Two‐dimensional transport of lactate‐modified nanoscale iron particles in porous media

This study investigates the two‐dimensional transport of nanoscale iron particles (NIP) and lactate‐modified NIP (LMNIP) in homogeneous and heterogeneous porous media under typical pressurized groundwater flow conditions. A two‐dimensional bench‐scale test setup was developed and a series of experiments was conducted simulating homogeneous sand profile and two‐layer profile with two different sands. NIP and LMNIP at a concentration of 4 g/L were prepared in electrolyte simulating groundwater conditions and were injected at the inlet of the test setup under different pressure gradients (0.5. 0.8, 1, and 2 pounds per square inch). During the testing, effluent was collected and its volume and nanoiron concentrations were measured. At the end of the testing, soil cores were obtained at different distances from the inlet and were used to measure nanoiron concentrations and magnetic susceptibility values. Results showed that the transport of NIP and LMNIP was enhanced by increased pressure gradient. LMNIP transport occurred more uniformly as compared to bare NIP. The iron concentrations decreased with distance from the inlet to the outlet and increased from the top to the bottom of the test cell. The data indicate that, as the particles were transported, they underwent aggregation and sedimentation, which resulted in the observed non‐uniform spatial distribution of iron. The NIP and LMNIP transported through the high‐porosity and high‐permeability soil layer in the heterogeneous soil profile, implying that the transport occurred predominantly along the path of least resistance for the flow. Magnetic susceptibility values are found to have good correlation with the iron content in the soil and are helpful to characterize the transport of NIP and LMNIP. Overall, this study shows that the non‐uniform distribution of NIP and LMNIP occurs under two‐dimensional transport conditions and the soil heterogeneities can significantly impact the transport of NIP and LMNIP. The design of field delivery systems should consider such conditions and optimize the pressurized injection systems. © 2011 Wiley Periodicals, Inc.     

Stationary Source Surveillance for Large Air Quality Control Regions in Nonurban Areas

Increased energy processing activity in the north has resulted in a demand for measured data on plume dispersion that is relevant to this particular region. The north was, therefore, selected for study in a comprehensive government/Industry research program. The objective of these studies was to assess the behaviour of plumes in various geographic areas In Canada. The program utilizes airborne and automobile-mounted probes to determine SO₂ and temperature profiles within stock-emitted plumes as well as meteorological data on local atmospheric structure. The data are then analyzed numerically to obtain plume axis elevations and standard deviations of spread and these results are compared to accepted predictive methods. Good agreement with the analysis of Briggs was observed for predicting the location of the plume axis In neutral conditions; some deviations were noted in stable conditions. Values of the measured product ( σay-σ;z) were generally larger than those of Pasquill, particularly for those values close to the source. A difference between the measured values of (σ;y-σ;z) in fall and winter was observed in stable conditions.     

Magnitude and distribution of option value for the Washakie Wilderness,northwest Wyoming,USA

Option value is estimated for the Washakie Wilderness, northwest Wyoming, USA, using the contingent valuation technique. Consumer surplus, the traditional measure of economic value, is estimated separately and compared with option value. Several populations are tested, including Washakie visitors, Yellowstone National Park visitors, and residents from four metropolitan test markets: Salt Lake City, Utah; Portland, Oregon; Nashville, Tennessee; and Orlando, Florida, USA. The average annual preservation option value (consumer surplus) expressed by on-site wilderness visitors is $46.17 ($80.13), by urban residents is $9.70 ($8.97), and by rural residents is $8.43 ($7.80). Four selected attributes are determined to be important in motivating option demand for the Washakie, including existence value, bequest value, the desire for an on-site visit, and interest in securing the visiting privileges of others. The results suggest that option value is important in wilderness valuation and that off-site users account for a large part of the economic value of wilderness.     

Environmental site assessments and audits: Building inspection requirements

Environmental site assessment criteria were originally developed by organizations that focused, almost exclusively, on surface, subsurface, and pollution source contamination. Many of the hazards associated with indoor environments and building structures were traditionally not considered when evaluating sources and entities of environmental pollution. Since a large number of building materials are potentially hazardous, careful evaluation is necessary. Until recently, little information on building inspection requirements of environmental problems has been published. Traditionally, asbestos has been the main component of concern. The ever-changing environmental standards have dramatically expanded the scope of building surveys. Indoor environmental concerns, for example, currently include formaldehyde, lead-based paint, polychlorinated biphenyls, radon, and indoor air pollution. Environmental regulations are being expanded and developed that specifically include building structures. These regulatory standards are being triggered by an increased awareness of health effects from indoor exposure, fires, spills, and other accidents that have resulted in injury, death, and financial loss. This article discusses various aspects of assessments for building structures.     

