term and long-term lags of climate on flowering provided best-case climatic scenarios for each species’ flowering; e.g. more intense peak flowering is likely in Eucalyptus leucoxylon when cool, wet conditions coincide with peak flowering and is further enhanced if the preceding autumn and winter were warm and dry, and the previous spring and summer cool and wet. Three clear species groupings, according to similar SSA (cross-)correlation signatures, were identified: (1) E. leucoxylon and E. tricarpa; (2) E. camaldulensis, E. melliodora and E. polyanthemos and (3) E. goniocalyx, E. microcarpa and E. macrorhyncha. Lastly, change point years for flowering based on SSA sub-components in four of the species seem to align with years of major shift in global ENSO signal (1951/1957/1958) as indicated by the extended multivariate ENSO index. 相似文献
162.
163.
Levels of α-, β-, and γ-hexabromocyclododecane (HBCD) were determined in pooled eggs from herring gulls (Larus argentatus) sampled on three bird sanctuaries near the German North Sea coast between 1988 and 2008 (Mellum and Trischen) and the German Baltic Sea coast between 1998 and 2008 (Heuwiese) and archived by the German Environmental Specimen Bank. Pressurized fluid extraction, gel permeation chromatography, and LC-MS/MS using 13C12-labelled isotope standards and a chiral column were applied. α-HBCD was the dominating diastereomer and ranged between 3.7 and 107 ng g−1 lw while β- and γ-HBCD were throughout close to LOQ. The highest α-HBCD concentration was found in eggs from Mellum sampled in the year 2000. Interestingly, HBCD in eggs from the three islands displayed similar time courses with levels increasing to a peak contamination around 2000 and decreasing levels ever since. Chiral signatures of α-HBCD in eggs differed among the islands but indicated a preferential enrichment of the first eluting enantiomer (−)-α-HBCD. 相似文献
164.
The natural methane oxidation potential of methanotrophic bacteria in landfill top covers is a sustainable and inexpensive method to reduce methane emissions to the atmosphere. Basically, the activity of methanotrophic bacteria is limited by the availability of oxygen in the soil. A column study was carried out to determine whether and to what extent vegetation can improve soil aeration and maintain the methane oxidation process. Tested soils were clayey silt and mature compost. The first soil is critical in light of surface crusting due to vertical erosion of an integral part of fine-grained material, blocking pores required for the gas exchange. The second soil, mature compost, is known for its good methane oxidation characteristics, due to high air-filled porosity, favorable water retention capacity and high nutrient supply. The assortment of plants consisted of a grass mixture, Canadian goldenrod and a mixture of leguminous plants. The compost offered an excellent methane oxidation potential of 100% up to a CH4-input of 5.6 l CH4 m−2 h−1. Whereas the oxidation potential was strongly diminished in the bare control column filled with clayey silt even at low CH4-loads. By contrast the planted clayey silt showed an increased methane oxidation potential compared to the bare column. The spreading root system forms secondary macro-pores, and hence amplifies the air diffusivity and sustain the oxygen supply to the methanotrophic bacteria. Water is produced during methane oxidation, causing leachate. Vegetation reduces the leachate by evapotranspiration. Furthermore, leguminous plants support the enrichment of soil with nitrogen compounds and thus improving the methane oxidation process. In conclusion, vegetation is relevant for the increase of oxygen diffusion into the soil and subsequently enhances effective methane oxidation in landfill cover soils. 相似文献
165.
AbstractObjective: Systems that can warn the driver of a possible collision with a vulnerable road user (VRU) have significant safety benefits. However, incorrect warning times can have adverse effects on the driver. If the warning is too late, drivers might not be able to react; if the warning is too early, drivers can become annoyed and might turn off the system. Currently, there are no methods to determine the right timing for a warning to achieve high effectiveness and acceptance by the driver. This study aims to validate a driver model as the basis for selecting appropriate warning times. The timing of the forward collision warnings (FCWs) selected for the current study was based on the comfort boundary (CB) model developed during a previous project, which describes the moment a driver would brake. Drivers’ acceptance toward these warnings was analyzed. The present study was conducted as part of the European research project PROSPECT (“Proactive Safety for Pedestrians and Cyclists”).Methods: Two warnings were selected: One inside the CB and one outside the CB. The scenario tested was a cyclist crossing scenario with time to arrival (TTA) of 4?s (it takes the cyclist 4?s to reach the intersection). The timing of the warning inside the CB was at a time to collision (TTC) of 2.6?s (asymptotic value of the model at TTA = 4?s) and the warning outside the CB was at TTC = 1.7?s (below the lower 95% value at TTA = 4?s). Thirty-one participants took part in the test track study (between-subjects design where warning time was the independent variable). Participants were informed that they could brake any moment after the warning was issued. After the experiment, participants completed an acceptance survey.Results: Participants reacted faster to the warning outside the CB compared to the warning inside the CB. This confirms that the CB model represents the criticality felt by the driver. Participants also rated the warning inside the CB as more disturbing, and they had a higher acceptance of the system with the warning outside the CB. The above results confirm the possibility of developing wellsaccepted warnings based on driver models.Conclusions: Similar to other studies’ results, drivers prefer warning times that compare with their driving behavior. It is important to consider that the study tested only one scenario. In addition, in this study, participants were aware of the appearance of the cyclist and the warning. A further investigation should be conducted to determine the acceptance of distracted drivers. 相似文献
166.
