环境自动监测站固定式辐射监测仪性能测试与评价

参考计量技术规范《固定式环境γ辐射空气比释动能(率)仪现场校准规范》(JJF 1733—2018),对辐射环境空气自动监测站78台高气压电离室开展辐射特性测试。现场校准方面,仅88%的电离室满足1±0.2的响应范围要求;78台电离室的重复性均不超过1%,响应的非线性均不超过6.5%,符合规范要求。针对电离室开展辐射性能测试,发现电离室在9.0×10^-2~1.0×10⁹ μGy/h范围内的响应均不超过1±0.2;电离室对164 keV以上的光子的能量响应趋于1.0,对60 keV以下的光子无响应能力,而当光子能量在60~164 keV范围内时,响应曲线会因γ光子与电离室内部惰性气体的光电效应出现"鼓包";电离室不具备对核临界事故脉冲辐射的监测与警示能力;电离室能够在2 s内给出测量范围内的准确示值,但在分段电压的交界处,响应时间会延长至180~360 s;电离室的响应受环境温度、湿度变化的影响大小不足±0.01,表明电离室的环境适应性优良。     

微米零价铁去除磷酸盐效果与机理研究

为探究微米零价铁除磷效果与机理,首先考察了水化学条件对微米零价铁除磷效果的影响;其次研究了微米零价铁对磷的去除效果以及酸盐磷在磁性固体和悬浮固体中的动态分配情况,并通过监测不同浓度反应体系中理化参数(pH、DO、ORP)的变化,进一步分析了体系中的反应过程;最后通过扫描电子显微镜(SEM)、X射线衍射(XRD)和X射线光电子能谱(XPS)等表征手段对反应产物进行了分析。结果表明:较低pH能显著提高微米零价铁的反应活性,加快磷的去除;离子强度的增加可加快反应速率; AsO 4 3 -和 SiO 3 2 -对微米零价铁除磷具有明显的抑制作用, SO 4 2 -影响很小,而 NO 3 -和 CO 3 2 -有一定的促进作用。被去除的磷酸盐在反应产物磁性固体和悬浮固体中的浓度接近。SEM分析表明,有磷条件与无磷条件下反应产物固体表面形貌具有明显区别。XPS分析表明,微米零价铁除磷过程中主要生成了Fe2+铁和Fe3+。1,10-菲啰啉掩蔽试验结果表明,磷酸盐与Fe2+结合是微米零价铁除磷的主要途径。XRD分析发现生成了H2FeP2O7,说明微米零价铁除磷存在沉淀作用。     

新型无机复合混凝剂的制备及脱色效果研究

了以铝厂赤泥为原料制备无机复合凝凝剂的工艺,以制备过程中酸溶尼所用的盐酸浓度、酸溶时间和聚合ＰＨ等进行了优化。直接耐酸大红溶液和分散黄溶液的脱色以试验结果表明,此种混凝剂的脱色效果优于聚合氯化铝和聚合硫酸铁。     

斜井送排式通风隧道的火灾救援通风研究

公路隧道发生火灾开启横通道后,形成通风网络。本文以重庆地区吕家梁隧道为工程依托,进行了斜井前后不同位置发生火灾的通风网络模拟。结果表明,斜井前发生火灾时,受斜井浮力效应、风流密度变化等的影响,主风机的工作压力降低,而体积流量增加;当火灾发生在斜井前隧道时,采用斜井单抽方式可实现全部火灾烟流从竖井中排除,斜井前设射流风机增压调节、斜井后设射流风机增阻调节是一较好方案;对于斜井后发生火灾,采用全射流火灾通风和斜井压入两种通风方案均能满足火灾风流控制要求,虽然后者需要开启轴流风机,通风能耗大,但火灾通风的时效性要好于前者。     

铁循环微生物对环境中重金属的影响研究进展

铁循环微生物包括铁氧化菌(Fe(Ⅱ)-oxidizing bacteria,FeOB)和铁还原菌(Fe(Ⅲ)-reducing bacteria,FeRB),在由它们介导Fe2+(Fe3+)氧化(还原)的过程中,往往也伴随着一系列重金属元素的迁移转化,对重金属在环境中的生物有效性和迁移性方面有重要作用.本文综述了环境中...     

