Interference by wood ant influences size selection and retrieval rate of prey by Formica fusca

Summary Dominance relations between the territorial wood ant Formica polyctena and the submissive F. fusca generate testable predictions on the mechanisms of their coexistence. Here I tested the influence of interference competition by the dominant F. polyctena on the foraging of F. fusca. In the presence of F. polyctena, the activity and the retrieval rate of items of F. fusca decreased significantly. When F. fusca were given a choice between small chironomids and flies a hundred times heavier they selected nearly always flies in the absence of wood ants; when disturbed F. fusca took proportionately more chironomids. In nature, irrespective of distance from the wood-ant mound the size distribution of potentially available food items was the same. F. fusca collected smaller items close to the wood-ant mound, where the density of interfering wood ants was high, than far from it. Also, F. polyctena carried larger protein items from the outskirts of its territory than from the center. The items of F. fusca were on average smaller than those of F. polyctena although the item-size overlap was substantial. When encountering a F. polyctena, those F. fusca workers carrying a fly always lost their booty to the dominant but always managed to bring the chironomids to the nest. F. fusca and F. polyctena were equally efficient in detecting single chironomids placed on the surface of ground, but the presence of either species decreased the discovery rate of the other. This implies mutual exploitation competition between the species for the locally most abundant protein resource. F. polyctena found single flies faster than F. fusca. In an earlier study I showed that close to the wood-ant mound the colony size and production of sexual offspring of F. fusca were reduced. I suggest that the suppressed colony success of F. fusca is attributable to the diminished size and decreased retrieval rate of prey items close to the woodant mound abounding with interfering wood-ant foragers.     

Cost-Effectiveness of Alternative Strategies in Mitigating the Greenhouse Impact of Waste Management in Three Communities of Different Size

Waste management is a significant source of methane (CH₄) emissions. CH₄ is second to carbon dioxide (CO₂) the most important anthropogenic greenhouse gas. In this article the methodology and results from a study on the reduction potential of alternative waste treatment strategies in mitigating the greenhouse impact are presented. The objective is to provide information to decision makers so that the greenhouse issue can be included in the decision making on waste management strategies. The potential cost-effectiveness of reducing the greenhouse impact of alternative waste treatment strategies in three communities of different size in Finland is assessed. The estimation of the greenhouse impact includes estimates of the greenhouse gas (GHG) emissions, the amount of carbon (C) stored at landfills (Csink) and the emission savings that can be achieved by using waste for energy production (assumed decrease in the use of fossil fuels). Landfill gas recovery with energy production was found to be the most-efficient way in reducing the greenhouse impact from large landfills. Burning of all the waste or the combustible fraction in municipal solid waste (MSW) was also an efficient method to reduce greenhouse gas emissions, especially if the energy produced can reduce the burning of fossil fuels. Emissions from transportation of waste are small compared with the emissions from landfills. Even if the transportion mileage is doubled due to increasing separation and recycling the greenhouse impact of transportation would be only 3–4 percent of the impact of landfilling the waste.     

Henry's law constants for hexachlorobenzene, p,p'-DDE and components of technical chlordane and estimates of gas exchange for Lake Ontario

The Henry's law constants (HLC) for trans- and cis-chlordane (TC, CC), trans-nonachlor (TN), hexachlorobenzene (HCB) and p,p'-DDE were determined by the gas-stripping method over a temperature range of 5-35 degrees C. The HLC variation versus temperature (K) was described by logH=m/T+b. Parameters of this equation were (with standard deviations) TC: m=-1524+/-158, b=6.58+/-0.54; CC: m=-1786+/-209, b=7.42+/-0.71; TN m=-2068+/-284, b=8.44+/-0.97; HCB: m=-3013+/-174, b=11.60+/-0.59 and p,p'-DDE: m=-2043+/-240, b=8.37+/-0.82. The HLCs (Pa m3 mol(-1)) at 25 degrees C (298.15 K) were: TC=29; CC=27; TN=32; p,p'-DDE=33 and HCB=35. These HLCs values were used to calculate fugacity ratios from paired air and water data from Lake Ontario, July 1998. The resulting fugacity ratios predict that volatilization was occurring for all compounds during that month.     

