Assessment of chlorophyll-a as a criterion for establishing nutrient standards in the streams and rivers of Illinois

Nutrient enrichment is a frequently cited cause for biotic impairment of streams and rivers in the USA. Efforts are underway to develop nutrient standards in many states, but defensible nutrient standards require an empirical relationship between nitrogen (N) or phosphorus (P) concentrations and some criterion that relates nutrient levels to the attainment of designated uses. Algal biomass, measured as chlorophyll-a (chl-a), is a commonly proposed criterion, yet nutrient-chl-a relationships have not been well documented in Illinois at a state-wide scale. We used state-wide surveys of >100 stream and river sites to assess the applicability of chl-a as a criterion for establishing nutrient standards for Illinois. Among all sites, the median total P and total N concentrations were 0.185 and 5.6 mg L(-1), respectively, during high-discharge conditions. During low-discharge conditions, median total P concentration was 0.168 mg L(-1), with 25% of sites having a total P of > or =0.326 mg L(-1). Across the state, 90% of the sites had sestonic chl-a values of < or =35 microg L(-1), and watershed area was the best predictor of sestonic chl-a. During low discharge there was a significant correlation between sestonic chl-a and total P for those sites that had canopy cover < or =25% and total P of < or =0.2 mg L(-1). Results suggest sestonic chl-a may be an appropriate criterion for the larger rivers in Illinois but is inappropriate for small rivers and streams. Coarse substrate to support benthic chl-a occurred in <50% of the sites we examined; a study using artificial substrates did not reveal a relationship between chl-a accrual and N or P concentrations. For many streams and rivers in Illinois, nutrients may not be the limiting factor for algal biomass due to the generally high nutrient concentrations and the effects of other factors, such as substrate conditions and turbidity.     

Chronic and episodic acidification of Adirondack streams from acid rain in 2003-2005

Limited information is available on streams in the Adirondack region of New York, although streams are more prone to acidification than the more studied Adirondack lakes. A stream assessment was therefore undertaken in the Oswegatchie and Black River drainages; an area of 4585 km(2) in the western part of the Adirondack region. Acidification was evaluated with the newly developed base-cation surplus (BCS) and the conventional acid-neutralizing capacity by Gran titration (ANC(G)). During the survey when stream water was most acidic (March 2004), 105 of 188 streams (56%) were acidified based on the criterion of BCS < 0 microeq L(-1), whereas 29% were acidified based on an ANC(G) value < 0 microeq L(-1). During the survey when stream water was least acidic (August 2003), 15 of 129 streams (12%) were acidified based on the criterion of BCS < 0 microeq L(-1), whereas 5% were acidified based on ANC(G) value < 0 microeq L(-1). The contribution of acidic deposition to stream acidification was greater than that of strongly acidic organic acids in each of the surveys by factors ranging from approximately 2 to 5, but was greatest during spring snowmelt and least during elevated base flow in August. During snowmelt, the percentage attributable to acidic deposition was 81%, whereas during the October 2003 survey, when dissolved organic carbon (DOC) concentrations were highest, this percentage was 66%. The total length of stream reaches estimated to be prone to acidification was 718 km out of a total of 1237 km of stream reaches that were assessed.     

Lake variability: key factors controlling mercury concentrations in New York State fish

A 4year study surveyed 131 lakes across New York State beginning in 2003 to improve our understanding of mercury and gather information from previously untested waters. Our study focused on largemouth and smallmouth bass, walleye and yellow perch, common piscivorous fish shown to accumulate high mercury concentrations and species important to local fisheries. Fish from Adirondack and Catskill Forest Preserve lakes generally had higher mercury concentrations than those from lakes in other areas of the state. Variability between nearby individual lakes was observed, and could be due to differences in water chemistry, lake productivity or the abundance of wetlands in the watershed. We found the following factors impact mercury bioaccumulation: fish length, lake pH, specific conductivity, chlorophyll a, mercury concentration in the water, presence of an outlet dam and amount of contiguous wetlands.     

Evaluating mobilization and transport of arsenic in sediments and groundwaters of Aquia aquifer, Maryland, USA

Groundwater and sediment samples were collected along a flow path in the Aquia aquifer (Paleocene), Maryland in order to examine and study the factors influencing "evolution" of arsenic (As) in these groundwaters. The Aquia crops out near Washington, DC, where it is unconfined, and extends approximately 90 km down dip to the south and east towards and beneath the Chesapeake Bay. The studied flow path was chosen owing to (i) the number of accessible wells, (ii) differences in total dissolved As concentrations in groundwaters from some of the sampled wells, which reach values >/=667 nmol kg(-1) or >/=50 ppb, and (iii) the distinct difference in total dissolved As concentrations in Aquia groundwaters between the northern and southern portions of the study area. In groundwater samples, in situ separation of inorganic As species [As(III) and As(V)] were performed by using anion exchange chromatography. Subsequently, As concentrations were determined by inductively coupled plasma mass spectrometry. In situ measurements of Fe concentrations and speciation, dissolved S(-II) concentrations, pH, alkalinity, and oxidation-reduction potential (Eh) were determined to establish the oxidation-reduction conditions and solution chemistry along the flow path. Concentrations of As in 12 analyzed groundwater samples range from approximately 0.75 to 1 072 nmol kg(-1), and As(III) concentrations ranging from 0.24 to 980 nmol kg(-1) appears to be the dominant form of As in solution. 50% of the studied wells yielded groundwaters with concentrations that exceed the US EPA's Maximum Contaminant Level for As in drinking water of 133 nmol kg(-1) or 10 ppb. In order to examine the solid phase speciation of As within the aquifer sediments, we collected a number of Aquia sediment samples from a drill core that was archived at the Maryland Geological Survey. These sediment samples were evaluated using a previously established sequential extractions procedure. Solid phase As concentrations range between 973 and 2,012 nmol kg(-1). Additionally, petrographic, X-Ray diffraction and diffuse reflectance spectroscopy analyses of the Aquia sediments reveal presence of glauconite, and smectite along with goethite and hematite within the samples. Here, we present the possible mechanisms responsible for the elevated As concentrations in the studied groundwaters of the Aquia aquifer.     

