咪唑类[PF6]^-型离子液体萃取胺类化合物

以眯唑类[PF6]^-型离子液体1-丁基-3-甲基咪唑六氟磷酸盐（[Bmim][PF6]）、1-己基-3-甲基咪唑六氟磷酸盐（[Hmim][PF6]）和1-辛基-3-甲基咪唑六氟磷酸盐（[Omim][PF6]）对苯胺、对氯苯胺等7种胺类化合物的萃取,考察了溶液初始浓度、相比、盐类、pH及离子液体眯唑基团上取代烷基对萃取平衡的影响,并研究了萃取过程的热效应。实验结果表明：溶液初始浓度对分配系数影响较小;相比10：1是离子液体对胺类化合物的溶解饱和临界点,当相比大于10：1时,分配系数降低;NaCl、K2SO4可以增大萃取分配系数,ZnSO4对分配系数几乎没有影响;pH增加,分配系数增大;离子液体对不同取代基的胺类萃取能力有较大的差异,咪唑基团上取代烷基的长度对不同胺类物质的分配系数影响较显著;萃取过程属于焓增大的吸热过程。     

An eco-environmental water demand based model for optimising water resources using hybrid genetic simulated annealing algorithms. Part II. Model application and results

The present optimisation model described in Part I of this work is applied to optimise water resources in the Haihe river basin, an important basin in north China that covers 31.82 million km². Results show that this optimisation model with the HGSAA solution is feasible and effective in the long-term optimisation of water resource use. It is shown that the combined forecasting method can improve the forecast precision. The results obtained indicate that the mean relative errors of BP and polynomial models are 2.3% and 4.9%, respectively, while that of the combined forecasting method is 1.93% in a case study on the Tumahe River for 2010. The combined forecasting method performs better because it incorporates various forecasting methods. The optimisation results show that both domestic and eco-environmental water demands can satisfy the requirements of the forecasting procedure, and the harmonious indices all exceeded 0.7. The Luanhe River is the most water-scarce sub-basin in the Haihe river basin.     

畜牧业污水中大环内酯和拟除虫菊酯类驱虫剂物质的LCMSMS检测

采用无需衍生化的同相萃取为前处理手段,高效液相色谱-串联四极杆质谱联用技术(LCMSMS)为检测手段,在电喷雾电离正离子模式下,对澳大利亚畜牧业污水中常见的大环内酯和拟除虫菊酯两类共7种驱虫剂物质的残留,建立了一次进样下的有效快速分析方法.经一系列优化试验,确定了以50%丙酮+50%乙腈为洗提剂、每次4 mL共8 mL的洗提方法.结果表明,该固相萃取技术(SPE)的加标回收试验结果较好,各化合物的平均回收率为95.50%～108.00%,相对标准差范围为0.73%-8.82%.以含10mmoL/L醋酸铵、0.1%甲酸的超纯水和甲醇混合溶液为流动相,以准分子离子峰[M+NH_4]~+、[M+H]~+作为母离子的定量离子对,所建立的1～500 ng/mL范围内的8点校正曲线中.各物质的相关系数均高于0.998 0,定量限范围为0.03-2.47 ng/mL.实际样品测定时.不同处理流程中各化合物的残留浓度有较好地体现.     

SPME/HPLC 对水中多环芳烃的定量分析

应用ＳＰＭＥ／ＨＰＬＣ,通过对水中５种多环芳烃的确定,得到了吸附量／吸附时间和解吸量／解吸时间的关系,并在吸附时间和解吸时间一定的条件下,测定了５种多环芳烃的响应值与浓度的线性关系,重现性及加标回收率（７６％－１１１％）。     

含溴氨酸体系中菌株NAX的生长及其吸附特性

从污染土壤筛选到的菌株NAX能在含溴氨酸的体系中生长,并能吸附溴氨酸。随碳源浓度的增加,菌体生长旺盛。体系中高浓度的溴氨酸和盐度抑制菌株生长。菌株对溴氨酸的吸附等温线数据用改型的Pearl生长模型拟合比用Freundlich方程好。这意味菌株吸附溴氨酸存在多层吸附机理。     

Snow-cover environmental monitoring and assessment in Northeast China using passive microwave emission models

In this study, we present the application of the passive microwave emission models to snow-cover environment monitoring and assessment in Northeast China. The study employs the radiative transfer function and strong fluctuation theory to develop the models. We used the exponential form of a spherical symmetric correlation function to describe random permittivity fluctuations. From strong fluctuation, we then obtained the phase matrix and extinction coefficients of snow-packs for the spherical symmetric correlation function. We also used the vector radiative transfer formula for the layer of a random medium by solving Gaussian quadrature and eigen analysis. By comparing the brightness temperatures at 5, 10.7, 18, and 37 GHz, the modelling results agreed with experimental data of dry-snow physical parameters as measured in the fieldwork.     

Research on carbon emissions in China's export trade based on input-output model

Becoming the world’s largest emitter of carbon makes China the object of criticism;however,people may ignore the fact that when China exports low-carbon products,the carbon emissions have been left in the meanwhile,forming the so-called"embodied carbon".Using the input-output model,this paper analyzes the carbon emission intensity and amount of embodied carbon of various sectors in China’s export trade in 2002 and 2007,and filters out high carbon emission sectors.In addition,this paper also points out the problem of carbon emissions’international transfer from developed countries to China through the analysis of national and regional flow of export carbon emissions and changing of the proportion of emissions for exports relative to total emissions,and explains the reason that caused carbon transfer to China by using the treadmill of production theory.Based on that,this paper proposes some measures for carbon reduction in China from the foreign trade perspective.     

区域可持续发展生态评估的能值分析研究进展与展望

可持续发展的生态评估是当前国际生态经济学与可持续发展研究的前沿问题之一，能值分析以能量为单位定量评估人类生态经济系统中各种生态流的可持续性，是一个重要的研究方向。尽管能值分析定量评价了自然环境资源对人类生态经济系统的贡献．克服了传统能量与经济分析方法的诸多缺憾，但在理论方法上仍存在不足之处。综合国内外区域能值分析的最新进展。能值转换率的确定、能值分析与空阃格局分析的整合、能值成本价值论与市场（使用）价值论的整合、可持续性阈值等问题将是下一步的研究重点。     

基于层次分析法的消防中队灭火救援能力评估

火灾风险评价是认识和控制建筑(区域)火灾的基本手段.目前对建筑(区域)火灾风险的评价方法很多,但是这些方法很少系统地考虑消防力量对建筑风险的影响.本文在调查研究和专家打分的基础上,构建了消防力量中的灭火救援基本单位--消防中队灭火救援能力评价指标体系,并运用层次分析法确定各指标的权重.该体系为消防中队灭火救援能力评价研究提供一种新的尝试,也为以后的建筑风险综合评价中如何确定消防力量对风险因子的影响提供可靠的基础数据.