AbstractObjective: Impact speed is one of the most important factors explaining the severity of injuries to cyclists when they collide with passenger cars. To reduce injury severity (especially for vulnerable road users), since 2008, Swedish municipalities have the authority to lower the speed limit to 30 or 40?km/h in urban areas as appropriate. The aim of this study was to evaluate how this speed limit reduction has influenced the injury severity for cyclists in this type of collision.Method: Data from 1,953 collisions between bicycles and passenger cars were collected using information from third-party-liability insurance claims from 2005 to 2017. The change of speed limit distribution, influenced by the reduction of speed limits in urban areas, where car-to-cyclist collisions occurred was studied. Following that, injury severity for cyclists was evaluated regarding collisions occurring in areas with different speed limits.Results: The results show that, in collisions with cars, cyclists have a significantly lower risk of a moderate-to-fatal (MAIS 2+) injury when the speed limit is 30–40?km/h compared to 50–60?km/h. During the last decade, while the speed-limit has been lowered on many road-sections in urban areas from 50–60?km/h to 30–40?km/h the risk of a cyclist getting a MAIS 2+ injury decreased by 25%. In 2005 to 2011, 16% of the crashes happened on a road with a speed limit of 30–40?km/h; in 2016–2017, this percentage had increased to approximately 50%. Thus, in recent years more crashes occurred on roads with lower speed limits, and in these crashes, there was a lower risk of severe injuries to cyclists. Unfortunately, it was not possible to evaluate the risk of a crash for specific speed limits; since one limitation of this study was the lack of exposure data, nor do we know the impact speed or the actual speed of the vehicles.Conclusions: This study is an important follow-up on the implementation of measures that can influence bicycle safety. The insurance data used, made it possible to quantify a positive effect on injury severity for cyclists in passenger car-to-cyclist collisions when the speed limit was reduced in urban areas. Insurance claims cover collisions of all crash severity, so they include data covering all types of injuries—not just the most severe/fatal ones. This aspect is especially important in the speed intervals evaluated here, since moderate (MAIS 2) injuries are very frequent in lower-speed crashes and even these injuries can result in long-term consequences. 相似文献
167.
168.
The prenatal diagnosis of thrombocytopenia absent radius syndrome in both dizygotic twins utilizing ultrasound, radiography and fetoscopy is described. 相似文献
169.
The toxic combination effects of xenobiotics of different substance classes were investigated in human fibroblasts. Subtoxic concentrations of 4-chloroaniline enhanced the toxicity of 2,4-dichlorophenoxyacetic acid (2,4-D, dimethylammonium salt) in an additive manner. A mixture of 4-chloroaniline, dicofol and 4-chlorophenol increased the toxicity of 2,4-D synergistically. The concentrations of the components used in the mixture were one third of their ?no observed effect concentrations” (NOEC). The combination of 4-chloroaniline, dicofol and 4-chlorophenol (without 2,4-D) at subtoxic concentrations also showed synergistic effects. The great differences in the lipophilicity of the combined substances might be the cause of the synergistic action. 相似文献
170.
Papadopoulos A Vassiliadou I Costopoulou D Papanicolaou C Leondiadis L 《Chemosphere》2004,57(5):413-419
Food intake is the main source of exposure to dioxin-like compounds for humans. The results of a surveillance programme on polychlorinated dibenzo-p-dioxins (PCDDs), dibenzofurans (PCDFs) and co-planar polychlorinated biphenyls (co-PCBs) in 77 food samples from the Greek market and producers are presented. The study included the analyses of milk and dairy products, meat and meat products, fish, vegetable oil, eggs, fruit, vegetable and rice collected between August and December 2002. After extraction, extracts were cleaned up on a series of carbon column chromatography, silica gel, alumina chromatography, and then analysed by high resolution gas chromatography/high resolution mass spectrometry. All samples had a dioxin content far below the EC Regulation (2375/2001/EC) limits. 相似文献