Development and Application of Critical,Target and Monitoring Loads for the Management of Acid Deposition in Alberta,Canada

The Alberta, Canada acid deposition management framework, based upon the application of critical, target and monitoring loads, is described. This framework is the culmination of four years work by stakeholders brought together within Alberta's Clean Air Strategic Alliance (CASA). The elements of the framework include scientific aspects of measurement, model estimation, and monitoring of acid deposition, assessment of receptor sensitivity, and management processes to reduce emissions and deposition (should reductions become necessary). All loads are applied to grid cells measuring 1°latitude × 1° longitude, with each cell being categorized as sensitive, moderately sensitive or of low sensitivity on the basis of the sensitivities of the soil and water systems within the cell. Critical loads have been set at 0.25, 0.50 and 1.00 keq H⁺ ha^-1 yr^-1 for grid cells that are categorized as sensitive, moderately sensitive, and of low sensitivity, respectively. Target loads, the environmental management objectives, have been set at 0.22, 0.45, and 0.90 keq H⁺ ha^-1 yr^-1, and monitoring loads, a new concept in acid deposition management, have been set at 0.17, 0.35 and 0.70 keq H⁺ ha^-1 yr^-1 for the three sensitivity classes. When model prediction indicates that deposition may be exceeding the monitoring load, deposition monitoring and receptor sensitivity studies are to be initiated to confirm the deposition model prediction, and to ensure that the sensitivity of the recipient systems is understood. In this manner, management actions that occur in the event of a target load exceedance will be based upon receptor sensitivity and deposition data rather than upon model prediction alone. A process for stakeholder involvement in the evaluation of the framework and its application in long-term, long-range management of emissions and deposition is also included within the framework.     

Do national levels of individualism and internal locus of control relate to well‐being: an ecological level international study

Data were collected from managers in 24 nations/territories on work locus of control (LOC), individualism–collectivism (I–C), and well‐being (job satisfaction, absence of psychological strain, and absence of physical strain). There were significant mean differences across samples on all five of these measures, and consistent with our hypothesis, at the ecological or sample mean level well‐being was associated with an internal locus of control. However, contrary to our hypothesis, well‐being was not associated with I–C, despite a strong correlation between I–C and LOC. Findings at the ecological level were consistent with the literature concerning the salutary effects of control on well‐being. Copyright © 2001 John Wiley & Sons, Ltd.     

Effects of Organized Turtle Watches on Loggerhead (Caretta caretta) Nesting Behavior and Hatchling Production in Florida

To evaluate the effects of organized turtle watches on female sea turtles and their eggs, we quantified nesting behavior and hatchling production of loggerhead turtles ( Caretta caretta ) in south Brevard Country, Florida, U.S.A. We compared the duration of five phases of nesting behavior, the directness of the turtle's return path, rate of travel during return crawl, hatching success, and hatchling emergence success between experimental and control turtles. Experimental turtles nested while observed by an organized turtle watch group consisting of at least 15 people; control turtles were not observed by a turtle watch group. Experimental turtles spent significantly less time camouflaging nest sites than did control turtles. The duration of the other four phases of nesting behavior were not significantly different between the two groups. Experimental turtles also traveled less-direct paths during return crawls, although their rates of travel were not significantly different from those of control turtles. Hatching success and hatchling emergence success were not significantly different between experimental and control turtle nests in either year. Although turtle watch groups influenced nesting behavior, they were not found to be detrimental to hatchling production. Florida's turtle watch program is a means for garnering public support for sea turtle conservation through education, and it should continue.     

Cornelia de Lange syndrome (CdLS): prenatal and autopsy findings

Cornelia de Lange Syndrome (CdLS) is a multisystem disorder characterized by somatic defects and mental retardation. Prenatal diagnosis of this severe condition is difficult in view of the non-specific ultrasound abnormalities. We report three cases with prenatally suspected CdLS based on the ultrasound findings as well as low PAPP-A detected on first trimester screening in one case, and the results of the autopsy and the NIPBL gene mutation analysis. Copyright © 2009 John Wiley & Sons, Ltd.     

A conceptual scheme for aquatic studies: Framework for aquatic curriculum development

Responding to increased concern for an aquatically literate public, the authors discuss the present state of aquatic education curriculum efforts, the need for a comprehensive conceptual scheme for aquatic studies, and the subsequent development and use of the COAST Conceptual Scheme for Aquatic Studies.     

Canadian insights: The challenges of an integrated environmental assessment framework

The paper draws results from a review of literature to examine the strengths and weaknesses of the integrated environmental assessment framework in Canada with respect to the inclusion of health impact assessment. Insights include the legislative nature, rigid structure and priority for the natural environment that may restrict progress and the pool of government agencies that need to be convinced of the benefits of health impact assessment that may provide a strong structure for compliance in the long term.