Enhanced hydrogen production in microbial electrolysis through strategies of carbon recovery from alkaline/thermal treated sludge

• High hydrogen yield is recovered from thermal-alkaline pretreated sludge. • Separating SFL by centrifugation is better than filtration for hydrogen recovery. • The cascaded bioconversion of complex substrates in MECs are studied. • Energy and electron efficiency related to substrate conversion are evaluated. The aim of this study was to investigate the biohydrogen production from thermal (T), alkaline (A) or thermal-alkaline (TA) pretreated sludge fermentation liquid (SFL) in a microbial electrolysis cells (MECs) without buffer addition. Highest hydrogen yield of 36.87±4.36 mgH₂/gVSS (0.026 m³/kg COD) was achieved in TA pretreated SFL separated by centrifugation, which was 5.12, 2.35 and 43.25 times higher than that of individual alkaline, thermal pretreatment and raw sludge, respectively. Separating SFL from sludge by centrifugation eliminated the negative effects of particulate matters, was more conducive for hydrogen production than filtration. The accumulated short chain fatty acid (SCFAs) after pretreatments were the main substrates for MEC hydrogen production. The maximum utilization ratio of acetic acid, propionic acid and n-butyric acid was 93.69%, 90.72% and 91.85%, respectively. These results revealed that pretreated WAS was highly efficient to stimulate the accumulation of SCFAs. And the characteristics and cascade bioconversion of complex substrates were the main factor that determined the energy efficiency and hydrogen conversion rate of MECs.     

人工草坪昆虫多样性与环境因子的相关性初步研究——以庐山风景区为例

昆虫在自然界中占据着多样性更高、空间尺度更小的生境,对生境的变化也更敏感,开展昆虫多样性与环境因子的相关性研究对生态环境监测和保护具有重要意义。实验中我们选用庐山风景区不同人工草坪进行研究,对它们昆虫群落及环境因子特征进行了随机取样调查,采用多样性指数和典范对应分析（CCA）研究昆虫群落与环境因子之间的相关性。实验共收集了昆虫11目,472头,以直翅目和鳞翅目占优势,其个体数分别占捕获昆虫总个体数的5324%和2278%。CCA分析表明：昆虫与环境因子之间的相关性高达100%,提示环境因子变化影响昆虫的分布,从研究结果看,践踏强度、样地大小、植被类型都对昆虫群落的分布影响很大。为该区域昆虫资源的保护和利用以及人工草坪的设置等相关研究提供科学依据     

Plot-scale spatiotemporal variations of CO2 concentration and flux across water–air interfaces at aquaculture shrimp ponds in a subtropical estuary

Human activities have increased anthropogenic CO₂ emissions, which are believed to play important roles in global warming. The spatiotemporal variations of CO₂ concentration and flux at fine spatial scales in aquaculture ponds remain unclear, particularly in China, the country with the largest aquaculture. In this study, the plot-scale spatiotemporal variations of water CO₂ concentration and flux, both within and among ponds, were researched in shrimp ponds in Shanyutan Wetland, Min River Estuary, Southeast China. The average water CO₂ concentration and flux across the water–air interface in the shrimp ponds over the shrimp farming period varied from 22.79?±?0.54 to 186.66?±?8.71 μmol L^?1 and from ??0.50?±?0.04 to 2.87?±?0.78 mol m^?2 day^?1, respectively. There was no remarkable difference in CO₂ concentration and flux within the ponds, but significantly spatiotemporal differences in CO₂ flux were observed between shrimp ponds. Chlorophyll a, pH, salinity, air temperature, and morphometry were the important factors driving the spatiotemporal patterns of CO₂ flux in the shrimp ponds. Our findings highlighted the importance and spatiotemporal variations of CO₂ flux in the important coastal ecosystems.

     

水库泥沙淤积量测算方法研究综述及展望

我国江河大多泥沙量大，所建水库淤积严重，由此带来了一系列的问题。因此，及时、准确地确定其淤积量及淤积位置对工程措施的实施非常重要。首先，介绍了水库淤积量的测量方法，包括经纬仪测记法、SAR法、GPS＋测深仪法；然后，针对淤积量的计算方法进行了详尽的述评，如：等深线、规则网格镶嵌法、断面或地形法、基于GIS的DTM法、泰森多边形法及基于库容曲线的泥沙淤积量计算法、输沙量平衡法和水力模型法等；最后，对水深测量误差的控制及淤积体体积计算的改进进行了探讨和展望，指出了需要进一步研究和解决的问题。     

模糊综合评价在焦化废水处理技术中的应用

采集某焦化厂废水处理系统的数据,选取当前常用的3种焦化废水处理技术和该焦化厂现用废水处理技术建立了较为完整的模糊综合评价数学模型,选择技术综合评价的评价因素集,利用判断矩阵分析法确定各评价因素的权重,建立了各定量因素指标的隶属函数,确定了各定性因素指标的模糊评语集,最后以模糊矩阵的合成运算完成模糊综合评价.4种焦化废水处理技术的综合性能优劣次序为:该焦化厂现用废水处理技术>普通活性污泥法>湿式催化氧化法>多相光催化氧化法.