PHYSICAL DETERMINANTS OF ECONOMIC VALUE OF RIPARIAN BUFFERS IN AN AGRICULTURAL WATERSHED1

ABSTRACT: Economic values of riparian buffers in a watershed are evaluated by the changes in the net economic return for farming with and without riparian buffers when achieving the same water quality objectives. The simulated water quality impacts of alternative farming systems using SWAT and experimental data for riparian buffers are used in a mathematical optimization model to estimate net economic return for farming subject to a water quality objective. Physical characteristics such as stream length, channel slope, average land slope, cropland percentage and several soil attributes are identified in the watershed using ARC/INFO GIS. A regression model is then used to evaluate the impacts of these physical characteristics on the estimated economic values of buffers. The study is conducted in Goodwater Creek watershed, Missouri. The results show the estimated economic value of buffers is significantly affected by some soil properties, stream length, and cropland percentage in watershed and can be used to improve the effectiveness of riparian buffers at watershed and regional levels.     

固定床PVC燃烧脱氯的机理和试验

研究垃圾组分PVC在焚烧过程中HCl的排放和脱除特性的实验在准等温、电加热的水平石英管反应器中进行.随着床温从700℃升高到900℃,HCl的转化率从82.5%平缓增加到88.3%,而过量空气系数的增加促使部分HCl转化为C1₂(1.9%～4.5%)的形式存在.钙基吸收剂CaCO₃,Ca(OH)₂,Ca(CH₃COO)₂对HCl的脱除效率高达68%～79%,而镁基吸收剂的脱氯效率却低于3%.小的吸收剂粒径、高的Ca/Cl比会促进脱氯效率的提高;烟气中CO₂和H₂O对脱氯效率的影响与它们在反应平衡中所起作用有关.高温下燃烧固氯机理反应的平衡常数的计算不仅诠释了实验结果,而且提供了脱氯吸收剂选择的依据.     

Determination of the dissociation constants of polyepoxysuccinic acid

The dissociation constants of polyepoxysuccinic acid (PESA) were investigated in this study. Based on the potentiometric titration and the BEST program, the dissociation constants of PESA were determined. Considering the complexity of the dissociation of PESA in aqueous solution, several models were constructed to simulate the dissociation process of PESA. By comparison, the dissociation constants of PESA were obtained with model 4. The species distribution of PESA in aqueous solution as a function of pH was also presented according to the experimental and calculation results. It showed that the H₂L model with five basic structure units to describe the dissociation of PESA was reasonable, and the relevant constants had less error and better matching between the experimental and calculation data. The corresponding values of pK _ai were 4.68 and 4.92, respectively, for H₂L at 35°C with ionic strength of 0.1 mol/L.     

恶臭嗅辨实验室的建立与发展研究

在使用国家推荐标准方法《空气质量恶臭的测定三点比较式臭袋法》（GB／T14675—93）测定恶臭气体浓度时,环节较多较繁杂,需要人工配气和人工嗅辨,监测过程中使用的器材、设备较多,因此容易引入误差。笔者建议从器材设备、实验室布局、嗅辨员选择等方面加强质量管理,通过严格执行相关标准,规范配气和嗅辨环节,加强质量控制等措施建立标准、规范的实验室,以提高监测结果的准确性。文章也简要介绍了国内外针对该方法监测过程中人工配气、人工嗅辨、人工计算的三大环节所开展的探索。     

土壤汞污染及修复措施研究进展

土壤汞污染已经严重危害到人类健康和生态环境,成为一个世界性问题,对其治理的各种修复措施也成为当前研究的一个热点。本文对土壤汞污染的来源、危害和修复措施等方面进行综述,指出了当前存在的问题,并对今后治理的研究方向提出了相关建议。     

Occurrence and infection risk of waterborne pathogens in Wanzhou watershed of the Three Gorges Reservoir, China