Getting organizational buy-in for benchmarking: Environmental management at weyerhaeuser

Benchmarking is a process companies use to identify and evaluate the best practices, both inside and outside their industry, in their field of interest. The goal is to identify gaps between their performance and the benchmarks so that they can find ways to improve their performance. This article describes an early benchmarking effort in the environmental management area of the Weyerhaeuser Company.     

COST SHARING IN TRANSITION: THE CASE OF PLAN 6, CENTRAL ARIZONA PROJECT1

ABSTRACT: In the past, development of Federal water resource projects depended heavily or exclusively on Federal financing of construction costs. However, pressures on the Federal budget, environmental issues, and the notion that there are economic efficiency gains when beneficiaries of Federal water resource projects increase their cost share are causing changes. The case of the Central Arizona Project Plan 6 is a noteworthy example of the transition to more non-Federal participation in water resource development. This is because the non-Federal financing is to be provided for a project already under construction. The negotiation and terms of the Plan 6 financing agreement between the Department of the Interior and multiple interests in Arizona are used as an example of how Federal water project cost sharing is in a state of transition. The negotiation process is described, a financial analysis is provided, and the terms of the agreement and policy issues that were deliberated in the Executive Branch of the Federal Government are discussed.     

Impact of flood control reservoirs and pollution influx on the Sandy Creek Watershed,Mercer County,Pennsylvania, USA

A study of the impact of two flood control reservoirs and pollution influx was conducted on two streams within the Sandy Creek Watershed, Mercer County, Pennsylvania, USA. Fecal coliforms were significantly reduced in the outflows without affecting water chemistry, thereby improving the overall water quality. The size and composition of the aquatic communities as well as stream metabolism varied seasonably among the different sampling stations. Pollution influx primarily from communities and agricultural drainage had a greater impact on the stream ecosystem than did impounding of the streams. Natural wetlands and riparian vegetation were important factors in reducing the pollution load in these streams. The reestablishment and maintenance of riparian vegetation should therefore be an integral part of the land-use plan for watersheds in order to improve water quality and wildlife habitats. In the future, the maintenance of riparian vegetation should be given prime consideration in the development of watershed projects.     

EFFECTS OF DIVERSIONS ON THE NORTH AMERICAN GREAT LAKES1

ABSTRACT: Water level fluctuations of the Great Lakes often have created regional controversies among the states and Canadian provinces that share this vast resource. Even though the 100-year range of their water levels is only four to five feet, episodes of high and low Great Lakes water levels have been a recurring problem throughout the twentieth century. The possibility of increased diversion and consumptive use has exacerbated the existing conflicts over how to manage this water resource. A research project evaluated the effects of interbasin diversion on the Great Lakes system and on the industries that depend on the maintenance of historical water levels, namely hydropower and commercial navigation. The simulation approach employed in this research and some of the important findings are presented. The approach is similar to that used in recent government studies of Great Lakes water level regulation. Several significant modifications were made specifically addressing the diversion issue. Aggregate annual impacts to hydropower and shipping resulting from a diversion of 10,000 cubic feet per second were found to vary from 60 to 100 million dollars. Increases in impacts as a function of diversion rate are nonlinear for the navigation industry.     

EMPIRICAL MODELS FOR TROPHIC STATE IN SOUTHEASTERN U.S. LAKES AND RESERVOIRS1

ABSTRACT: A cross-sectional data set of 80 lakes and reservoirs in nine southeastern states was examined to specify and parameterize trophic state relationships. The relationships fitted are based on measurements of several limnological variables taken over the course of a growing season or year in each of the lakes. The trophic state models relate phosphorus and nitrogen loading to inlake phosphorus and nitrogen concentrations, which in turn are related to maximum chlorophyll level, Secchi disk depth, dominant algal species, and hypolimnetic dissolved oxygen status. Due to the empirical nature of the study, causal conclusions are limited; rather, the models are most useful for prediction of average growing season conditions related to trophic state.