Matrix-bound phosphine and phosphorus fractions in paddy soils

Phosphine (PH(3)) is a natural gaseous carrier of phosphorus (P) in its geochemical cycles, and it might be important to the P balance of natural ecosystems. Paddy fields are thought to be one of the main sources responsible for the production and emission of PH(3) in to the environment. The relationships between matrix-bound PH(3) (MBP) and different P fractions, as well as selected metals were investigated to explore the possible production of MBP and its link to P cycle in the paddy soils. MBP range from 20.8 (-1) to 502 ng kg(-1) with an average of 145 ng kg(-1). Concentrations at the milk stage are significantly higher than at the jointing stage. The total P range from 333 mg kg(-1) to 592 mg kg(-1). Average P fractions decrease in the order: Ca-P (69.9%) > Organic P (16.5%) > occluded P (6.50%) > Fe-P (5.93%) > dissolved P (0.80%) > exchangeable P (0.32%) > Al-P (0.02%). Different levels of nitrogen fertilizer have little effect on the contents of MBP, P fractions and metals. A significant positive correlation between MBP and Ca-P (p = 0.002), as well as between MBP and Ca (p = 0.008) could be observed, suggesting that Ca-P mainly affects the production of MBP in the paddy soils. It is suggested that soil MBP is strongly linked to Ca-P fertilizer use because soil spiked with P-fertilizer produced an additional 758 ± 142 ng of MBP per kg of soil, compared to only 81.7 ± 12.3 ng of MBP per kg of unspiked soil. No correlations are found between MBP and other P fractions, or between MBP and Al, Fe and Mn.     

重金属对土壤—植物系统中氮的转化与NO3-淋失影响的研究

本项研究采用“微宇宙”方法,在实验室植物生长箱可控条件下,进行动态模拟实验。实验选择了七种重金属,按照土壤阳离子代换量计算出三种不同等级的土壤重金属剂量,研究它们对京津渤地区典型土壤(碳酸盐草甸土)中氮的转化与NO_3~-淋失影响。实验结果表明:七种重金属对该类土壤中氮的转化与NO_3~-淋失量有明显影响,但其表现的程度和特征有很大差异。其作用强度的次序为:Hg~(2 )>>Cd~(2 )>>Ni~(2 )>>Zn~(2 )>Pb~(2 )>Cu~(2 )>Cr~(3 )。各重金属作用的持续时间不同:Hg~(2 )、Cd~(2 )达7—11周以上,而其余重金属在4—7周。实验结论:本地区碳酸盐土壤虽然对重金属有较大的容量,但从土壤—植物系统污染生态学角度,仍可选择NO_3~-作为一项反映重金属对土壤生态毒性的早期诊断指标。     

最佳管理措施在非点源污染防治中的应用

综述了最佳管理措施（ＢＭＰｓ）在非点源污染控制中的应用现状，工程性措施有人工湿地、植被过滤带与缓冲带、蓄水池与沉淀塘等，非工程性措施有免耕－少耕法、化肥农药合理使用、生物废弃物再利用、地下水位控制、灌溉水生态化等，以及它们所取得的成果，并展望其发展趋势及前景。     

煤矸石制非烧结砖的可行性研究

从实验室试验和工业性试验出发， 煤矸石制非烧结砖的可行性。研究结果表明，用煤矸石和适量固化剂制成的非绕结砖经过２８ｄ自然养护后，其质量和放射性均符合国家有关标准。利用煤矸石非烧砖无 技术上还是经济上都是可行和有利的。     

陕西铜厂矿田控矿断裂带显微构造特征

本文在研究铜厂矿田地质特征和宏观断裂构造带特征的基础上 ,对矿田内不同类型断裂构造岩进行了分类和显微结构面力学性质的鉴定 ,研究了岩石和矿物的形变与相变 ,探讨了微观领域内的动力成岩成矿作用 ,并分别估算和厘定了古应力的大小和方向 ,为再现矿田构造应力场奠定了基础。     

旅游资源的环境保护对策

随着旅游和假日经济的日益升温，旅游资源的环境保护就显得更为迫切。本文基于旅游业的可持续发展要求，提出了有效保护旅游资源环境的几点对策     

复合污染状态下尾矿区有害化学品的迁移研究

用混合尾矿浆及尾矿渣淋溶柱,研究选矿药剂在尾矿渣及尾矿废水中的静态分布及其淋溶作用,结果表明:①选矿药剂对整个尾矿区都污染,即使是水溶性好的药剂,它们在尾矿渣中的静态分布也占有相当的比例,油溶性好的药剂多存在于尾矿渣中,尾矿污染为多种药剂的复合污染,各种药剂在尾矿渣及尾矿废水中的总浓度成倍加大;②用尾矿渣淋溶柱测得单一药剂的淋溶值:25号黑药>MIBC> CN->二号油>乙基黄药>丁基黄药>Y-89黄药.但多种药剂复合污染时,药剂的淋溶距离明显加大,其中CN-和Y-89黄药加大近一倍.复合药剂污染加大药剂的残留期,也加大它们向地下水及其它水源迁移的几率.     

基层环境执法中环境行政强制问题的探讨

环境行政强制包括环境行政强制措施和环境行政强制执行.在基层环境执法实践中,环境行政强制措施尤其是环境行政强制执行存在许多困惑和问题,拓展环境行政强制措施,给予环保部门一定的行政强制执行权是提高基层环境执法效率和遏制环境污染的有效途径.     

我国城市地下空间开发研究初论

城市地下空间是城市空间资源的重要组成部分,在提高土地利用效率、缓解城市矛盾、节约能源、保护环境等方面起着举足轻重的作用,其开发利用与规划工作已被国家列入城市规划的重要内容。回顾国内地下空间开发方面的研究,可以概括为解决了开发情况介绍、开发效益分析、内部环境研究、利用规划管理4类,只要我们解决了研究存在的一些问题,就可更好推动我国地下空间建设健康协调发展。     

Characterizing Drought in Irrigated Agricultural Systems: The Surface Water Delivery Index (SWDI)

Quantifying surface water shortages in arid and semiarid agricultural regions is challenging because limited water supplies are distributed over long distances based on complex water management systems constrained by legal, economic, and social frameworks that evolve with time. In such regions, the water supply is often derived in a climate dramatically different from where the water is diverted to meet agricultural demand. The existing drought indices which rely on local climate do not portray the complexities of the economic and legal constraints on water delivery. Nor do these indices quantify the shortages that occur in drought. Therefore, this research proposes a methodological approach to define surface water shortages in irrigated agricultural systems using a newly developed index termed the Surface Water Delivery Index (SWDI). The SWDI can be used to uniformly quantify surface water deficits/shortages at the end of the irrigation season. Results from the SWDI clearly illustrate how water shortages in droughts identified by the existing indices (e.g., SPI and PDSI) vary strongly both within and between basins. Some surface water entities are much more prone to water shortages than other entities based both on their source of water supply and water right portfolios.