The Three Gorges Reservoir (TGR), formed by China’s Yangtze Three Gorges Project, is the largest lake in the world, but there is too little information available about fecal contamination and waterborne pathogen impacts on this aquatic ecosystem. During two successive 1-year study periods (July 2009 to July 2011), the water quality in Wanzhou watershed of the TGR was tested with regard to the presence of fecal indicators and pathogens. According to Chinese and World Health Organization water quality standards, water quality in the mainstream was good but poor in backwater areas. Salmonella, Enterohemorrhagic Escherichia coli (EHEC), Giardia and Cryptosporidium were detected in the watershed. Prevalence and concentrations of the pathogens in the mainstream were lower than those in backwater areas. The estimated risk of infection with Salmonella, EHEC, Cryptosporidium, and Giardia per exposure event ranged from 2.9 × 10 -7 to 1.68 × 10-5 , 7.04 × 10-10 to 2.36 × 10-7 , 5.39 × 10-6 to 1.25 × 10-4 and 0 to 1.2 × 10-3 , respectively, for occupational divers and recreational swimmers exposed to the waters. The estimated risk of infection at exposure to the 95% upper confidence limit concentrations of Salmonella, Cryptosporidium and Giardia may be up to 2.62 × 10-5 , 2.55 × 10-4 and 2.86 × 10-3 , respectively. This study provides useful information for the residents, health care workers and managers to improve the safety of surface water and reduce the risk of fecal contamination in the TGR.     

攀钢六号烧结烟气脱硫树脂脱盐工艺参数优化研究

针对攀钢六号烧结烟气脱硫树脂脱盐工艺中存在的脱氯效率低、脱硫剂夹带损耗严重的现状,在现场开展了树脂脱盐工艺参数的优化研究工作。通过对树脂脱盐各步骤工艺参数的优化改进,有效地提高了树脂脱盐的脱氯效率及降低了脱硫剂损耗,为脱硫系统的高效、稳定运行奠定了基础。     

流砂过滤技术在齐鲁乙烯污水处理中的应用

针对中国石化齐鲁乙烯污水场流砂过滤器在调试和运行中存在的问题,分析了流砂过滤器优化运行的措施和效果。     

Effects of fenvalerate concentrations and its chiral isomers on bacterial community structure in the sediment environment of aquaculture ponds

To investigate the effect of chiral pesticide fenvalerate (FV) on the micro-ecological environment of aquaculture pond sediment, we used an indoor static experiment to observe the effects of FV added at different concentrations with different chiral isomers on the changes in the sediment bacterial community. The 16S rDNA high-throughput sequencing technique was used to conduct sequencing and analysis of the bacterial community structure as well as changes in aquaculture pond sediments after 4 weeks of cultivation. The results showed that the microbial alpha diversity indices (Sobs and Shannon indices) of the treated groups were significantly lower than those of the control group after 4 weeks (P < 0.05), and the values in the high-concentration group were significantly lower than those of the low-concentration group (P < 0.05). In terms of bacterial group composition, the proportion of abundance of Proteobacteria and Acidobacteria in the treated groups were greater than in the control group after 4 weeks, while the proportion of abundance of Bacteroidetes and Verrucomicrobia were lower. In the high-concentration FV treatment group, the proportion of abundance of Bacteroidetes, Acidobacteria, Chloroflexi, Nitrospinae, unclassified_k_norank, Ignavibacteriae, and Nitrospirae were significantly different from those of the other groups (P < 0.05). Principal coordinate analysis (PCoA) and ANONISIM/Adonis analysis showed that the cis-enantiomer had a stronger effect on the bacterial community as the concentration of FV increased. In addition, the linear discriminant analysis effect size (LEfSe) and linear discriminant analysis (LDA) results revealed differences in the level of enrichment of bacterial groups caused by FV at different concentrations and isomer levels. Collectively, this study showed that FV residue has a pronounced effect on bacterial communities in sediment, which becomes more significant with increasing exposure concentration. The effects of the cis- and trans-enantiomers of FV on the sediment environment are different; the cis-enantiomer has a stronger effect on the bacterial community.