Natural Oil-Based Alkyd-Acrylic Copolymers: New Candidates for Barrier Materials

The feasibility of using alkyd-acrylic copolymers as a barrier material was studied. Copolymers of tall oil fatty acid or rapeseed oil-based alkyd resin and polyacrylates were synthesized and films of these copolymers were prepared. Nuclear magnetic resonance spectroscopy revealed that after copolymerization the proportion of double bonds in alkyd resin was diminished due to grafting reactions. The mechanical properties, such as strength and flexibility, of the copolymer films were tested, and the performance of the films as water, oil, and oxygen barrier was evaluated. An increased amount of alkyd resin made the films more brittle and increased their oxygen permeability, however, at the same time their hydrophobicity was increased.     

Parameterization and evaluation of sulfate adsorption in a dynamic soil chemistry model

Sulfate adsorption was implemented in the dynamic, multi-layer soil chemistry model SAFE. The process is modeled by an isotherm in which sulfate adsorption is considered to be fully reversible and dependent on sulfate concentration as well as pH in soil solution. The isotherm was parameterized by a site-specific series of simple batch experiments at different pH (3.8-5.0) and sulfate concentration (10-260 micromol 1(-1)) levels. Application of the model to the Lake Gardsj6n roof covered site shows that including sulfate adsorption improves the dynamic behavior of the model and sulfate adsorption and desorption delay acidification and recovery of the soil. The modeled adsorbed pool of sulfate at the site reached a maximum level of 700 mmol/m(2) in the late 1980s, well in line with experimental data.     

Heterogeneous preferences for recreation-oriented management in commercial forests: the role of citizens’ socioeconomic characteristics and recreational profiles

The management of forests for multiple benefits, such as recreational services alongside timber production, can greatly benefit from the knowledge of public preferences for management-related forest attributes. This paper investigates citizens’ recreational use and preferences for recreation-oriented management in the case of state-owned commercial forests in Finland using data from a choice experiment study. We focus on attributes related to the typical management practices applied to enhance recreation: scenic buffer zones along waters, game bird habitats, and the quality of scenery along hiking trails. Recreational use and its frequency were found to be related to citizens’ background and specific outdoor activities. The scenic buffer zones were the most important attribute to the citizens. While the recreation-enhancing practices were generally valued, respondent segments with distinct preferences were found. Preference heterogeneity was related to citizens’ socioeconomic characteristics and recreational profiles.     

Investigation of source apportioning for α-HCH using enantioselective analysis

Enantiomeric analysis can be used as a complementary tool for source apportionment of chiral compounds, particularly for α-HCH. In this study we used archived samples from studies related to the distribution of POPs in air–water and air–soil–grass systems. Such approach is based on the behaviour of chiral compounds released into the atmosphere from a primary source, when they are expected to show racemic or close to racemic composition. Contrarily, when chiral compounds have been reemitted from secondary sources (e.g. water or soil), their enantiomeric signatures are frequently non-racemic and are similar to the signature of the secondary source. To show such evidence, extracts from passive air samples deployed throughout Europe were analyzed for the enantiomers of α-HCH. The proximity to a large water body showed a high impact on the enantiomeric signatures: Baltic air had enantiomeric fractions (EFs) < 0.500, while Mediterranean air had predominantly EFs > 0.500. Similarly, Atlantic air showed a latitude influence: above 50°N most EFs < 0.500, whereas at latitudes below 50°N, EFs were > 0.500. A similar trend was also observed for EFs of α-HCH measured in air samples from a latitudinal transect during an Atlantic cruise. This transect shows that samples from higher latitudes (above 40°N) have EF < 0.500, whereas in the more southern samples (African coast and Southern Atlantic), there is no clear trend for EFs. Inland air samples showed a large range in EF values, with racemic signatures for samples with the highest α-HCH concentrations and an increasing spread in the EFs for lower α-HCH concentrations. As expected, the EF values of α-HCH in air, soils and grass were also impacted by latitude. Correlations between EFs and geographic characteristics of the sampling locations, as well as α-HCH concentrations, α-/γ-isomer ratios, or temperature suggest that enantioselective analysis can give additional information on the distribution and sources of α-HCH in the environment.     

Nontargeted evaluation of the fate of steroids during wastewater treatment by comprehensive two-dimensional gas chromatography–time-of-flight mass spectrometry

Emerging organic contaminants in wastewater are usually analyzed by targeted approaches, and especially estrogens have been the focus of environmental research due to their high hormonal activity. The selection of specific target compounds means, however, that most of the sample components, including transformation products and potential new contaminants, are neglected. In this study, the fate of steroidal compounds in wastewater treatment processes was evaluated by a nontargeted approach based on comprehensive two-dimensional gas chromatography–time-of-flight mass spectrometry. The potential of the nontargeted approach to generate comprehensive information about sample constituents was demonstrated with use of statistical tools. Transformation pathways of the tentatively identified compounds with steroidal four-ring structure were proposed. The purification efficiency of the wastewater treatment plants was studied, and the distribution of the compounds of interest in the suspended solids, effluent water, and sludge was measured. The results showed that, owing to strong adsorption of hydrophobic compounds onto the solid matter, the steroids were mostly bound to the suspended solids of the effluent water and the sewage sludge at the end of the treatment process. The most abundant steroid class was androstanes in the aqueous phase and cholestanes in the solid phase. 17β-estradiol was the most abundant estrogen in the aqueous phase, but it was only detected in the influent samples indicating efficient removal during the treatment process. In the sludge samples, however, high concentrations of an oxidation product of 17β-estradiol, estrone, were measured.     

Effects of soil phosphorus status on environmental risk assessment of glyphosate and glufosinate-ammonium

The increased use of herbicides poses a risk to the aquatic environment. Easy and economical methods are needed to identify the fields where specific environment protection measures are needed. Phosphorus (P) and organophosphorus herbicides compete for the same adsorption sites in soil. In this study the relationship between P obtained in routine Finnish agronomic tests (acid ammonium acetate [P(AC)]) and adsorption of glyphosate and glufosinate-ammonium was investigated to determine whether P(AC) values could be used in the risk assessment. The adsorption of glyphosate ((N-(phosphonomethyl)glycine) and glufosinate-ammonium (2-amino-4-(hydroxymethylphosphinyl)butanoic acid) was studied in a clay and a sandy loam soil enriched with increasing amounts of P added as potassium dihydrogen phosphate. Desorption was also determined for some P-enriched soil samples. The adsorption of both herbicides diminished with increasing P(AC) value. The correlations between Freundlich adsorption coefficients obtained in the adsorption tests and P(AC) were nonlinear but significant (r > 0.98) in both soils. The exponential models of the relationship between soil P(AC) values and glyphosate adsorption were found to fit well to an independent Finnish soil data set (P < 0.1 for glyphosate and P < 0.01 for glufosinate-ammonium). The desorption results showed that glufosinate-ammonium sorption is not inversely related to soil P status, and the high correlation coefficients obtained in the test of the model were thus artifacts caused by an abnormal concentration of exchangeable potassium in soil. The solved equations are a useful tool in assessing the leaching risks of glyphosate, but their use for glufosinate-ammonium is questionable.     

波罗的海蓝藻赤潮的历史

波罗的海所发生的赤湖,主要是由Nodudaria spupmigena和Aphanizomenon sp.这两种蓝藻形成的.有关这些赤潮的长期变化记录可以从过去(1887～1938年)和现代(1974～1998年)出版的浮游植物数据记录中找到.通过各种不同的收集、分析方法已经得到了大量的数据,为了提高这些数据的可比性,人们正在不断地尝试老的、新的采样方式与固定方法.l00多年前,浮游生物就做为鱼类的食物来源而引起了人们的兴趣;富营养化问题主要出现在南部的礁湖(haffs)以及大城市附近的海边水ro域.二战前,很少有关于开阔海域赤潮的报道.在过去的营养环境中,Nodudaria spupmlgena和Aphanizomenon sp.的数量还很少,从l 887～1938年的137个夏季采样中表明它们的丰度还没有达到过最高峰.在现在的营养环境中,高丰度是非常普遍的,这两个物种的数目范围相对于过去的营养环境来说有了明显的增长.自20世纪60年代以来,蓝藻赤潮在波罗的海本体与芬兰湾的开阔海域是非常常见的,这表明了营养物已经高度丰富.